Synthesis and Structure of Tetraphenylantimony Methacrylate and Tetraphenylantimony Crotonate and Their Use for the Production of Antimony-Containing Polystyrene

Tetraphenylantimony methacrylate Ph 4 SbO 2 CC(CH 3 )=CH 2 and tetraphenylantimony crotonate Ph 4 SbO 2 CCH=CHCH 3 were synthesized by the action of acids on Ph 5 Sb or on Ph 4 SbBr in the presence of Et 2 NH. According to X-ray diffraction analysis data, both compounds are antimony complexes with d...

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Bibliographic Details
Published in:	Russian journal of general chemistry Vol. 91; no. 2; pp. 227 - 234
Main Authors:	Gushchin, A. V., Maleeva, A. I., Kipelkin, E. V., Tumanyan, A. S., Andreev, P. V., Ovsetsina, T. I., Somov, N. V.
Format:	Journal Article
Language:	English
Published:	Moscow Pleiades Publishing 01-02-2021 Springer
Subjects:	Acrylates Chemistry Chemistry and Materials Science Chemistry/Food Science Polymerization Polystyrene antimony-containing polystyrene tetraphenylantimony methacrylate tetraphenylantimony crotonate
Online Access:	Get full text
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Summary:	Tetraphenylantimony methacrylate Ph 4 SbO 2 CC(CH 3 )=CH 2 and tetraphenylantimony crotonate Ph 4 SbO 2 CCH=CHCH 3 were synthesized by the action of acids on Ph 5 Sb or on Ph 4 SbBr in the presence of Et 2 NH. According to X-ray diffraction analysis data, both compounds are antimony complexes with distorted tetragonal-pyramidal geometry. Polymerization of styrene with Ph 4 SbO 2 CC(CH 3 )=CH 2 and Ph 4 SbO 2 CCH=CHCH 3 additives gave transparent antimony-containing polystyrene soluble in chloroform, dichloromethane, and THF.
ISSN:	1070-3632 1608-3350
DOI:	10.1134/S1070363221020110