Search Results - "Knapp, Spring M. M."
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Operando Spectroscopic and Kinetic Characterization of Aerobic Allylic C–H Acetoxylation Catalyzed by Pd(OAc)2/4,5-Diazafluoren-9-one
Published in Journal of the American Chemical Society (03-07-2019)“…Allylic C–H acetoxylations are among the most widely studied palladium(II)-catalyzed C–H oxidation reactions. While the principal reaction steps are well…”
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2
Experimental and Computational Investigation of the Aerobic Oxidation of a Late Transition Metal-Hydride
Published in Journal of the American Chemical Society (10-07-2019)“…The rational development of homogeneous catalytic systems for selective aerobic oxidations of organics has been hampered by the limited available knowledge of…”
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3
Benzoquinone Cocatalyst Contributions to DAF/Pd(OAc)2‑Catalyzed Aerobic Allylic Acetoxylation in the Absence and Presence of a Co(salophen) Cocatalyst
Published in ACS catalysis (04-06-2021)“…Palladium(II)-catalyzed allylic acetoxylation has been the focus of extensive development and investigation. Methods that use molecular oxygen (O2) as the…”
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4
Mechanistic Studies of Alkene Isomerization Catalyzed by CCC-Pincer Complexes of Iridium
Published in Organometallics (27-01-2014)“…Iridium complexes containing CCC-pincer m-phenylene-bridged N-heterocyclic carbene ligands were examined as catalysts for alkene isomerization. Complexes…”
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5
Quinone-mediated hydrogen anode for non-aqueous reductive electrosynthesis
Published in Nature (London) (02-11-2023)“…Electrochemical synthesis can provide more sustainable routes to industrial chemicals 1 – 3 . Electrosynthetic oxidations may often be performed…”
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6
Frontiers in catalytic nitrile hydration: Nitrile and cyanohydrin hydration catalyzed by homogeneous organometallic complexes
Published in Coordination chemistry reviews (01-04-2011)“…Acrylic monomers are a significant part of the global economy, contributing to the manufacture of over a billion tons of diverse polymeric consumer products…”
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7
Ester Hydrogenation Catalyzed by CNN-Pincer Complexes of Ruthenium
Published in Organometallics (11-04-2016)“…Ruthenium complexes supported by two new CNN-pincer ligands were synthesized. Both were tested as catalysts for the hydrogenation of esters under mild…”
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Dichlorido(η(6)-p-cymene)(eth-oxy-diphenyl-phosphane)ruthenium(II)
Published in Acta crystallographica. Section E, Structure reports online (01-12-2012)“…The title compound, [RuCl2(C10H14)(C14H15OP)], is an Ru(II) complex in which an η(6)-p-cymene ligand, two chloride anions and the P atom of an…”
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9
Mechanistic Investigations and Secondary Coordination Sphere Effects in the Hydration of Nitriles with [Ru(η6‑arene)Cl2PR3] Complexes
Published in Organometallics (11-02-2013)“…The mechanism of the nitrile-to-amide hydration reaction using [Ru(η6-arene)Cl2(PR3)] complexes as catalysts was investigated (η6-arene = C6H6, p-cymene,…”
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10
Cyanohydrin Hydration with [Ru(η6-p-cymene)Cl2PR3] Complexes
Published in Organometallics (23-04-2012)“…The catalytic hydration of cyanohydrins to their corresponding α-hydroxyamides provides a route to industrially useful α-hydroxy amides, α-hydroxy esters,…”
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11
Catalytic Nitrile Hydration with [Ru(η6‑p‑cymene)Cl2(PR2R′)] Complexes: Secondary Coordination Sphere Effects with Phosphine Oxide and Phosphinite Ligands
Published in Organometallics (08-07-2013)“…The rates of nitrile hydration reactions were investigated using [Ru(η6-p-cymene)Cl2(PR2R′)] complexes as homogeneous catalysts, where PR2R′ =…”
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12
Investigation of the Reactivity of Pt Phosphinito and Molybdocene Nitrile Hydration Catalysts With Cyanohydrins
Published in Inorganic chemistry (17-08-2009)“…Aldehyde- and ketone-derived cyanohydrins were reacted with the nitrile hydration catalysts [PtCl(PR2OH){(PR2O)2H}] (1) and Cp2Mo(OH)(OH2)+ (2) under a variety…”
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13
Platinum Phosphinito Catalysts for Nitrile Hydration
Published in Journal of inorganic and organometallic polymers and materials (01-01-2014)“…The reaction of PEt 2 OH with K 2 PtCl 4 yields [PtCl{(PEt 2 O) 2 H}] 2 ( 2 ). The X-ray crystal structure of 2 shows that the two chloride ligands bridge the…”
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Dichlorido(η 6 - p -cymene)(ethoxydiphenylphosphane)ruthenium(II)
Published in Acta crystallographica. Section E, Structure reports online (01-12-2012)“…The title compound, [RuCl 2 (C 10 H 14 )(C 14 H 15 OP)], is an Ru II complex in which an η 6 - p -cymene ligand, two chloride anions and the P atom of an…”
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15
2,2'-(Propane-2,2-di-yl)dibenzothia-zole
Published in Acta crystallographica. Section E, Structure reports online (08-09-2010)“…The two symmetry-independent mol-ecules in the asymmetric unit of the title compound, C(17)H(14)N(2)S(2), have similar geometry; the dihedral angles between…”
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16
2,2′-(Propane-2,2-diyl)dibenzothiazole
Published in Acta crystallographica. Section E, Structure reports online (01-10-2010)Get full text
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2,2 #8242;-(Propane-2,2-diyl)dibenzothiazole
Published in Acta crystallographica. Section E, Structure reports online (01-10-2010)“…The two symmetry-independent molecules in the asymmetric unit of the title compound, C17H14N2S2, have similar geometry; the dihedral angles between the…”
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