Search Results - "Kays, Deborah L"

Selective reduction and homologation of carbon monoxide by organometallic iron complexes by Sharpe, Helen R., Geer, Ana M., Taylor, Laurence J., Gridley, Benjamin M., Blundell, Toby J., Blake, Alexander J., Davies, E. Stephen, Lewis, William, McMaster, Jonathan, Robinson, David, Kays, Deborah L.

“…Carbon monoxide is a key C 1 feedstock for the industrial production of hydrocarbons, where it is used to make millions of tonnes of chemicals, fuels, and…”
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The anticancer and EGFR-TK/CDK-9 dual inhibitory potentials of new synthetic pyranopyrazole and pyrazolone derivatives: X-ray crystallography, in vitro, and in silico mechanistic investigations by Musa, Arafa, Ihmaid, Saleh K., Hughes, David L., Said, Musa A., Abulkhair, Hamada S., El-Ghorab, Ahmed H., Abdelgawad, Mohamed A., Shalaby, Khaled, Shaker, Mohamed E., Alharbi, Khalid Saad, Alotaibi, Nasser Hadal, Kays, Deborah L., Taylor, Laurence J., Parambi, Della Grace Thomas, Alzarea, Sami I., Al-Karmalawy, Ahmed A., Ahmed, Hany E. A., El-Agrody, Ahmed M.

“…Treatment options for the management of breast cancer are still inadequate. This inadequacy is attributed to the lack of effective targeted medications, often…”
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Morpholino-Substituted BODIPY Species: Synthesis, Structure and Electrochemical Studies by Hassanain, Hawazen, Davies, E. Stephen, Lewis, William, Kays, Deborah L., Champness, Neil R.

“…Functionalization of 4,4-difluoro-4-bora-3a,4a-diaza-s-indacene (BODIPY) chromophores at the 2,6-positions with iodo substituents and morpholino-substituted…”
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Cationic Terminal Borylene Complexes: Structure/Bonding Analysis and [4+1] Cycloaddition Reactivity of a BN Vinylidene Analogue by Aldridge, Simon, Jones, Cameron, Gans-Eichler, Timo, Stasch, Andreas, Kays (née Coombs), Deborah L., Coombs, Natalie D., Willock, David J.

“…Charge changes everything: The cationic terminal aminoborylene complex [CpFe(CO)2(BNCy2)]+[BArF4]− (1, Cy= cyclohexyl, ArF=3,5‐(CF3)2C6H3; Fe orange, B green,…”
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Organoruthenium Complexes Containing Phosphinodicarboxamide Ligands by Nolla-Saltiel, Roberto, Geer, Ana M., Sharpe, Helen R., Huke, Cameron D., Taylor, Laurence J., Linford-Wood, Thomas G., James, Ashleigh, Allen, Jamie, Lewis, William, Blake, Alexander J., McMaster, Jonathan, Kays, Deborah L.

“…Ruthenium complexes of phosphinocarboxamide ligands, and their use to form metallacycles using halide abstraction/deprotonation reactions are reported. Thus,…”
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Half-Sandwich Group 8 Borylene Complexes: Synthetic and Structural Studies and Oxygen Atom Abstraction Chemistry by Pierce, Glesni A, Vidovic, Dragoslav, Kays, Deborah L, Coombs, Natalie D, Thompson, Amber L, Jemmis, Eluvathingal D, De, Susmita, Aldridge, Simon

“…Cationic terminal borylene complexes, synthesized by halide abstraction, offer a versatile platform on which to gauge the effects on the electronic structure…”
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Bridging the Gap between Coordination and Cluster Compounds: Unusual Bonding Modes for Zinc by Kays, Deborah L, Aldridge, Simon

“…Inner virtue: The reaction of [Mo⁰(GaCp*)₆] with ZnMe₂ yields the novel multinuclear zinc system [MoZn₁₂Me₉Cp*₃] which geometrically resembles a classical…”
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Cationic Terminal Borylene Complexes: Interconversion of Amino and Alkoxy Borylenes by an Unprecedented Meerwein-Ponndorf Hydride Transfer by Kays (née Coombs), Deborah L., Day, Joanna K., Aldridge, Simon, Harrington, Ross W., Clegg, William

“…It's all new to B: In the reaction of borylene complex 1 with benzophenone, a Meerwein–Ponndorf β‐hydride transfer from the aminoborylene ligand to the…”
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Cationic Terminal Borylene Complexes: A Synthetic and Mechanistic Investigation of MB Metathesis Chemistry by Kays (née Coombs), Deborah L., Day, Joanna K., Ooi, Li-Ling, Aldridge, Simon

“…Halide ion chemistry has been exploited to generate the cationic terminal borylene complex 1, which reacts with Ph3PS or Ph3AsO to form 3 and 4. In the case…”
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Synthesis of the Bulky Phosphanide [P(Si i Pr3)2]− and Its Stabilization of Low-Coordinate Group 12 Complexes by Churchill, Olivia P., Dase, Antonia, Taylor, Laurence J., Argent, Stephen P., Coles, Nathan T., Walker, Gavin S., Kays, Deborah L.

