The Effects of Concentration, Pressure, and Temperature on the Diffusion Coefficient and Correlation Length of SDS Micelles
The effects of sodium dodecyl sulfate (SDS) concentration (≤ 10 mass %), temperature (35 and 50 °C), and pressure (0.1 to 100 MPa) on the cooperative diffusion coefficient and static correlation length of micelles in solutions in 1 M NaCl were studied using static and dynamic light scattering. These...
Saved in:
| Published in: | The journal of physical chemistry. B Vol. 105; no. 21; pp. 4846 - 4852 |
|---|---|
| Main Authors: | , , , , |
| Format: | Journal Article |
| Language: | English |
| Published: |
American Chemical Society
31-05-2001
|
| Online Access: | Get full text |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| Summary: | The effects of sodium dodecyl sulfate (SDS) concentration (≤ 10 mass %), temperature (35 and 50 °C), and pressure (0.1 to 100 MPa) on the cooperative diffusion coefficient and static correlation length of micelles in solutions in 1 M NaCl were studied using static and dynamic light scattering. These data are interpreted in terms of models of dilute and semidilute solutions of rod-like polymers. The results indicate that the effects of pressure are most significant near the crossover concentration between dilute and semidilute solution behavior. This concentration is a function of temperature and pressure because both of these thermodynamic parameters affect the mean micellar size. |
|---|---|
| Bibliography: | ark:/67375/TPS-D32LT9T4-7 istex:8137DD9AF944654E0DBAD40A369817443C66483A |
| ISSN: | 1520-6106 1520-5207 |
| DOI: | 10.1021/jp004572h |