Search Results - "Kissin, Yury V"
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CHEMICAL MECHANISMS OF CATALYTIC CRACKING OVER SOLID ACIDIC CATALYSTS: ALKANES AND ALKENES
Published in Catalysis reviews. Science and engineering (31-05-2001)“…The review discusses chemical mechanisms of most important reactions that take place in the course of catalytic cracking of alkenes and alkanes over solid…”
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2
Mechanism of Alkane Transfer-Dehydrogenation Catalyzed by a Pincer-Ligated Iridium Complex
Published in Journal of the American Chemical Society (02-07-2003)“…The mechanism of (PCP)Ir-catalyzed transfer−dehydrogenation has been elucidated for the prototypical substrate/acceptor couple, COA/TBE, at 55 °C (COA =…”
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3
Analysis of polyolefins and olefin copolymers using Crystaf technique: Resolution of Crystaf curves
Published in Journal of applied polymer science (15-12-2007)“…An experimental technique, crystallization analysis fractionation (Crystaf), is used to analyze compositional uniformity of ethylene/α‐olefin copolymers and…”
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4
Active centers in Ziegler–Natta catalysts: Formation kinetics and structure
Published in Journal of catalysis (01-08-2012)“…[Display omitted] ► Kinetics of ethylene polymerization with Ziegler–Natta catalysts is studied. ► Temperature, 1-alkenes, H2 and IITi species affect the rate…”
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The role of alkoxysilanes in propylene polymerization catalysis. A study of model Ti(Oi‐C3H7)4‐Al(C2H5)2Cl/Mg(C4H9)2 catalyst system
Published in Polymer international (01-07-2023)“…The article describes the modifying effect of methylcyclohexyldimethoxysilane (CH3)(cyclo‐C6H11)Si(OCH3)2 in propylene polymerization reactions with a…”
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6
Alkene polymerization reactions with catalysts based on acetylacetonate complexes of vanadium and titanium: effect of cocatalyst
Published in Polymer international (01-03-2022)“…Alkene polymerization reactions were studied with three catalyst systems containing complexes of vanadium and titanium with the acetylacetonate ligand…”
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Active centers in propylene polymerization catalysts of the fourth generation
Published in Journal of catalysis (01-12-2015)“…[Display omitted] •Isospecific centers in propylene polymerization catalysts are nonuniform.•Populations of active centers differ in kinetic parameters and in…”
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Ethylene polymerization and copolymerization reactions with Ti(OR)4 – Al2(C2H5)3Cl3/Mg(C4H9)2 catalyst
Published in Polymer international (01-12-2020)“…The ternary Ti(Oiso‐C3H7)4–Al2(C2H5)3Cl3/Mg(C4H9)2 catalyst polymerizes ethylene and copolymerizes it with 1‐hexene but does not polymerize propylene. The…”
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An Alternative Route to Methylalumoxane: Synthesis, Structure, and the Use of Model Methylalumoxanes as Cocatalysts for Transition Metal Complexes in Polymerization Reactions
Published in Macromolecules (14-01-2003)“…Methylalumoxane (MAO) is commonly produced by controlled hydrolysis of AlMe3; it is widely used as a cocatalyst for metallocene complexes and complexes of late…”
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The second life of Ziegler catalyst. Ethylene polymerization reactions with TiCl4–Al[C2H5]2Cl/Mg(C4H9)2 catalyst
Published in Journal of applied polymer science (20-04-2019)“…ABSTRACT The Ziegler catalyst, a combination of TiCl4 and Al(C2H5)2Cl, was widely used since 1950s for the commercial manufacture of linear polyethylene. We…”
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11
Modeling differential scanning calorimetry melting curves of ethylene/α‐olefin copolymers
Published in Journal of polymer science. Part B, Polymer physics (01-02-2011)“…A procedure is developed for modeling differential scanning calorimetry (DSC) melting curves of linear polyethylene and ethylene/α‐olefin copolymers produced…”
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Synthesis of atactic polypropylene: Propylene polymerization reactions with TiCl4–Al(C2H5)2Cl/Mg(C4H9)2 catalyst
Published in Journal of applied polymer science (05-07-2019)“…ABSTRACT The Ziegler catalyst, a combination of TiCl4 and Al(C2H5)2Cl, is a very poor catalyst for propylene polymerization. However, the addition of Mg(C4H9)2…”
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13
Peculiarities of Ethylene Polymerization Reactions with Bis(imino)pyridyl Complexes of CoCl2 and FeCl2
Published in Chinese journal of polymer science (01-04-2024)“…The article describes ethylene polymerization reactions with transition metal catalysts based on complexes of CoCl 2 and FeCl 2 with an N,N,N -tridentate…”
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14
A New Cocatalyst for Metallocene Complexes in Olefin Polymerization
Published in Macromolecules (13-06-2000)“…Activation of metallocene complexes for olefin polymerization reactions can only be achieved by a relatively short list of special cocatalysts: dialkylaluminum…”
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15
Elmendorf Tear Test of Polyethylene Films: Mechanical Interpretation and Model
Published in Macromolecular materials and engineering (15-08-2011)“…A physical model of one of the principal end‐use tests of film manufactured from linear low‐density and low‐density PE resins, the Elmendorf tear test (ASTM…”
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Polymers of propylene and higher 1-alkenes produced with post-metallocene complexes containing a saligenin-type ligand
Published in Polymer (Guilford) (14-11-2013)“…Polymerization reactions of propylene and three higher linear 1-alkenes, 1-hexene, 1-octene and 1-decene, were carried out with post-metallocene catalysts…”
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Detailed Kinetics of 1-Hexene Oligomerization Reaction with (n-Bu-Cp)2ZrCl2-MAO Catalyst
Published in Macromolecular chemistry and physics (06-08-2009)“…The paper describes a kinetic study of 1‐hexene oligomerization reaction with the (n‐Bu‐Cp)2ZrCl2–MAO catalyst system at 70 °C. GC analysis of the…”
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Post-oligomerization of α-olefin oligomers: A route to single-component and multicomponent synthetic lubricating oils
Published in Journal of applied polymer science (05-01-2009)“…This article describes a synthetic route to single-component and multicomponent base stocks for synthetic lubricated oils. The synthesis was carried out in two…”
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Ziegler-Natta catalysts for propylene polymerization: Chemistry of reactions leading to the formation of active centers
Published in Journal of molecular catalysis. A, Chemical (15-05-2008)“…The article describes chemical reactions between a fourth-generation solid Ziegler-Natta catalyst for propylene polymerization, TiCl 4/MgCl 2/diisobutyl…”
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A new post-metallocene catalyst for alkene polymerization: copolymerization of ethylene and 1-hexene with titanium complexes bearing N,N-dialkylcarbamato ligands
Published in Polymer international (01-03-2014)“…New catatytic systems based on N,N‐dialkylcarbamato Ti(IV) precursors for copolymerization of ethylene and 1‐hexene are presented. High 1‐hexene content in the…”
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