Search Results - "Keutsch, Frank N."
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1
Contribution of Hydroxymethane Sulfonate to Ambient Particulate Matter: A Potential Explanation for High Particulate Sulfur During Severe Winter Haze in Beijing
Published in Geophysical research letters (16-11-2018)“…PM2.5 during severe winter haze in Beijing, China, has reached levels as high as 880 μg/m3, with sulfur compounds contributing significantly to PM2.5…”
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2
Glyoxal in Aqueous Ammonium Sulfate Solutions: Products, Kinetics and Hydration Effects
Published in Environmental science & technology (01-08-2011)“…Reactions and interactions between glyoxal and salts in aqueous solution were studied. Glyoxal was found to react with ammonium to form imidazole,…”
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3
Missing Gas-Phase Source of HONO Inferred from Zeppelin Measurements in the Troposphere
Published in Science (American Association for the Advancement of Science) (18-04-2014)“…Gaseous nitrous acid (HONO) is an important precursor of tropospheric hydroxyl radicals (OH). OH is responsible for atmospheric self-cleansing and controls the…”
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4
Qualitative and quantitative analysis of atmospheric organosulfates in Centreville, Alabama
Published in Atmospheric chemistry and physics (30-01-2017)“…Organosulfates are components of secondary organic aerosols (SOA) that form from oxidation of volatile organic compounds (VOCs) in the presence of sulfate. In…”
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5
Predicting Real Refractive Index of Organic Aerosols From Elemental Composition
Published in Geophysical research letters (28-06-2023)“…Accurate estimates of aerosol refractive index (RI) are critical for modeling aerosol‐radiation interaction, yet this information is limited for ambient…”
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6
High resolution nanoscale chemical analysis of bitumen surface microstructures
Published in Scientific reports (30-06-2021)“…Surface microstructures of bitumen are key sites in atmospheric photo-oxidation leading to changes in the mechanical properties and finally resulting in…”
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7
Isoprene photochemistry over the Amazon rainforest
Published in Proceedings of the National Academy of Sciences - PNAS (31-05-2016)“…Isoprene photooxidation is a major driver of atmospheric chemistry over forested regions. Isoprene reacts with hydroxyl radicals (OH) and molecular oxygen to…”
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8
Product distribution, kinetics, and aerosol formation from the OH oxidation of dimethyl sulfide under different RO2 regimes
Published in Atmospheric chemistry and physics (20-12-2022)“…The atmospheric oxidation of dimethyl sulfide (DMS) represents a major natural source of atmospheric sulfate aerosols. However, there remain large…”
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Identification of organic hydroperoxides and peroxy acids using atmospheric pressure chemical ionization–tandem mass spectrometry (APCI-MS/MS): application to secondary organic aerosol
Published in Atmospheric measurement techniques (30-05-2018)“…Molecules with hydroperoxide functional groups are of extreme importance to both the atmospheric and biological chemistry fields. In this work, an analytical…”
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10
Glyoxal Yield from Isoprene Oxidation and Relation to Formaldehyde: Chemical Mechanism, Constraints from SENEX Aircraft Observations, and Interpretation of OMI Satellite Data
Published in Atmospheric chemistry and physics (18-07-2017)“…Glyoxal (CHOCHO) is produced in the atmosphere by the oxidation of volatile organic compounds(VOCs). Like formaldehyde (HCHO), another VOC oxidation product,…”
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Emissions of Glyoxal and Other Carbonyl Compounds from Agricultural Biomass Burning Plumes Sampled by Aircraft
Published in Environmental science & technology (17-10-2017)“…We report enhancements of glyoxal and methylglyoxal relative to carbon monoxide and formaldehyde in agricultural biomass burning plumes intercepted by the NOAA…”
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Validation of satellite formaldehyde (HCHO) retrievals using observations from 12 aircraft campaigns
Published in Atmospheric chemistry and physics (29-10-2020)“…Formaldehyde (HCHO) has been measured from space for more than 2 decades. Owing to its short atmospheric lifetime, satellite HCHO data are used widely as a…”
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13
Water Clusters: Untangling the Mysteries of the Liquid, One Molecule at a Time
Published in Proceedings of the National Academy of Sciences - PNAS (11-09-2001)“…Extensive terahertz laser vibration-rotation-tunneling spectra and mid-IR laser spectra have been compiled for several isotopomers of small (dimer through…”
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Measurement techniques for identifying and quantifying hydroxymethanesulfonate (HMS) in an aqueous matrix and particulate matter using aerosol mass spectrometry and ion chromatography
Published in Atmospheric measurement techniques (07-10-2019)“…Oxidation of sulfur dioxide (SO2) in the gas phase and in cloud and fog water leads to the formation of sulfate that contributes to ambient particulate matter…”
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15
Kinetics and Product Yields of the OH Initiated Oxidation of Hydroxymethyl Hydroperoxide
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (02-08-2018)“…Hydroxymethyl hydroperoxide (HMHP), formed in the reaction of the C1 Criegee intermediate with water, is among the most abundant organic peroxides in the…”
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Author Correction: High resolution nanoscale chemical analysis of bitumen surface microstructures
Published in Scientific reports (19-08-2021)Get full text
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17
Dimensionality-reduction techniques for complex mass spectrometric datasets: application to laboratory atmospheric organic oxidation experiments
Published in Atmospheric chemistry and physics (27-01-2020)“…Oxidation of organic compounds in the atmosphere produces an immensely complex mixture of product species, posing a challenge for both their measurement in…”
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Hydroxycarboxylic Acid-Derived Organosulfates: Synthesis, Stability, and Quantification in Ambient Aerosol
Published in Environmental science & technology (01-08-2011)“…Organosulfates have been proposed as contributors to aerosol growth and have been detected in both chamber and atmospheric aerosol samples. We present a simple…”
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Observational constraints on glyoxal production from isoprene oxidation and its contribution to organic aerosol over the Southeast United States
Published in Journal of geophysical research. Atmospheres (27-08-2016)“…We use a 0‐D photochemical box model and a 3‐D global chemistry‐climate model, combined with observations from the NOAA Southeast Nexus (SENEX) aircraft…”
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Technical note: Conversion of isoprene hydroxy hydroperoxides (ISOPOOHs) on metal environmental simulation chamber walls
Published in Atmospheric chemistry and physics (24-03-2017)“…Sources and sinks of isoprene oxidation products from low-NOx isoprene chemistry have been studied at the CERN CLOUD (Cosmics Leaving Outdoor Droplets) chamber…”
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