Novel synthetic route to fluorofullerenes: reaction with binary and complex lead fluorides

We have recently developed methods of preparation of fluorofullerenes with specific fluorine content. Our previous successful synthesis of C 60F 36 and C 60F 18 with the use of transition metal fluorides inspired us to probe other high oxidation metal fluorides. In this work we report on the use of...

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Bibliographic Details
Published in:	Journal of fluorine chemistry Vol. 110; no. 2; pp. 157 - 163
Main Authors:	Troshin, P.A, Boltalina, O.V, Polyakova, N.V, Klinkina, Z.E
Format:	Journal Article
Language:	English
Published:	Elsevier B.V 2001
Subjects:	Fluorination Fluorofullerene Fullerene Lead fluorides Preparation Fullerene Fluorofullerene Fluorination Lead fluorides Preparation
Online Access:	Get full text
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Summary:	We have recently developed methods of preparation of fluorofullerenes with specific fluorine content. Our previous successful synthesis of C 60F 36 and C 60F 18 with the use of transition metal fluorides inspired us to probe other high oxidation metal fluorides. In this work we report on the use of the binary lead fluorides (PbF 2, PbF 4, Pb 2F 6) and their complexes with alkali metal and alkaline earth metal fluorides (M 2PbF 6, M 3PbF 7 and M′PbF 6) as fluorinating reagents for fullerenes.
ISSN:	0022-1139 1873-3328
DOI:	10.1016/S0022-1139(01)00424-9