Plasma enhanced atomic layer deposition of magnesium oxide as a passivation layer for enhanced photoluminescence of ZnO nanowires
The growth characteristics and film properties of magnesium oxide (MgO) thin films fabricated by plasma enhanced atomic layer deposition (PE-ALD) and thermal ALD (Th-ALD) were comparatively investigated for passivation layer applications. For both processes, well-saturated growth characteristics wer...
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Published in: | Journal of luminescence Vol. 145; pp. 307 - 311 |
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Main Authors: | , , , , , , , , , , , |
Format: | Journal Article |
Language: | English |
Published: |
Amsterdam
Elsevier B.V
01-01-2014
Elsevier |
Subjects: | |
Online Access: | Get full text |
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Summary: | The growth characteristics and film properties of magnesium oxide (MgO) thin films fabricated by plasma enhanced atomic layer deposition (PE-ALD) and thermal ALD (Th-ALD) were comparatively investigated for passivation layer applications. For both processes, well-saturated growth characteristics were observed, with a higher saturated growth rate for Th-ALD. X-ray photoemission analysis showed that very high purity MgO film with virtually no carbon contamination was deposited by PE-ALD. X-ray diffraction and transmission electron microscopy analysis showed that the PE-ALD MgO thin films had a larger grain size than the Th-ALD MgO thin films and were predominantly (111) crystal orientation. The photoluminescence analysis showed enhanced luminescence properties of the ALD MgO shell/ZnO nanowires. In particular, PE-ALD MgO showed greater enhancement of the luminescence properties than Th-ALD MgO.
•Atomic layer deposition of Magnesium oxide (MgO) thin films were studied using Magnesium bis(cyclopentadienyl) (MgCp2) with H2O and O2 plasma.•PE-ALD MgO thin films show (111) orientation and have larger grain size than Th-ALD MgO thin films.•Enhanced luminescence properties of the ALD MgO shell/ZnO nanowires are observed.•PE-ALD MgO showed greater enhancement of the luminescence properties than Th-ALD MgO. |
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Bibliography: | ObjectType-Article-2 SourceType-Scholarly Journals-1 ObjectType-Feature-1 content type line 23 |
ISSN: | 0022-2313 1872-7883 |
DOI: | 10.1016/j.jlumin.2013.07.076 |