Tuneable blue to orange phosphor from Sm3+ doped ZnAl2O4 nanomaterials

Tuneable blue to orange phosphor from Sm3+ doped ZnAl2O4 nanomaterials

•Nanopowders were synthesized by precipitation method.•Sm3+ doping of ZnAl2O4 induced defects at around 380, 401, 601, and 649 nm.•The emission color tuning from blueish to white to orange by varying the Sm3+. Undoped and Sm3+ doped ZnAl2O4 nanopowders were synthesized using the co-precipitation met...

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Bibliographic Details
Published in:Results in optics Vol. 9; p. 100280
Main Authors: Khambule, S.P., Motloung, S.V., Motaung, T.E., Koao, L.F., Kroon, R.E., Malimabe, M.A.
Format: Journal Article
Language:English
Published: Elsevier B.V 01-12-2022
Elsevier
Subjects:
Co-precipitation
Dopant
Photoluminescence
Sm3
Surface defects
ZnAl2O4
Sm3
Dopant
ZnAl2O4
Surface defects
Co-precipitation
Photoluminescence
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Summary:•Nanopowders were synthesized by precipitation method.•Sm3+ doping of ZnAl2O4 induced defects at around 380, 401, 601, and 649 nm.•The emission color tuning from blueish to white to orange by varying the Sm3+. Undoped and Sm3+ doped ZnAl2O4 nanopowders were synthesized using the co-precipitation method and annealed at 750 ℃ for 3.5 h. The aim of this study was to investigate the effect of varying the Sm3+ concentration on the ZnAl2O4 structure, morphology, and optical properties. The X-ray diffraction analysis confirmed that the samples have a face-centred cubic structure. Crystallite size decreased with an increase in Sm3+ concentration. Scanning electron microscopy revealed that the addition of Sm3+ slightly influence the morphology of the samples. Transmission electron microscopy confirmed a slight decrease in particle sizes. Energy-dispersive X-ray spectroscopy analysis confirmed the anticipated elemental composition. Ultraviolet–visible spectroscopy showed an increase in bandgap compared to the host. Photoluminescence analysis indicated that doping with Sm3+ induced defects within ZnAl2O4. The emission peaks observed around 380, 401, 451, 500, and 739 nm are attributed to host material. The emission peaks at 564, 601, and 649 nm correspond to the 5G5/2 → 6H5/2, 6H7/2, and 6H9/2 transition of Sm3+, respectively. The highest luminescence intensity was found for the 0.5 % Sm3+ sample. The CIE colour chromaticity diagram showed that the emission colour could be tuned from bluish to nearly white to orange.
ISSN:2666-9501
2666-9501
DOI:10.1016/j.rio.2022.100280