“…Here, we report an improved synthesis of the bulky phosphanide anion [P­(Si i Pr3)2]− in synthetically useful yields and its complexation to group 12 metals…”
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Group 11 m‑Terphenyl Complexes Featuring Metallophilic Interactions by Liu, Yu, Taylor, Laurence J, Argent, Stephen P, McMaster, Jonathan, Kays, Deborah L

“…A series of group 11 m-terphenyl complexes have been synthesized via a metathesis reaction from the iron­(II) complexes (2,6-Mes2C6H3)2Fe and (2,6-Xyl2C6H3)2Fe…”
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Iron(II)‐Catalyzed Hydrophosphination of Isocyanates by Sharpe, Helen R., Geer, Ana M., Lewis, William, Blake, Alexander J., Kays, Deborah L.

“…The first transition metal catalyzed hydrophosphination of isocyanates is presented. The use of low‐coordinate iron(II) precatalysts leads to an unprecedented…”
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Homotropic Cooperativity in Iron-Catalyzed Alkyne Cyclotrimerizations by Geer, Ana M., Navarro, Janeth, Alamán-Valtierra, Pablo, Coles, Nathan T., Kays, Deborah L., Tejel, Cristina

“…Enhancing catalytic activity through synergic effects is a current challenge in homogeneous catalysis. In addition to the well-established metal–metal and…”
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Synthesis and isolation of [Fe@Ge(10)](3-): a pentagonal prismatic Zintl ion cage encapsulating an interstitial iron atom by Zhou, Binbin, Denning, Mark S, Kays, Deborah L, Goicoechea, Jose M

“…Reaction of an ethylenediamine (en) solution of the Zintl phase precursor K(4)Ge(9) with FeAr(2) (Ar = 2,6-Mes(2)C(6)H(3)) in the presence of 2,2,2-crypt…”
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Mechanistic investigations of the Fe() mediated synthesis of squaraines by Liu, Yu, Coles, Nathan T, Cajiao, Nathalia, Taylor, Laurence J, Davies, E. Stephen, Barbour, Alistair, Morgan, Patrick J, Butler, Kevin, Pointer-Gleadhill, Ben, Argent, Stephen P, McMaster, Jonathan, Neidig, Michael L, Robinson, David, Kays, Deborah L

“…The scission and homologation of CO is a fundamental process in the Fischer-Tropsch reaction. However, given the heterogeneous nature of the catalyst and…”
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Alkaline Earth Complexes of a Sterically Demanding Guanidinate Ligand by Moxey, Graeme J., Blake, Alexander J., Lewis, William, Kays, Deborah L.

“…The synthesis of the guanidine MesN{C(NCy2)}N(H)Mes (LH; Mes = 2,4,6‐Me3C6H2, Cy = cyclohexyl), and its use as a proligand for the synthesis of alkaline earth…”
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Structural and Electronic Studies of Substituted m‑Terphenyl Group 12 Complexes by Valentine, Andrew J., Taylor, Laurence J., Geer, Ana M., Huke, Cameron D., Wood, Katherine E., Tovey, Will, Lewis, William, Argent, Stephen P., Teale, Andrew M., McMaster, Jonathan, Kays, Deborah L.

“…The effects of para-substitution on the structural and electronic properties of four series of two-coordinate m-terphenyl Group 12 complexes (R-Ar#)2M (M = Zn,…”
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Catalyst-free Hydrophosphinylation of Isocyanates and Isothiocyanates under Low-Added-Solvent Conditions by Huke, Cameron D, Taylor, Laurence J, Argent, Stephen P, Kays, Deborah L

“…A catalyst-free, low-solvent method for the hydrophosphinylation of isocyanates and isothiocyanates is reported. A range of phosphorus nucleophiles including…”
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Iron(II)-Catalyzed Hydroamination of Isocyanates by South, Amy J, Geer, Ana M, Taylor, Laurence J, Sharpe, Helen R, Lewis, William, Blake, Alexander J, Kays, Deborah L

“…A two-coordinate Fe­(II) m-terphenyl complex acts as a precatalyst for the hydroamination of isocyanates, affording urea and biuret derivatives, with product…”
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Hydrophosphination of Activated Alkenes by a Cobalt(I) Pincer Complex by Nolla‐Saltiel, Roberto, Geer, Ana M., Taylor, Laurence J., Churchill, Olivia, Davies, E. Stephen, Lewis, William, Blake, Alexander J., Kays, Deborah L.

“…Herein we report the synthesis of three heteroleptic first‐row transition metal(II) complexes containing carbazolido NNN pincer ligands and conversion to the…”
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