Silyl Migration in Conjunction with Substitution on Silicon in Copper(I) t-Butoxide-promoted Coupling between o-Silylphenyl Ketones and Organic Halides

(Z)-Di-t-butoxymethylsilyl enol ethers were stereoselectively produced by the copper(I) t-butoxide-promoted cross-coupling of o-(dimethylphenylsilyl)phenyl ketones with organic halides. The reaction proceeds via the formation of arylcopper species generated by silyl migration to enolate oxygen, acco...

Full description

Bibliographic Details

Published in:	Chemistry letters Vol. 38; no. 12; pp. 1180 - 1181
Main Authors:	Tsubouchi, Akira, Matsuda, Hiroko, Kira, Takashiro, Takeda, Takeshi
Format:	Journal Article
Language:	English
Published:	Tokyo The Chemical Society of Japan 05-12-2009 Chemical Society of Japan
Online Access:	Get full text
Tags:	Add Tag No Tags, Be the first to tag this record!