Search Results - "Kloth, Marc"

N-heterocyclic carbene coordinated gallanes and chlorogallanes by Cole, Marcus L., Furfari, Samantha K., Kloth, Marc

“…Four N-heterocyclic carbene coordinated gallanes and chlorogallanes are reported that represent some of the most thermally stable molecular gallium hydrides…”
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Synthesis of Molecular Vanadium(III) Phosphonates by Khanra, Sumit, Kloth, Marc, Mansaray, Hassanatu, Muryn, Christopher A., Tuna, Floriana, Sañudo, E. Carolina, Helliwell, Madeleine, McInnes, Eric J. L., Winpenny, Richard E. P.

“…All in the family: Organophosphonate complexes of high‐valent vanadium are common, but their VIII analogues are few and far between. Reaction of VCl3…”
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Bulky amidinato complexes and amidine adducts of Al, Ga and In halides by Jones, Cameron, Junk, Peter C., Kloth, Marc, Proctor, Kathryn M., Stasch, Andreas

“…The reactions of several bulky amidinate salts with group 13 metal(I), (II) and (III) halides have been carried out. These have led to a variety of…”
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Synthesis and Characterization of Thermally Robust Amidinato Group 13 Hydride Complexes by Cole, Marcus L., Jones, Cameron, Junk, Peter C., Kloth, Marc, Stasch, Andreas

“…The reactivity of two sterically bulky amidines, ArNC(R)N(H)Ar (Ar=2,6‐diisopropylphenyl; R=H (HFiso); tBu, (HPiso)) towards LiMH4, M=Al or Ga, [AlH3(NMe3)],…”
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Synthesis and Structural Characterization of Thermally Stable Group 13 Hydride Complexes Derived from a Gallium(I) Carbene Analogue by Baker, Robert J., Jones, Cameron, Kloth, Marc, Platts, Jamie A.

“…The first covalently bonded metal complexes derived from an anionic gallium carbene analogue (see picture) show remarkable thermal stability in the solid…”
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An EPR and ENDOR Investigation of a Series of Diazabutadiene-Group 13 Complexes by Baker, Robert J., Farley, Robert D., Jones, Cameron, Mills, David P., Kloth, Marc, Murphy, Damien M.

“…Paramagnetic diazabutadienegallium(II or III) complexes, [(Ar‐DAB)2Ga] and [{(Ar‐DAB.)GaX}2] (X=Br or I; Ar‐DAB={N(Ar)C(H)}2, Ar=2,6‐diisopropylphenyl), have…”
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Structural and spectroscopic studies of carbene and N-donor ligand complexes of Group 13 hydrides and halides by Baker, Robert J, Davies, Aaron J, Jones, Cameron, Kloth, Marc

“…The syntheses of two Group 13 complexes of the sterically demanding carbene, 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene, (IPr), are reported, vis. [MX…”
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Oxidative Coupling of an Anionic Gallium(I) Carbene Analogue:  Synthesis and Structural Characterization of an Unprecedented π-Cyclopentadienyl-Bridged Digallane Complex by Baker, Robert J, Jones, Cameron, Kloth, Marc, Platts, Jamie A

“…An unprecedented π-cyclopentadienyl-bridged digallane complex, [{Ga[N(Ar)C(H)]2}2{μ-CpK(tmeda)2}] (Ar = C6H3Pri 2-2,6), incorporating the first structurally…”
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Kinetic Control over the Thermal Stability of the InH Bond: Synthesis and Characterization of Amido Indium Hydride Complexes by Baker, Robert J., Jones, Cameron, Junk, Peter C., Kloth, Marc

“…High thermal stability is a characteristic feature of the depicted amido indium hydride complex (In red; hydride yellow), which is amongst the first to be…”
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Controlled Decomposition of an Indium Trihydride Adduct:  Synthesis and Characterization of the First Mixed-Oxidation-State Indium Sub-halide Complex Anion, [In5Br8(quinuclidine)4] by Cole, Marcus L, Jones, Cameron, Kloth, Marc

“…The first example of a compound containing a mixed-oxidation-state indium sub-halide complex anion, [In5Br8(quinuclidine)4]-, has been accessed by the…”
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X-ray Structural Characterization of Diethyl Ether Solvated Lithium Iodide Derived from a Metathesis Reaction by Brym, Markus, Jones, Cameron, Junk, Peter C., Kloth, Marc

“…[LiI(Et2O)]4 was isolated from the reaction mixture following the reaction of [Li(FIso)(Et2O)n] (HFIso = N,N′‐di(2,6‐diisopropylphenyl)formamidine) with GaI…”
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X-ray structural characterization of some sterically bulky N-donor and N-alkyl Grignard reagents by Andrews, Philip C., Brym, Markus, Jones, Cameron, Junk, Peter C., Kloth, Marc

“…X-ray crystal structures of [MgBr 2(thf) 3] and [FisoMg(thf)Cl] 2, (Fiso − = [ArNC(H)NAr] −, Ar = C 6 H 3 Pr 2 i - 2 , 6 ), [2-PyC(SiMe 3) 2Mg(thf)Cl] 2,…”
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Studies of low oxidation state group 13 halide, hydride and heterocyclic complexes by Kloth, Marc

“…The work presented in this thesis describes the synthesis, structure and stability of a range of halido, hydrido and heterocyclic complexes of the group 13…”
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Kinetic Control over the Thermal Stability of the InH Bond: Synthesis and Characterization of Amido Indium Hydride Complexes by Baker, Robert J., Jones, Cameron, Junk, Peter C., Kloth, Marc

“…Hohe thermische Stabilität zeichnet den abgebildeten Amidoindiumhydrid‐Komplex (In rot, Hydrid gelb) aus, der zu den ersten derartigen Komplexen zählt, die…”
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Synthesis of Molecular Vanadium(III) Phosphonates by Khanra, Sumit, Kloth, Marc, Mansaray, Hassanatu, Muryn, Christopher A., Tuna, Floriana, Sañudo, E. Carolina, Helliwell, Madeleine, McInnes, Eric J. L., Winpenny, Richard E. P.

“…Eine ganze Familie: Organophosphonatkomplexe des Vanadiums in hoher Oxidationsstufe sind verbreitet, ihre VIII‐Analoga sind dagegen äußerst dünn gesäht. Aus…”
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Synthesis and Structural Characterization of Thermally Stable Group 13 Hydride Complexes Derived from a Gallium(I) Carbene Analogue by Baker, Robert J., Jones, Cameron, Kloth, Marc, Platts, Jamie A.

“…Anionische Gallium‐Carben‐Analoga binden kovalent an Gallium(III)‐ und Indium(III)‐Einheiten (siehe Bild). Die bemerkenswerte Temperaturbeständigkeit der…”
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Synthesis of Molecular Vanadium(III) Phosphonates by Khanra, Sumit, Kloth, Marc, Mansaray, Hassanatu, Muryn, Christopher A., Tuna, Floriana, Sañudo, E. Carolina, Helliwell, Madeleine, McInnes, Eric J. L., Winpenny, Richard E. P.

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