Search Results - "Kol, Moshe"
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Zirconium Complexes of Phenylene-Bridged {ONSO} Ligands: Coordination Chemistry and Stereoselective Polymerization of rac-Lactide
Published in Inorganic chemistry (02-09-2014)“…Sequential tetradentate dianionic thio-imine diphenolate ligands featuring an ortho-phenylene core and their zirconium complexes are described for the first…”
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2
Titanium and Zirconium Complexes of Dianionic and Trianionic Amine−Phenolate-Type Ligands in Catalysis of Lactide Polymerization
Published in Inorganic chemistry (12-06-2006)“…The synthesis of alkoxotitanium(IV) and -zirconium(IV) complexes of seven chelating tetradentate di- or trianionic amine−phenolate ligands belonging to three…”
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3
Dithiodiolate Ligands: Group 4 Complexes and Application in Lactide Polymerization
Published in Inorganic chemistry (03-05-2010)“…Dithiodiolate ligands were synthesized by reacting 1,2-ethanedithiol or 1,2-benzenedithiol with 2,2-bis(trifluoromethyl)oxirane, led selectively to mononuclear…”
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4
Diastereomerically-Specific Zirconium Complexes of Chiral Salan Ligands: Isospecific Polymerization of 1-Hexene and 4-Methyl-1-pentene and Cyclopolymerization of 1,5-Hexadiene
Published in Journal of the American Chemical Society (11-10-2006)“…Chiral Salan ligands were found to wrap in a highly diastereoselective manner around zirconium leading to C 2-symmetric complexes of predetermined chirality at…”
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5
New facets of an old ligand: titanium and zirconium complexes of phenylenediamine bis(phenolate) in lactide polymerisation catalysis
Published in Chemical communications (Cambridge, England) (01-01-2009)“…Phenylenediamine bis(phenolate) binds in the reduced dianionic form to titanium and zirconium alkoxides giving either mononuclear or bridging dinuclear…”
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Group 4 Complexes of a New [OSSO]-Type Dianionic Ligand. Coordination Chemistry and Preliminary Polymerization Catalysis Studies
Published in Inorganic chemistry (01-10-2007)“…A straightforward synthesis of a new type of tetradentate dianionic [OSSO]-type ligand is described. This ligand features an ethylenedithiol core bridged via…”
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7
Same Ligand, Different Metals: Diiodo−Salan Complexes of the Group 4 Triad in Isospecific Polymerization of 1-Hexene and Propylene
Published in Macromolecules (23-02-2010)Get full text
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8
Isospecific Living Polymerization of 1-Hexene by a Readily Available Nonmetallocene C2-Symmetrical Zirconium Catalyst
Published in Journal of the American Chemical Society (01-11-2000)Get full text
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9
Titanium and Zirconium Complexes of Robust Salophan Ligands. Coordination Chemistry and Olefin Polymerization Catalysis
Published in Journal of the American Chemical Society (20-02-2008)“…The synthesis of [ONNO]-type robust Salophan ligands featuring tertiary nitrogen donors is described for the first time. By varying the substitution pattern on…”
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10
2,2′-Bipyrrolidine versus 1,2-Diaminocyclohexane as Chiral Cores for Helically Wrapping Diamine−Diolate Ligands
Published in Inorganic chemistry (07-09-2009)“…The synthesis of chiral tetradentate dianionic diamine−diolate ligands assembled around either N,N′-dimethyl-trans-1,2-diaminocyclohexane or 2,2′-bipyrrolidine…”
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11
Oscillating Non-Metallocenes - from Stereoblock-Isotactic Polypropylene to Isotactic Polypropylene via Zirconium and Hafnium Dithiodiphenolate Catalysts
Published in European Journal of Inorganic Chemistry (01-12-2011)“…Octahedral group 4 complexes of a new bulky tetradentate dithiodiphenolate {OSSO}‐type ligand that oscillate between two enantiomeric C2‐symmetric…”
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12
Zirconium Complexes of Amine−Bis(phenolate) Ligands as Catalysts for 1-Hexene Polymerization: Peripheral Structural Parameters Strongly Affect Reactivity
Published in Organometallics (09-07-2001)“…Novel amine bis(phenolate) zirconium dibenzyl complexes were synthesized in quantitative yields from a versatile family of chelating…”
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13
Isospecific Polymerization of Vinylcyclohexane by Zirconium Complexes of Salan Ligands
Published in Macromolecules (11-03-2008)“…The polymerization of vinylcyclohexane by C 2-symmetric dibenzylzirconium complexes of nonchiral and chiral Salan ligands that feature electron-withdrawing…”
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14
[ONXO]-Type Amine Bis(phenolate) Zirconium and Hafnium Complexes as Extremely Active 1-Hexene Polymerization Catalysts
Published in Organometallics (18-02-2002)“…Several [ONXO]-type zirconium and hafnium dibenzyl complexes of amine bis(phenolate) ligands, where X is a heteroatom donor located on a pendant arm, were…”
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15
Construction of C1-symmetric zirconium complexes by the design of new Salan ligands. Coordination chemistry and preliminary polymerisation catalysis studies
Published in Chemical communications (Cambridge, England) (2008)“…The first synthesis of achiral and chiral [ONNO']-type Salan ligands featuring two different phenol arms, and the diastereoselective formation of the…”
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Diastereoisomerically Selective Enantiomerically Pure Titanium Complexes of Salan Ligands: Synthesis, Structure, and Preliminary Activity Studies
Published in Inorganic chemistry (27-06-2005)“…The degree of diastereoselectivity in the wrapping of four new chiral Salan ligands to form chiral-at-metal titanium complexes ranged from mild to perfect as a…”
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17
Bis(aniline–phenolate) complexes of group 4 metals: Coordination chemistry and lactide polymerization catalysis
Published in Inorganic chemistry communications (01-05-2011)“…The substituted aniline–phenol ligand binds in the reduced-monoanionic form to the group 4 metals giving fluxional octahedral [{NO} 2M(OR) 2]-type complexes…”
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Zinc Complexes of Amine Mono(phenolate) [NOO2] Ligands: Controlling Coordination Modes by Bulk of Phenolate Substituents
Published in European Journal of Inorganic Chemistry (01-07-2006)“…The coordination chemistry of three tripodal monoanionic amine mono(phenolate) ligands bearing two methoxy sidearm donors with ethylzinc(II) is reported…”
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19
Group IV Complexes of a Tetradentate Amine Mono(phenolate) Ligand: a Second Side-Arm Donor Stabilizes Cationic Species
Published in Inorganic chemistry (14-11-2005)“…An amine mono(phenolate) ligand bearing two side-arm donors led to octahedral trialkoxo and trialkyl group IV metal complexes, in which one of the donors was…”
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20
Eilatin as a Bridging Ligand in Ruthenium(II) Complexes: Synthesis, Crystal Structures, Absorption Spectra, and Electrochemical Properties
Published in Inorganic chemistry (02-06-2003)“…The potential of the heptacyclic aromatic alkaloid eilatin (1), that features two nonequivalent binding sites, to serve as a bridging ligand is reported. The…”
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