Search Results - "Khvoinova, Natalie M."

Divalent Germanium Compound with a Radical-Anionic Ligand:  Molecular Structures of (dpp-BIAN)•-GeCl and Its Hydrochloration Products [(dpp-BIAN)(H)2]•+[GeCl3]- and [{(dpp-BIAN)(H)2 •+}2(Cl-)]+[GeCl3]- (dpp-BIAN = 1,2-Bis{(2,6-diisopropylphenyl)imino}acenaphthene) by Fedushkin, Igor L, Khvoinova, Natalie M, Baurin, Andrey Yu, Fukin, Georgii K, Cherkasov, Vladimir K, Bubnov, Mikhail P

“…The germanium(II) compound (dpp-BIAN)GeCl (1), which contains the radical anion of dpp-BIAN can be prepared either by reacting free dpp-BIAN ligand with 2…”
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Monomeric Magnesium and Calcium Complexes containing the Rigid, Dianionic 1, 2-Bis[(2, 5-di-tert-butylphenyl)imino]acenaphthene (dtb-BIAN) and 1, 2-Bis[(2-biphenyl)imino]acenaphthene (bph-BIAN) Ligands by Fedushkin, Igor L., Chudakova, Valentina A., Skatova, Alexandra A., Khvoinova, Natalie M., Kurskii, Yuri A., Glukhova, Tatyana A., Fukin, Georgy K., Dechert, Sebastian, Hummert, Markus, Schumann, Herbert

“…The new rigid bidentate nitrogen ligands 1, 2‐bis[(2, 5‐di‐tert‐butylphenyl)imino]acenaphthene (1) (dtb‐BIAN) and 1, 2‐bis[(2‐biphenyl)imino]acenaphthene (2)…”
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Stable Germylenes Derived from 1,2-Bis(arylimino)acenaphthenes by Fedushkin, Igor L, Skatova, Alexandra A, Chudakova, Valentina A, Khvoinova, Natalie M, Baurin, Andrey Yu, Dechert, Sebastian, Hummert, Markus, Schumann, Herbert

“…Metal exchange reactions of the magnesium complexes (dpp-BIAN)Mg(THF) n , (dtb-BIAN)Mg(THF) n , and (bph-BIAN)Mg(THF) n with GeCl2(dioxane) afford the stable…”
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Oxidative Addition of Phenylacetylene through CH Bond Cleavage To Form the Mg II –dpp‐bian Complex: Molecular Structure of [Mg{dpp‐bian(H)}(CCPh)(thf) 2 ] and Its Diphenylketone Insertion Product [Mg(dpp‐bian) . − {OC(Ph 2 )CCPh}(thf)] by Fedushkin, Igor L., Khvoinova, Natalie M., Skatova, Alexandra A., Fukin, Georgy K.

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Oxidative addition of phenylacetylene through C-H bond cleavage to form the MgII-dpp-bian complex: molecular structure of [Mg[dpp-bian(H)](C[triplebond]CPh)(thf)2] and its diphenylketone insertion product [Mg(dpp-bian)-[OC(Ph2)C[triplebond]CPh](thf)] by Fedushkin, Igor L, Khvoinova, Natalie M, Skatova, Alexandra A, Fukin, Georgy K

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Oxidative Addition of Phenylacetylene through CH Bond Cleavage To Form the MgII-dpp-bian Complex: Molecular Structure of [Mg{dpp-bian(H)}(CCPh)(thf)2] and Its Diphenylketone Insertion Product [Mg(dpp-bian).−{OC(Ph2)CCPh}(thf)] by Fedushkin, Igor L., Khvoinova, Natalie M., Skatova, Alexandra A., Fukin, Georgy K.

“…The use of a rigid bidentate ligand allows oxidative addition of an acetylene derivative to a non‐transition‐metal complex, not through oxidation of the metal…”
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Divalent germanium compound with a radical-anionic ligand: molecular structures of (dpp-BIAN)- GeCl and its hydrochloration products [(dpp-BIAN)(H)2]+ [GeCl3]- and [[(dpp-BIAN)(H)2+]2(Cl-)]+ [GeCl3]- (dpp-BIAN=1,2-Bis[(2,6-diisopropylphenyl)imino]acenaphthene) by Fedushkin, Igor L, Khvoinova, Natalie M, Baurin, Andrey Yu, Fukin, Georgii K, Cherkasov, Vladimir K, Bubnov, Mikhail P

“…The germanium(II) compound (dpp-BIAN)GeCl (1), which contains the radical anion of dpp-BIAN can be prepared either by reacting free dpp-BIAN ligand with 2…”
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Oxidative Addition of Phenylacetylene through CH Bond Cleavage To Form the Mg II –dpp‐bian Complex: Molecular Structure of [Mg{dpp‐bian(H)}(CCPh)(thf) 2 ] and Its Diphenylketone Insertion Product [Mg(dpp‐bian) . − {OC(Ph 2 )CCPh}(thf)] by Fedushkin, Igor L., Khvoinova, Natalie M., Skatova, Alexandra A., Fukin, Georgy K.

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Oxidative Addition of Phenylacetylene through CH Bond Cleavage To Form the MgII-dpp-bian Complex: Molecular Structure of [Mg{dpp-bian(H)}(CCPh)(thf)2] and Its Diphenylketone Insertion Product [Mg(dpp-bian).−{OC(Ph2)CCPh}(thf)] by Fedushkin, Igor L., Khvoinova, Natalie M., Skatova, Alexandra A., Fukin, Georgy K.

“…Ein starrer zweizähniger Ligand ermöglicht die oxidative Addition eines Alkins an einen Hauptgruppenmetallkomplex. Hierbei wird nicht das Magnesiumzentrum…”
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