Search Results - "Köhler, Klaus"
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Leaching Mechanism of Different Palladium Surface Species in Heck Reactions of Aryl Bromides and Chlorides
Published in ACS catalysis (05-06-2020)“…Since the development of solid palladium catalysts for the Heck coupling reaction, many studies focused on the differentiation between homogeneous and…”
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2
Abatement of nitrous oxide by ruthenium catalysts: Influence of the support
Published in Applied catalysis. A, General (25-09-2015)“…•Synthesis of Ru particles of narrow size distribution (1.5–2nm) on oxide, carbon and carbide supports.•Activated carbon and silicon carbide supports act as…”
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3
Palladium leaching dependent on reaction parameters in Suzuki–Miyaura coupling reactions catalyzed by palladium supported on alumina under mild reaction conditions
Published in Journal of catalysis (28-07-2010)“…Various reaction parameters including temperature, solvent, base, substrates and additives influence the palladium leaching in Suzuki coupling reactions…”
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4
Genesis of Coordinatively Unsaturated Palladium Complexes Dissolved from Solid Precursors during Heck Coupling Reactions and Their Role as Catalytically Active Species
Published in Inorganic chemistry (19-03-2007)“…The Forum Article critically summarizes investigations and discussions on the nature and role of potential active species in C−C coupling reactions of the Heck…”
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Leaching of palladium atoms from small cluster models during Heck reactions – An experimental and theoretical study
Published in Catalysis communications (01-05-2022)“…Relevant parameters for the leaching of palladium atoms from small Pd clusters during Heck reactions of bromobenzene and styrene have been explored…”
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Manganese containing copper aluminate catalysts: Genesis of structures and active sites for hydrogenation of aldehydes
Published in Journal of catalysis (01-03-2021)“…[Display omitted] •Copper aluminate spinel catalysts comprehensively characterized by multiple techniques.•Complex hydrogenation reaction mechanism including…”
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Fluoridonitrosyl Complexes of Technetium(I) and Technetium(II). Synthesis, Characterization, Reactions, and DFT Calculations
Published in Inorganic chemistry (19-05-2014)“…A mixture of [Tc(NO)F5]2– and [Tc(NO)(NH3)4F]+ is formed during the reaction of pertechnetate with acetohydroxamic acid (Haha) in aqueous HF. The blue…”
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In Situ Generation of Highly Active Dissolved Palladium Species from Solid Catalysts-A Concept for the Activation of Aryl Chlorides in the Heck Reaction
Published in Angewandte Chemie International Edition (26-03-2004)“…Needing a leach: Optimized palladium/metal oxide systems are highly active heterogeneous catalysts for the Heck reaction. Non‐activated and deactivated aryl…”
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Macrocyclic Palladium(II) Complexes in CC Coupling Reactions: Efficient Catalysis by Controlled Temporary Release of Active Species
Published in Advanced synthesis & catalysis (10-09-2010)“…Stabilization of palladium species against agglomeration is essential for reasonable catalytic activity in CC coupling reactions. In contrast to common…”
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Reduced nonthermal rollover of wide-well GaInN light-emitting diodes
Published in Applied physics letters (26-01-2009)“…Nonthermal rollover (or efficiency droop) of the electroluminescence (EL) efficiency has been investigated for near-UV-emitting (AlGaIn)N single-well…”
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Acceleration of the Rate of the Heck Reaction through UV- and Visible-Light-Induced Palladium(II) Reduction
Published in ChemCatChem (15-11-2010)“…Irradiation with light (UV and visible) increases the rate of the Heck reaction using homogeneous (palladium(II) acetate) and heterogeneous (Pd/Al2O3 and…”
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Highly Active Palladium/Activated Carbon Catalysts for Heck Reactions: Correlation of Activity, Catalyst Properties, and Pd Leaching
Published in Chemistry : a European journal (02-02-2002)“…A variety of palladium on activated carbon catalysts differing in Pd dispersion, Pd distribution, Pd oxidation state, and water content were tested in Heck…”
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13
Heck Reactions of Aryl Chlorides Catalyzed by Ligand Free Palladium Salts
Published in Catalysis letters (01-10-2008)“…Palladium acetate has been shown to be a highly active catalyst for Heck reactions of aryl chlorides even in the absence of organic ligands. Bromobenzene can…”
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14
Control of Pd leaching in Heck reactions of bromoarenes catalyzed by Pd supported on activated carbon
Published in Journal of molecular catalysis. A, Chemical (31-05-2002)“…Parameters that influence the palladium leaching during and after Heck reactions of aryl bromides with olefins catalyzed by heterogeneous Pd on activated…”
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Single-Site VO x Moieties Generated on Silica by Surface Organometallic Chemistry: A Way To Enhance the Catalytic Activity in the Oxidative Dehydrogenation of Propane
Published in ACS catalysis (02-09-2016)“…We report here an accurate surface organometallic chemistry (SOMC) approach to propane oxidative dehydrogenation (ODH) using a μ2-oxo-bridged, bimetallic…”
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Coherent Zone-Folded Longitudinal Acoustic Phonons in Semiconductor Superlattices: Excitation and Detection
Published in Physical review letters (01-02-1999)Get full text
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Supported palladium as catalyst for carbon–carbon bond construction (Heck reaction) in organic synthesis
Published in Catalysis today (15-03-2001)“…The catalytic activity and selectivity of palladium supported on various metal oxides and zeolites in carbon–carbon coupling reactions of aryl bromides with…”
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18
Quantum Cascade Detectors
Published in IEEE journal of quantum electronics (01-08-2009)“…This paper gives an overview on the design, fabrication, and characterization of quantum cascade detectors. They are tailorable infrared photodetectors based…”
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Reduction of the threading edge dislocation density in AlGaN epilayers by GaN nucleation for efficient 350 nm light emitting diodes
Published in Physica status solidi. B. Basic research (01-07-2010)“…We report on the reduction of the threading edge dislocation density of Al0.15Ga0.85N buffer layers for efficient 350 nm light‐emitting diodes (LEDs)…”
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On-Surface Carbon Nitride Growth from Polymerization of 2,5,8-Triazido‑s‑heptazine
Published in Chemistry of materials (12-09-2023)“…Carbon nitrides have recently come into focus for photo- and thermal catalysis, both as support materials for metal nanoparticles as well as photocatalysts…”
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