Thermal stability of alkyl carbonate mixed-solvent electrolytes for lithium ion cells

Thermal stability of alkyl carbonate mixed-solvent electrolytes for lithium ion cells

The thermal stability of some mixed-solvent electrolytes used in lithium cells was measured by differential scanning calorimetry (DSC) using airtight containers. The electrolytes used were ethylene carbonate ( EC)+ diethyl carbonate ( DEC) , EC+ dimethyl carbonate ( DMC) , propylene carbonate (PC)+D...

Full description

Saved in:
Bibliographic Details
Published in:Journal of power sources Vol. 104; no. 2; pp. 260 - 264
Main Authors: Kawamura, Tetsuya, Kimura, Arihisa, Egashira, Minato, Okada, Shigeto, Yamaki, Jun-Ichi
Format: Journal Article
Language:English
Published: Lausanne Elsevier B.V 15-02-2002
Elsevier Sequoia
Subjects:
Applied sciences
Direct energy conversion and energy accumulation
Electrical engineering. Electrical power engineering
Electrical power engineering
Electrochemical conversion: primary and secondary batteries, fuel cells
Electrolyte
Exact sciences and technology
Lithium ion cell
Lithium metal
Safety
Thermal stability
Water
Water
Lithium metal
Lithium ion cell
Safety
Electrolyte
Thermal stability
Differential scanning calorimetry
Mixed solvent
Organic carbonate
Thermal behavior
Secondary cell
Lithium ion
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:The thermal stability of some mixed-solvent electrolytes used in lithium cells was measured by differential scanning calorimetry (DSC) using airtight containers. The electrolytes used were ethylene carbonate ( EC)+ diethyl carbonate ( DEC) , EC+ dimethyl carbonate ( DMC) , propylene carbonate (PC)+DEC, and PC+DMC in which was dissolved 1 M LiPF 6 or 1 M LiClO 4. The influence of water addition and lithium metal addition on the thermal behavior of these electrolytes was also investigated. The exothermic peak of LiPF 6 electrolytes containing DEC was found at 255 °C, and the peak temperature of the electrolytes containing DEC was 15–20 °C lower than that of LiPF 6 electrolytes containing DMC. This effect was also observed in the electrolytes including LiClO 4. DMC was found to be more reactive than DEC. The thermal behavior of various kinds of LiPF 6 electrolytes with lithium metal was measured by DSC. The exothermic reaction of 1 M LiPF 6/EC+DEC, 1 M LiPF 6/EC+DMC, and 1 M LiPF 6/PC+DMC with lithium metal began at the melting point of lithium metal because of the break down of the solid electrolyte interface (SEI). The temperature was approximately 180 °C, whereas the self-heating of 1 M LiPF 6/PC+DEC occurred before the melting point of lithium metal. The temperature at which the self-exothermal reaction began was 140 °C. Therefore, the lithium metal in this electrolyte was found to be thermally unstable. When water was added to the above electrolytes with lithium metal, the exothermic reaction began at less than 130 °C, probably due to a collapse of SEI in response to the HF that was a product of the reaction between LiPF 6 and the added water.
Bibliography:ObjectType-Article-2
SourceType-Scholarly Journals-1
ObjectType-Feature-1
content type line 23
ISSN:0378-7753
1873-2755
DOI:10.1016/S0378-7753(01)00960-0