1-Trifluoroacetyl-2-trimethylstannyl- and 1-trifluoroacetyl-2-bromoacetylenes as new dienophiles in the Diels–Alder reactions

Trifluoroacetic anhydride exotermically reacts with bis(trimethylstannyl)acetylene to form previously unknown 1-trifluoroacetyl-2-trimethylstannylacetylene, which interacts with bromine to produce 1-trifluoroacetyl-2-bromoacetylene.

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Bibliographic Details
Published in:Mendeleev communications Vol. 11; no. 3; pp. 99 - 100
Main Authors: Koldobsky, Andrei B., Shilova, Olga S., Kalinin, Valery N.
Format: Journal Article
Language:English
Published: Elsevier B.V 2001
Online Access:Get full text
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Description
Summary:Trifluoroacetic anhydride exotermically reacts with bis(trimethylstannyl)acetylene to form previously unknown 1-trifluoroacetyl-2-trimethylstannylacetylene, which interacts with bromine to produce 1-trifluoroacetyl-2-bromoacetylene.
ISSN:0959-9436
DOI:10.1070/MC2001v011n03ABEH001401