Plasma enhanced atomic layer deposition of magnesium oxide as a passivation layer for enhanced photoluminescence of ZnO nanowires

The growth characteristics and film properties of magnesium oxide (MgO) thin films fabricated by plasma enhanced atomic layer deposition (PE-ALD) and thermal ALD (Th-ALD) were comparatively investigated for passivation layer applications. For both processes, well-saturated growth characteristics wer...

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Published in:Journal of luminescence Vol. 145; pp. 307 - 311
Main Authors: Song, Jeong-Gyu, Park, Jusang, Yoon, Jaehong, Woo, Hwangje, Ko, Kyungyong, Lee, Taeyoon, Hwang, Sung-Hwan, Myoung, Jae-Min, Kim, Keewon, Jang, Youngman, Kim, Kwangseok, Kim, Hyungjun
Format: Journal Article
Language:English
Published: Amsterdam Elsevier B.V 01-01-2014
Elsevier
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Summary:The growth characteristics and film properties of magnesium oxide (MgO) thin films fabricated by plasma enhanced atomic layer deposition (PE-ALD) and thermal ALD (Th-ALD) were comparatively investigated for passivation layer applications. For both processes, well-saturated growth characteristics were observed, with a higher saturated growth rate for Th-ALD. X-ray photoemission analysis showed that very high purity MgO film with virtually no carbon contamination was deposited by PE-ALD. X-ray diffraction and transmission electron microscopy analysis showed that the PE-ALD MgO thin films had a larger grain size than the Th-ALD MgO thin films and were predominantly (111) crystal orientation. The photoluminescence analysis showed enhanced luminescence properties of the ALD MgO shell/ZnO nanowires. In particular, PE-ALD MgO showed greater enhancement of the luminescence properties than Th-ALD MgO. •Atomic layer deposition of Magnesium oxide (MgO) thin films were studied using Magnesium bis(cyclopentadienyl) (MgCp2) with H2O and O2 plasma.•PE-ALD MgO thin films show (111) orientation and have larger grain size than Th-ALD MgO thin films.•Enhanced luminescence properties of the ALD MgO shell/ZnO nanowires are observed.•PE-ALD MgO showed greater enhancement of the luminescence properties than Th-ALD MgO.
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content type line 23
ISSN:0022-2313
1872-7883
DOI:10.1016/j.jlumin.2013.07.076