Search Results - "Kohlgruber, Tsuyoshi A."
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Assembly of Uranyl Peroxides from Ball Milled Solids
Published in Inorganic chemistry (25-07-2022)“…Mechanochemistry enables transformations of highly insoluble materials such as uranium dioxide or the mineral studtite [(UO2)(O2)(H2O)2]·(H2O)2 into uranyl…”
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Exploring the Role of Organic Functional Groups in the Ionothermal Synthesis of Uranyl Phosphate Materials
Published in Zeitschrift für anorganische und allgemeine Chemie (1950) (13-12-2022)“…Four new hybrid organic‐inorganic uranyl phosphate compounds were structurally characterized after single crystals were grown via ionothermal synthesis using…”
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The Role of Alkalis in Orchestrating Uranyl‐Peroxide Reactivity Leading to Direct Air Capture of Carbon Dioxide
Published in Chemistry : a European journal (14-05-2024)“…Spectator ions have known and emerging roles in aqueous metal‐cation chemistry, respectively directing solubility, speciation, and reactivity. Here, we isolate…”
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Cover Feature: The Role of Alkalis in Orchestrating Uranyl‐Peroxide Reactivity Leading to Direct Air Capture of Carbon Dioxide (Chem. Eur. J. 27/2024)
Published in Chemistry : a European journal (14-05-2024)“…Nuclear double duty? When coupled with heavy alkali counter‐cations, depleted uranium (from nuclear fuel production) in the form of a uranyl triperoxide is a…”
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(NH4)2[UO2Cl4]·2H2O, a new uranyl tetrachloride with ammonium charge-balancing cations
Published in Acta crystallographica. Section E, Crystallographic communications (01-08-2023)“…A new uranyl tetrachloride salt with chemical formula, (NH4)2[UO2Cl4]·2H2O, namely, diammonium uranyl tetrachloride dihydrate, 1, was prepared and crystallized…”
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(NH4)2[UO2Cl4]·2H2O, a new uranyl tetra-chloride with ammonium charge-balancing cations
Published in Acta crystallographica. Section E, Crystallographic communications (07-07-2023)“…While several actinyl tetrahalides have been synthesized and their structures reported, (NH 4 ) 2 (UO 2 Cl 4 )·2H 2 O represents a new uranyl tetrachloride…”
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Effect of Ionothermal Conditions on the Crystallization of Organically Templated Uranyl Sulfate Compounds
Published in Crystal growth & design (03-02-2021)“…Seven novel uranyl sulfate compounds were crystallized by ionothermal synthesis methods through systematic changes in experimental conditions. The parameters…”
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Ionothermal Synthesis of Uranyl Vanadate Nanoshell Heteropolyoxometalates
Published in Inorganic chemistry (01-03-2021)“…Two uranyl vanadate heteropolyoxometalates (h-POMs) have been synthesized by ionothermal methods using the ionic liquid 1-ethyl-3-methylimidazolium diethyl…”
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In situ deca-rbonylation of N , N -di-methyl-formamide to form di-methyl-ammonium cations in the hybrid framework compound {[(CH 3 ) 2 NH 2 ] 2 [Zn{O 3 PC 6 H 2 (OH) 2 PO 3 }]} n
Published in Acta crystallographica. Section E, Crystallographic communications (01-10-2019)“…The title phospho-nate-based organic-inorganic hybrid framework, poly[bis(dimethylammonium) [(μ -2,5-dihydroxybenzene-1,4-diphosphonato)zinc(II)]], {(C H N)…”
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In situ decarbonylation of N , N -dimethylformamide to form dimethylammonium cations in the hybrid framework compound {[(CH 3 ) 2 NH 2 ] 2 [Zn{O 3 PC 6 H 2 (OH) 2 PO 3 }]} n
Published in Acta crystallographica. Section E, Crystallographic communications (01-10-2019)“…The title phosphonate-based organic–inorganic hybrid framework, poly[bis(dimethylammonium) [(μ 4 -2,5-dihydroxybenzene-1,4-diphosphonato)zinc(II)]], {(C 2 H 8…”
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11
(NH 4 ) 2 [UO 2 Cl 4 ]·2H 2 O, a new uranyl tetrachloride with ammonium charge-balancing cations
Published in Acta crystallographica. Section E, Crystallographic communications (01-08-2023)“…A new uranyl tetrachloride salt with chemical formula, (NH 4 ) 2 [UO 2 Cl 4 ]·2H 2 O, namely, diammonium uranyl tetrachloride dihydrate, 1 , was prepared and…”
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Utilizing Ionic Liquids as Bifunctional Reagents for the Ionothermal Synthesis of Uranyl Compounds
Published in Crystal growth & design (01-11-2023)“…The extraction of actinides, specifically uranyl and other actinyl ions, from fission products is a critical aspect of spent nuclear fuel reprocessing. In this…”
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Hydrogen bond network and bond valence analysis on uranyl sulfate compounds with organic-based interstitial cations
Published in Journal of solid state chemistry (01-03-2022)“…Seven new uranyl sulfate compounds with organic charge-balancing cations have been synthesized and structurally characterized. The structural unit topologies…”
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Hydrogen bond network and bond valence analysis on uranyl sulfate compounds with organic-based interstitial cations
Published in Journal of solid state chemistry (31-12-2021)“…Seven new uranyl sulfate compounds with organic charge-balancing cations have been synthesized and structurally characterized. The structural unit topologies…”
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The role of 1-ethyl-3-methylimidazolium diethyl phosphate ionic liquid in uranyl phosphate compounds
Published in Journal of solid state chemistry (01-11-2019)“…The ionic liquid 1-ethyl-3-methylimidazolium diethyl phosphate (EMIM-Et2PO4) was used in the synthesis of four new hybrid organic-inorganic uranyl phosphates…”
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The role of 1-ethyl-3-methylimidazolium diethyl phosphate ionic liquid in uranyl phosphate compounds
Published in Journal of solid state chemistry (01-11-2019)“…Not provided…”
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