Search Results - "Khan, M. Anwar"
-
1
Direct kinetic measurements and theoretical predictions of an isoprene-derived Criegee intermediate
Published in Proceedings of the National Academy of Sciences - PNAS (05-05-2020)“…Isoprene has the highest emission into Earth’s atmosphere of any nonmethane hydrocarbon. Atmospheric processing of alkenes, including isoprene, via ozonolysis…”
Get full text
Journal Article -
2
Emissions and Marine Boundary Layer Concentrations of Unregulated Chlorocarbons Measured at Cape Point, South Africa
Published in Environmental science & technology (01-09-2020)“…Unregulated chlorocarbons, here defined as dichloromethane (CH2Cl2), perchloroethene (C2Cl4), chloroform (CHCl3), and methyl chloride (CH3Cl), are gases not…”
Get full text
Journal Article -
3
Experimental Evidence of Dioxole Unimolecular Decay Pathway for Isoprene-Derived Criegee Intermediates
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (07-05-2020)“…Ozonolysis of isoprene, one of the most abundant volatile organic compounds emitted into the Earth’s atmosphere, generates two four-carbon unsaturated Criegee…”
Get full text
Journal Article -
4
Direct Measurements of Unimolecular and Bimolecular Reaction Kinetics of the Criegee Intermediate (CH3)2COO
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (12-01-2017)“…The Criegee intermediate acetone oxide, (CH3)2COO, is formed by laser photolysis of 2,2-diiodopropane in the presence of O2 and characterized by synchrotron…”
Get full text
Journal Article -
5
Do diverse wheat genotypes unleash their biochemical arsenal differentially to conquer cold stress? A comprehensive study in the Western Himalayas
Published in Physiologia plantarum (01-11-2023)“…Wheat is one of the most important cereal crops in the world. Cold stress is a major constraint in production of wheat grown in cold climate regions. In this…”
Get full text
Journal Article -
6
Aerosol mass and size-resolved metal content in urban Bangkok, Thailand
Published in Environmental science and pollution research international (01-11-2022)“…Inhalable particulate matter (PM) is a health concern, and people living in large cities such as Bangkok are exposed to high concentrations. This exposure has…”
Get full text
Journal Article -
7
Reaction of Perfluorooctanoic Acid with Criegee Intermediates and Implications for the Atmospheric Fate of Perfluorocarboxylic Acids
Published in Environmental science & technology (05-02-2019)“…The reaction of perfluorooctanoic acid with the smallest carbonyl oxide Criegee intermediate, CH2OO, has been measured and is very rapid, with a rate…”
Get full text
Journal Article -
8
Particle Number Concentration Measurements on Public Transport in Bangkok, Thailand
Published in International journal of environmental research and public health (29-03-2023)“…Traffic is a major source of particulate pollution in large cities, and particulate matter (PM) level in Bangkok often exceeds the World Health Organisation…”
Get full text
Journal Article -
9
Airborne observations over the North Atlantic Ocean reveal the importance of gas-phase urea in the atmosphere
Published in Proceedings of the National Academy of Sciences - PNAS (20-06-2023)“…Reduced nitrogen (N) is central to global biogeochemistry, yet there are large uncertainties surrounding its sources and rate of cycling. Here, we present…”
Get full text
Journal Article -
10
Investigation of Biofuel as a Potential Renewable Energy Source
Published in Atmosphere (01-10-2021)“…An accelerating global energy demand, paired with the harmful environmental effects of fossil fuels, has triggered the search for alternative, renewable energy…”
Get full text
Journal Article -
11
Atmospheric HCFC-22, HFC-125, and HFC-152a at Cape Point, South Africa
Published in Environmental science & technology (06-08-2019)“…One hydrochlorofluorocarbon and two hydrofluorocarbons (HCFC-22, HFC-125, and HFC-152a) were measured in air samples at the Cape Point observatory (CPT), South…”
Get full text
Journal Article -
12
Direct gas-phase formation of formic acid through reaction of Criegee intermediates with formaldehyde
Published in Communications chemistry (22-06-2023)“…Ozonolysis of isoprene is considered to be an important source of formic acid (HCOOH), but its underlying reaction mechanisms related to HCOOH formation are…”
Get full text
Journal Article -
13
Rate Coefficients of C1 and C2 Criegee Intermediate Reactions with Formic and Acetic Acid Near the Collision Limit: Direct Kinetics Measurements and Atmospheric Implications
Published in Angewandte Chemie (International ed.) (25-04-2014)“…Rate coefficients are directly determined for the reactions of the Criegee intermediates (CI) CH2OO and CH3CHOO with the two simplest carboxylic acids, formic…”
Get full text
Journal Article -
14
Improvements to the representation of BVOC chemistry–climate interactions in UKCA (v11.5) with the CRI-Strat 2 mechanism: incorporation and evaluation
Published in Geoscientific Model Development (20-08-2021)“…We present the first incorporation of the Common Representative Intermediates version 2.2 tropospheric chemistry mechanism, CRI v2.2, combined with…”
Get full text
Journal Article -
15
An Estimation of the Levels of Stabilized Criegee Intermediates in the UK Urban and Rural Atmosphere Using the Steady‐State Approximation and the Potential Effects of These Intermediates on Tropospheric Oxidation Cycles
Published in International journal of chemical kinetics (01-08-2017)“…ABSTRACT Levels of the stabilized Criegee Intermediate (sCI), produced via the ozonolysis of unsaturated volatile organic compounds (VOCs), were estimated at…”
Get full text
Journal Article -
16
The reaction of hydroxyl and methylperoxy radicals is not a major source of atmospheric methanol
Published in Nature communications (19-10-2018)“…Methanol is a benchmark for understanding tropospheric oxidation, but is underpredicted by up to 100% in atmospheric models. Recent work has suggested this…”
Get full text
Journal Article -
17
Investigating the Effect of Fine Particulate Matter (PM2.5) Emission Reduction on Surface-Level Ozone (O3) during Summer across the UK
Published in Atmosphere (01-06-2024)“…UK air pollutant data collected over a 10-year period (2010–2019) from 46 sites with Urban Traffic, Urban Background, Suburban Background, Rural Background,…”
Get full text
Journal Article -
18
Reaction between CH3O2 and BrO Radicals: A New Source of Upper Troposphere Lower Stratosphere Hydroxyl Radicals
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (14-05-2015)“…Over the last two decades it has emerged that measured hydroxyl radical levels in the upper troposphere are often underestimated by models, leading to the…”
Get full text
Journal Article -
19
Criegee Intermediate–Alcohol Reactions, A Potential Source of Functionalized Hydroperoxides in the Atmosphere
Published in ACS earth and space chemistry (21-12-2017)“…Ozonolysis, the mechanism by which alkenes are oxidized by ozone in the atmosphere, produces a diverse family of oxidants known as Criegee intermediates (CIs)…”
Get full text
Journal Article -
20
Elucidating the Effects of COVID-19 Lockdowns in the UK on the O3-NOx-VOC Relationship
Published in Atmosphere (01-05-2024)“…The unprecedented reductions in anthropogenic emissions over the COVID-19 lockdowns were utilised to investigate the response of ozone (O3) concentrations to…”
Get full text
Journal Article