Search Results - "Klotzbücher, Werner E"
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Sequential Photosubstitution of Carbon Monoxide by (E)-Cyclooctene in Hexacarbonyltungsten: Structural Aspects, Multistep Photokinetics, and Quantum Yields
Published in Organometallics (16-08-1999)“…The photochemical conversion of W(CO)6 (1) into a trans-W(CO)4(η2-olefin)2 complex has been investigated using (E)-cyclooctene (eco) as a model olefin…”
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Dissociative CO Photosubstitution in M(CO)4(1,4-diazabutadiene) Complexes (M = W, Mo) by an Olefin Affording Novel f ac-M(CO)3(1,4-diazabutadiene)(η2-olefin) Derivatives
Published in Organometallics (12-11-2001)“…Photolysis of M(CO)4(iprop-dab) (1, M = W; 2, M = Mo; iprop-dab = 1,4-diisopropyl-1,4-diazabuta-1,3-diene) in the presence of (E)-cyclooctene (eco) afforded…”
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Holmium Atoms and Small Clusters in Inert Matrices
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (19-06-1997)“…The UV−vis spectra of holmium atoms isolated in argon and krypton matrices at 9 K have been studied in the 200−800 nm region. By comparison with gas phase data…”
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The Very Low Barrier of CO Site Exchange in Tricarbonyl(η4-1,5-cyclooctadiene)iron: Picosecond Kinetics in Solution Investigated by Line Shape Simulation of the ν(CO) IR Bands and Complementary Evidence from the Course of 13CO Incorporation in a Low-Temperature Matrix
Published in Journal of the American Chemical Society (14-10-1998)“…Photochemical experiments with Fe(CO)3(η4-1,5-cyclooctadiene) (1) in a 13CO matrix at 10 K, monitored by means of IR spectroscopy, indicate the generation of…”
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Metal atom-metal cluster chemistry. 1. Alkane matrices
Published in Inorganic chemistry (01-12-1977)Get full text
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Photochemistry of (η6-2,6-X2C5H3N)Cr(CO)3 (X = H, CH3, (CH3)3Si). First Example of a Photoinduced Ring-Slip at an (η6-Arene)M(CO)3 Center. Molecular Structures of (η6-2,6-(CH3)2C5H3N)Cr(CO)3 and (η6-2,6-((CH3)3Si)2C5H3N)Cr(CO)3
Published in Organometallics (20-08-1996)“…The photochemistry of (η6-2,6-X2C5H3N)Cr(CO)3 was investigated both in low-temperature matrices (X = H or (CH3)3Si) and in room-temperature solution (X = H,…”
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The Very Low Barrier of CO Site Exchange in Tricarbonyl(η 4 -1,5-cyclooctadiene)iron: Picosecond Kinetics in Solution Investigated by Line Shape Simulation of the ν(CO) IR Bands and Complementary Evidence from the Course of 13 CO Incorporation in a Low-Temperature Matrix
Published in Journal of the American Chemical Society (01-10-1998)Get full text
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Photochemistry of (η 6 -2,6-X 2 C 5 H 3 N)Cr(CO) 3 (X = H, CH 3 , (CH 3 ) 3 Si). First Example of a Photoinduced Ring-Slip at an (η 6 -Arene)M(CO) 3 Center. Molecular Structures of (η 6 -2,6-(CH 3 ) 2 C 5 H 3 N)Cr(CO) 3 and (η 6 -2,6-((CH 3 ) 3 Si) 2 C 5 H 3 N)Cr(CO) 3
Published in Organometallics (20-08-1996)Get full text
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Intermediates in the time-resolved and matrix photochemistry of (.eta.5-cyclopentadienyl)rhodium complexes. Roles of alkane activation and rhodium-rhodium bond formation
Published in Journal of the American Chemical Society (01-10-1989)“…Pulsed laser photolysis studies of solutions of Cp{sub 2}Rh{sub 2}(CO){sub 3}, CpRh(CO){sub 2}, and CpRh(C{sub 2}H{sub 4})CO (Cp = {eta}{sup 5}-C{sub 5}H{sub…”
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Photochemical cleavage and recombination of matrix-isolated (1-.sigma.-4-6-.eta.3-organo)tricarbonyliron complexes
Published in Inorganic chemistry (01-09-1981)Get full text
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Generation of Re2(CO)9(N2) from Re2(CO)10: identification of photochemical intermediates by matrix isolation and liquid-noble-gas techniques
Published in Inorganic chemistry (07-10-1987)Get full text
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Bimetal atom chemistry. 2. Selective bimetallic photoaggregation of silver and chromium atoms to very small clusters, CrnAgm
Published in Inorganic chemistry (01-08-1979)Get full text
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Photoreactions of group 6 metal carbonyls with olefins
Published in Pure and applied chemistry (01-01-1988)“…Abstract…”
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