Search Results - "Knox, Selby A.R"

Synthesis and reactivity of μ-butadienyl diruthenium cations by Dennett, James N.L, Knox, Selby A.R, Charmant, Jonathan P.H, Gillon, Amy L, Orpen, A.Guy

“…Propargyl alcohols HCCCR 2OH (R=H, Me or Ph) react with [Ru 2(CO)(MeCN)(μ-CO)(μ-CH 2)(η-C 5H 5) 2] ( 2) to form the allylidene complexes [Ru 2(CO)(μ-CO){μ-η…”
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Linking of benzyne and carbon monoxide at a triruthenium centre by migratory insertion by Charmant, Jonathan P.H, Dickson, Helen A.A, Grist, Nigel J, Knox, Selby A.R, Orpen, A.Guy, Saynor, Kathryn, Viñas, Josep M

“…The μ 3-benzyne complex [Ru 3(CO) 7( μ-PPh 2) 2( μ 3-C 6H 4)] ( 1a) reacts at room temperature (r.t.) with carbon monoxide (1 atm), trimethylphosphite, or…”
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Diverse problems by Knox, Selby A.R

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Additions and intramolecular migrations of nucleophiles in cationic diruthenium μ-allenyl complexes by Knox, Selby A.R., Marchetti, Fabio

“…Hydride and halide anions readily replace the acetonitrile ligand in the diruthenium μ-allenyl complex 3b. The hydride can successively migrate to the C α…”
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Specific C–C coupling of the labile diruthenium bridging methylene complex, Cp2Ru2(μ-CH2)(CO)2(MeCN), with diazoalkanes (R2CN2) leading to alkenyl complexes, Cp2Ru2(μ-CHCR2)(μ-H)(CO)2, and alkenes, CH2CR2 by Akita, Munetaka, Hua, Ruimao, Knox, Selby A.R., Moro-oka, Yoshihiko, Nakanishi, Sadahiro, Yates, Michael I.

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The Coordination and Transformation of Arene Rings by Transition Metal Carbonyl Cluster Complexes by Brait, Sabrina, Deabate, Stefano, Knox, Selby A. R, Sappa, Enrico

“…A survey of the synthetic pathways and of the reactivity and catalytic activity of transition metal carbonyl clusters substituted with benzyne (and, for…”
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C-C bond formation at polynuclear metal centers by Knox, Selby A. R.

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Reactivity of bis(diphenylphosphino) methane at a di-iron centre: thermally induced rearrangements of dimetallacyclopentenone complexes [Fe 2(CO) 5{ μ- σ: η3-C(O)CRCr}( μ- dppm)] by Hogarth, Graeme, Knox, Selby A.R., Lloyd, Brian R., Macpherson, Kirsty A., Morton, David A.V., Orpen, A.Guy

“…In toluene at 100°C the dimetallacyclopentenone complex [Fe 2(CO) 5{ μ- σ: η 3-C(O)CHCH}( μ-dppm)] ( 1a) isomerises to the μ-vinyl complex [Fe 2(CO) 6{μ-C(CH…”
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Specific C–C coupling of the labile diruthenium bridging methylene complex, Cp 2Ru 2( μ-CH 2)(CO) 2(MeCN), with diazoalkanes (R 2CN 2) leading to alkenyl complexes, Cp 2Ru 2( μ-CHCR 2)( μ-H)(CO) 2, and alkenes, CH 2CR 2 by Akita, Munetaka, Hua, Ruimao, Knox 1, Selby A.R., Moro-oka 1, Yoshihiko, Nakanishi, Sadahiro, Yates, Michael I.

“…Treatment of the labile μ-methylene species, Cp 2Ru 2( μ-CH 2)(CO) 2(MeCN) 1, with diazoalkanes results in C–C coupling of the alkylidene units. The reaction…”
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Approaches to the synthesis of pentalene via metal complexes by Knox, Selby A. R, Stone, F. Gordon A

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