Search Results - "Khalsa, G.R.K."
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Neutron structure and inelastic-neutron-scattering and theoretical studies of Mo(CO)(H[sub 2])[(C[sub 6]D[sub 5])[sub 2]PC[sub 2]H[sub 4]P(C[sub 6]D[sub 5])[sub 2]][sub 2][center dot]4. 5C[sub 6]D[sub 6], a complex with an extremely low barrier to H[sub 2] rotation. Implications on the reaction coordinate for H-H cleavage to dihydride
Published in Journal of the American Chemical Society (27-01-1993)“…The synthesis and characterization of derivatives of Mo(CO)(R[sub 2]PC[sub 2]H[sub 4]PR[sub 2])[sub 2] (R = Et, i-Bu, Ph, Et-Ph) and their reactions with H[sub…”
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Journal Article -
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Molecular hydrogen complexes of the transition metals. 7. Kinetics and thermodynamics of the interconversion between dihydride and dihydrogen forms of W(CO) sub 3 (PR sub 3 ) sub 2 H sub 2 where R = isopropyl and cyclopentyl
Published in Journal of the American Chemical Society (09-05-1990)“…Kinetic and thermodynamic parameters have been obtained for the equilibrium system H{sub 2}W(CO){sub 3}(PR{sub 3}){sub 2} {rightleftharpoons} W(CO){sub…”
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Journal Article