Search Results - "Kjaergaard, H."
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Isoprene photooxidation: new insights into the production of acids and organic nitrates
Published in Atmospheric chemistry and physics (01-01-2009)“…We describe a nearly explicit chemical mechanism for isoprene photooxidation guided by chamber studies that include time-resolved observation of an extensive…”
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Nonclinical Characterization of the Hypoxia-Inducible Factor Prolyl Hydroxylase Inhibitor Roxadustat, a Novel Treatment of Anemia of Chronic Kidney Disease
Published in The Journal of pharmacology and experimental therapeutics (01-08-2020)“…Anemia of chronic kidney disease (CKD) is a multifactorial disorder caused by impaired erythropoietin (EPO) production and altered iron homeostasis associated…”
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3
Bilirubin oxidase from Magnaporthe oryzae: an attractive new enzyme for biotechnological applications
Published in Applied microbiology and biotechnology (01-12-2012)“…A novel bilirubin oxidase (BOD), from the rice blast fungus Magnaporthe oryzae , has been identified and isolated. The 64-kDa protein containing four coppers…”
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4
Two-Electron Reduction versus One-Electron Oxidation of the Type 3 Pair in the Multicopper Oxidases
Published in Journal of the American Chemical Society (15-07-2015)“…Multicopper oxidases (MCOs) utilize an electron shuttling Type 1 Cu (T1) site in conjunction with a mononuclear Type 2 (T2) and a binuclear Type 3 (T3) site,…”
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5
Mechanism of Chloride Inhibition of Bilirubin Oxidases and Its Dependence on Potential and pH
Published in ACS catalysis (02-06-2017)“…Bilirubin oxidases (BODs) belong to the multicopper oxidase (MCO) family and efficiently reduce O2 at neutral pH and under physiological conditions where…”
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Spectroscopic and Crystallographic Characterization of “Alternative Resting” and “Resting Oxidized” Enzyme Forms of Bilirubin Oxidase: Implications for Activity and Electrochemical Behavior of Multicopper Oxidases
Published in Journal of the American Chemical Society (28-03-2012)“…While there is broad agreement on the catalytic mechanism of multicopper oxidases (MCOs), the geometric and electronic structures of the resting trinuclear Cu…”
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7
Peroxy radical chemistry and OH radical production during the NO3-initiated oxidation of isoprene
Published in Atmospheric chemistry and physics (15-08-2012)“…Peroxy radical reactions (RO2 + RO2 ) from the NO3 -initiated oxidation of isoprene are studied with both gas chromatography and a chemical ionization mass…”
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8
Enzymatic versus Inorganic Oxygen Reduction Catalysts: Comparison of the Energy Levels in a Free-Energy Scheme
Published in Inorganic chemistry (19-04-2010)“…In this paper, we present a method to directly compare the energy levels of intermediates in enzymatic and inorganic oxygen reduction catalysts. We initially…”
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9
Photolysis of Sulfuric Acid Vapor by Visible Solar Radiation
Published in Science (American Association for the Advancement of Science) (07-03-2003)“…Atmospheric field measurements and models of the stratospheric sulfate aerosol layer led to the suggestion that sulfuric acid (H2SO4) must photolyze at high…”
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10
Chemical properties of HULIS from three different environments
Published in Journal of atmospheric chemistry (01-03-2015)“…Humic-like substances (HULIS) comprise a significant fraction of the organic compounds in aerosol particles. In the present study we report the chemical…”
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11
Transfer to hospital in planned home births: a systematic review
Published in BMC pregnancy and childbirth (29-05-2014)“…Doc number: 179 Abstract Background: There is concern about the safety of homebirths, especially in women transferred to hospital during or after labour. The…”
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First‐trimester Down syndrome screening: pregnant women's knowledge
Published in Ultrasound in obstetrics & gynecology (01-08-2011)“…Objectives The primary aim of this study was to assess pregnant women's knowledge of first‐trimester combined Down syndrome screening in a setting of required…”
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Theoretical study, and infrared and Raman spectra of copper(II) chelated complex with dibenzoylmethane
Published in Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy (15-07-2014)“…[Display omitted] •Electron delocalization between Ph and chelated rings of Cu(dbm)2 is confirmed.•M–L bond strength in target complexes are theoretically and…”
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Praxis and guidelines for planned homebirths in the Nordic countries – An overview
Published in Sexual & reproductive healthcare (01-03-2014)“…Abstract Objective The objective of this overview was to investigate the current situation regarding guidelines and praxis for planned homebirths and also to…”
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Emergency caesarean section in low risk nulliparous women
Published in Journal of obstetrics and gynaecology (01-08-2012)“…The rising incidence of caesarean section (CS), including emergency caesarean section (ECS) in nulliparas is of concern. Previous CS may have implications for…”
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16
Copper Active Sites in Biology
Published in Chemical reviews (09-04-2014)“…Solomon et al present information on the electronic structure and spectroscopy of copper active sites in biology, including mononuclear Cu(II) sites, binuclear…”
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Risk indicators for dystocia in low-risk nulliparous women: A study on lifestyle and anthropometrical factors
Published in Journal of obstetrics and gynaecology (01-01-2010)“…We examined background information and course of labour from a cohort of 2,810 low-risk nulliparas to identify possible lifestyle and anthropometrical risk…”
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18
Spectroscopic and computational insight into the activation of O₂ by the mononuclear Cu center in polysaccharide monooxygenases
Published in Proceedings of the National Academy of Sciences - PNAS (17-06-2014)“…Strategies for O ₂ activation by copper enzymes were recently expanded to include mononuclear Cu sites, with the discovery of the copper-dependent…”
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Mechanism of the Reduction of the Native Intermediate in the Multicopper Oxidases: Insights into Rapid Intramolecular Electron Transfer in Turnover
Published in Journal of the American Chemical Society (24-12-2014)“…The multicopper oxidases (MCOs) are the family of enzymes that catalyze the 4-electron reduction of O2 to H2O coupled to the four 1-electron oxidations of…”
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20
Molecular Origin of Rapid versus Slow Intramolecular Electron Transfer in the Catalytic Cycle of the Multicopper Oxidases
Published in Journal of the American Chemical Society (21-08-2013)“…Kinetic measurements on single-turnover processes in laccase established fast type-1 Cu to trinuclear Cu cluster (TNC) intramolecular electron transfer (IET)…”
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