Search Results - "Kattamuri, Padmanabha V"
-
1
Arylboronic Acid-Catalyzed C‑Allylation of Unprotected Oximes: Total Synthesis of N‑Me-Euphococcine
Published in Organic letters (20-03-2020)“…O-Unprotected keto- and aldoximes are readily C-allylated with allyl diisopropyl boronate in the presence of arylboronic acid catalysts to yield highly…”
Get full text
Journal Article -
2
Hydrogenation of Alkenes via Cooperative Hydrogen Atom Transfer
Published in Journal of the American Chemical Society (11-11-2020)“…Radical hydrogenation via hydrogen atom transfer (HAT) to alkenes is an increasingly important transformation for the formation of thermodynamic alkane…”
Get full text
Journal Article -
3
Enantioselective Catalytic Allylation of Acyclic Ketiminoesters: Synthesis of α‑Fully-Substituted Amino Esters
Published in Organic letters (15-11-2019)“…We report the first direct catalytic enantioselective allylation of acyclic α-ketiminoesters to afford α-allyl-α-aryl and α-allyl-α-trifluoromethyl amino…”
Get full text
Journal Article -
4
Aza-Quasi-Favorskii Reaction: Construction of Highly Substituted Aziridines through a Concerted Multibond Rearrangement Process
Published in Journal of the American Chemical Society (22-06-2022)“…A new molecular rearrangement, the aza-Quasi-Favorskii rearrangement, has been developed for the construction of highly substituted aziridines…”
Get full text
Journal Article -
5
Practical Singly and Doubly Electrophilic Aminating Agents: A New, More Sustainable Platform for Carbon–Nitrogen Bond Formation
Published in Journal of the American Chemical Society (16-08-2017)“…Given the importance of amines in a large number of biologically active natural products, active pharmaceutical ingredients, agrochemicals, and functional…”
Get full text
Journal Article -
6
Fe/Thiol Cooperative Hydrogen Atom Transfer Olefin Hydrogenation: Mechanistic Insights That Inform Enantioselective Catalysis
Published in Journal of the American Chemical Society (26-06-2024)“…Asymmetric hydrogenation of activated olefins using transition metal catalysis is a powerful tool for the synthesis of complex molecules, but traditional metal…”
Get full text
Journal Article -
7
Chiral N-phosphonyl imine chemistry: asymmetric additions of glycine enolate to diphenyl diamine-based phosphonyl imines
Published in Science China Chemistry (2010)“…Diphenyl diamine-based phosphonyl imines attached by the N -isopropyl group in the auxiliary have been synthesized in good yields under convenient reaction…”
Get full text
Journal Article -
8
Asymmetric catalytic Mannich-type reaction of hydrazones with difluoroenoxysilanes using imidazoline-anchored phosphine ligand-zinc(II) complexes
Published in Organic & biomolecular chemistry (07-04-2012)“…Asymmetric Mannich-type reaction of hydrazones with difluoroenoxysilanes using chiral zinc(II)-imidazoline-phosphine complexes as catalysts have been…”
Get more information
Journal Article -
9
Synthesis of Structurally Diverse 3‑, 4‑, 5‑, and 6‑Membered Heterocycles from Diisopropyl Iminomalonates and Soft C‑Nucleophiles
Published in Journal of organic chemistry (07-06-2019)“…Herein, we present a general synthetic strategy for the preparation of 3-, 4-, 5-, and 6-membered heterocyclic unnatural amino acid derivatives by exploiting…”
Get full text
Journal Article -
10
Approach to Vicinal t‑Boc-amino Dibromides via Catalytic Aminobromination of Nitrostyrenes without Using Chromatography and Recrystallization
Published in Journal of organic chemistry (01-02-2013)“…A 1.0 mol % amount of K3PO4·3H2O was found to catalyze aminohalogenation reaction of nitrostyrenes with N,N-dibromo-tert-butylcarbamate (t-Boc-NBr2) in a…”
Get full text
Journal Article -
11
-
12
N,N-DIIsopropyl-N-phosphonyl imines lead to efficient asymmetric synthesis of aziridine-2-carboxylic esters
Published in Organic & biomolecular chemistry (28-05-2013)“…Highly diastereoselective asymmetric synthesis of chiral aziridine-2-carboxylic esters is reported for 20 examples with good yields (51-87%) and excellent…”
Get more information
Journal Article -
13
Asymmetric Synthesis of α-Amino-1,3-dithianes via Chiral N-Phosphonyl Imine-Based Umpolung Reaction Without Using Chromatography and Recrystallization
Published in Journal of organic chemistry (15-04-2011)“…A series of α-amino-1,3-dithianes have been synthesized via the asymmetric Umpolung reaction of 2-lithio-1,3-dithianes with chiral N-phosphonyl imines in good…”
Get full text
Journal Article -
14
Asymmetric synthesis of novel N-(1-phenyl-2,3-dihydroxypropyl)arachidonylamides and evaluation of their anti-inflammatory activity
Published in Life sciences (1973) (19-03-2013)“…To design and synthesize novel N-(1-phenyl-2,3-dihydroxypropyl)arachidonylamides and evaluate their analgesic and anti-inflammatory potential. The murine…”
Get full text
Journal Article -
15
Aza-Quasi-Favorskii Reaction: Construction of Highly Substituted Aziridines through a Concerted Multi-bond Rearrangement Process
Published in Journal of the American Chemical Society (08-06-2022)“…A new molecular rearrangement, the aza -Quasi-Favorskii rearrangement, has been developed for the construction of highly-substituted aziridines. Electron…”
Get full text
Journal Article -
16
Asymmetric Synthesis of α-Amino 1,3-Dithianes via Chiral N-Phosphonyl Imine-based Umpolung Reaction
Published in Journal of organic chemistry (15-03-2011)“…A series of α-amino-1,3-dithianes have been synthesized via the asymmetric Umpolung reaction of 2-lithio-1,3-dithianes with chiral N -phosphonyl imines in good…”
Get full text
Journal Article