Thermochemical Properties of Menthol and Terpineol

The work continues the project of physicochemical characterization of terpenic substances that are present in plants and after emission to the atmosphere play an important role in the formation of cloud condensation nuclei. Two substances, which are solid at room temperature, were studied in this wo...

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Bibliographic Details
Published in:	Journal of solution chemistry Vol. 49; no. 9-10; pp. 1267 - 1278
Main Authors:	Wagner, Zdeněk, Bendová, Magdalena, Rotrekl, Jan, Parmar, Nirmal, Kočí, Stanislav, Vrbka, Pavel
Format:	Journal Article
Language:	English
Published:	New York Springer US 01-10-2020 Springer Nature B.V
Subjects:	Algorithms Chemistry Chemistry and Materials Science Condensation nuclei Condensed Matter Physics Data analysis Enantiomers Enthalpy Geochemistry Industrial Chemistry/Chemical Engineering Inorganic Chemistry Menthol Oceanography Physical Chemistry Room temperature Temperature Terpineol Thermochemical properties Vapor pressure Secondary organic aerosol Menthol Mathematical gnostics Advanced data analysis Terpineol
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Summary:	The work continues the project of physicochemical characterization of terpenic substances that are present in plants and after emission to the atmosphere play an important role in the formation of cloud condensation nuclei. Two substances, which are solid at room temperature, were studied in this work, namely both enantiomers of menthol and (–)- α -terpineol. Temperatures and enthalpies of fusion were measured, isobaric heat capacities were measured in the temperature range 326.15–348.15 K and vapor pressures were measured in the temperature range 400–430 K. The experimental values were compared with predictions by COSMO-RS. Modern nonstatistical algorithms based on mathematical gnostics were used for data analysis.
ISSN:	0095-9782 1572-8927
DOI:	10.1007/s10953-020-01027-6