Search Results - "Kenttaemaa, Hilkka I"
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Characterization of Asphaltene Deposits by Using Mass Spectrometry and Raman Spectroscopy
Published in Energy & fuels (18-02-2016)“…Crude oil deposition in oil transfer pipelines and bore wells afflicts many oil reservoirs. Asphaltenes play a major role in this process because of their…”
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2
Structural Comparison of Asphaltenes of Different Origins Using Multi-stage Tandem Mass Spectrometry
Published in Energy & fuels (19-03-2015)“…In this work, six petroleum asphaltene samples of different geographical origins were studied using atmospheric pressure chemical ionization (APCI) in…”
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3
Comparison of the Structures of Molecules in Coal and Petroleum Asphaltenes by Using Mass Spectrometry
Published in Energy & fuels (18-07-2013)“…Asphaltenes are a complex mixture of aromatic compounds that are present in petroleum and liquefied coal and have unknown molecular structures. Determination…”
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4
On-Line Mass Spectrometric Methods for the Determination of the Primary Products of Fast Pyrolysis of Carbohydrates and for Their Gas-Phase Manipulation
Published in Analytical chemistry (Washington) (19-11-2013)“…Mass spectrometric methodology was developed for the determination and manipulation of the primary products of fast pyrolysis of carbohydrates. To determine…”
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5
UV-induced effects on chlorination of creatinine
Published in Water research (Oxford) (15-09-2013)“…Ultraviolet (UV) irradiation is commonly employed for water treatment in swimming pools to complement conventional chlorination, and to reduce the…”
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6
On the factors that control the reactivity of meta-benzynes
Published in Chemical science (Cambridge) (01-01-2014)“…The reactivities of eleven 3,5-didehydropyridinium and six 2,4-didehydropyridinium cations toward cyclohexane were examined in the gas phase by using…”
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7
Mass spectrometric identification of the N-monosubstituted N-hydroxylamino functionality in protonated analytes via ion/molecule reactions in tandem mass spectrometry
Published in Rapid communications in mass spectrometry (30-04-2015)“…Rationale N‐Monosubstituted hydroxylamines correspond to an important class of metabolites for many bioactive molecules. In this study, a tandem mass…”
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8
A Differentially Pumped Dual Linear Quadrupole Ion Trap (DLQIT) Mass Spectrometer: A Mass Spectrometer Capable of MSn Experiments Free From Interfering Reactions
Published in Analytical chemistry (Washington) (03-12-2013)“…A novel differentially pumped dual linear quadrupole ion trap (DLQIT) mass spectrometer was designed and built to facilitate tandem MS experiments free from…”
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9
Reactivity Controlling Factors for an Aromatic Carbon-Centered σ,σ,σ-Triradical: The 4,5,8-Tridehydroisoquinolinium Ion
Published in Chemistry : a European journal (11-01-2016)“…The chemical properties of the 4,5,8‐tridehydroisoquinolinium ion (doublet ground state) and related mono‐ and biradicals were examined in the gas phase in a…”
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10
Ion-molecule reactions for the differentiation of primary, secondary and tertiary hydroxyl functionalities in protonated analytes in a tandem mass spectrometer
Published in Analyst (London) (21-12-2012)“…A mass spectrometric method utilizing gas-phase ion-molecule reactions of 1-butanethiol and di-tert-butyl peroxide has been developed for the differentiation…”
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11
Separation of Asphaltenes by Reversed-Phase Liquid Chromatography with Fraction Characterization
Published in Energy & fuels (17-05-2012)“…The use of a 4.6 × 250 mm, 5 μm cyanopropyl column is effective for the liquid chromatography (LC) separation of asphaltenes with sequential ultraviolet (UV)…”
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12
Analysis of carbohydrates by atmospheric pressure chloride anion attachment tandem mass spectrometry
Published in Fuel (Guildford) (01-03-2013)“…► We have developed a method for the analysis of cellulose degradation products. ► Chloride attachment in atmospheric pressure gently ionizes oligosaccharides…”
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13
Development of a High-Throughput Laser-Induced Acoustic Desorption Probe and Raster Sampling For Laser-Induced Acoustic Desorption/Atmospheric Pressure Chemical Ionization
Published in Analytical chemistry (Washington) (18-06-2013)“…Laser-induced acoustic desorption (LIAD) was recently coupled to atmospheric pressure chemical ionization (APCI) and shown to be of great utility for the…”
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14
Experimental and Computational Studies on the Formation of Three para-Benzyne Analogues in the Gas Phase
Published in Chemistry : a European journal (01-07-2013)“…Experimental and computational studies on the formation of three gaseous, positively‐charged para‐benzyne analogues in a Fourier transform ion cyclotron…”
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15
Reactivity of the 4,5-Didehydroisoquinolinium Cation
Published in Chemistry : a European journal (09-07-2012)“…The chemical properties of a 1,8‐didehydronaphthalene derivative, the 4,5‐didehydroisoquinolinium cation, were examined in the gas phase in a dual‐cell…”
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16
Substituent Effects on the Nonradical Reactivity of 4-Dehydropyridinium Cation
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (29-03-2012)“…Recent studies have shown that the reactivity of the 4-dehydropyridinium cation significantly differs from the reactivities of its isomers toward…”
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A novel chemical ionization reagent ion for organic analytes: the aquachloromanganese(II) cation [ClMn(H2O)+]
Published in Rapid communications in mass spectrometry (30-04-2012)“…The reactivity of ClMn(H2O)+ towards small organic compounds (L) was examined in a Fourier transform ion cyclotron resonance (FT‐ICR) mass spectrometer. The…”
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18
Identification and Counting of Oxygen Functionalities and Alkyl Groups of Aromatic Analytes in Mixtures by Positive-Mode Atmospheric Pressure Chemical Ionization Tandem Mass Spectrometry Coupled with High-Performance Liquid Chromatography
Published in Energy & fuels (17-05-2012)“…A tandem mass spectrometric method using a commercial linear quadrupole ion trap (LQIT) mass spectrometer and another LQIT coupled with a Fourier transform ion…”
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Chemical Characterization and Quantitation of Phenols in Fuel Extracts by Using Gas Chromatography/Methane Chemical Ionization Triple Quadrupole Mass Spectrometry
Published in Energy & fuels (06-10-2022)“…The ability to detect, characterize, and quantify phenols in aviation fuels is critical as these compounds can negatively affect the storage stability of the…”
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Total Utilization of Miscanthus Biomass, Lignin and Carbohydrates, Using Earth Abundant Nickel Catalyst
Published in ACS sustainable chemistry & engineering (04-04-2016)“…Lignin as a polymer of monomeric aromatic compounds retains great potential to be a source for liquid fuels and valuable chemicals. However, lignin from…”
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