Search Results - "Kastner, Katharina"
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A Molecular Placeholder Strategy To Access a Family of Transition-Metal-Functionalized Vanadium Oxide Clusters
Published in Chemistry : a European journal (15-09-2014)“…Systematic access to metal‐functionalized polyoxometalates has thus far been limited to lacunary tungsten oxide and molybdenum oxide clusters. The first…”
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Aerobic Oxidation Catalysis by a Molecular Barium Vanadium Oxide
Published in Chemistry : a European journal (03-04-2018)“…Aerobic catalytic oxidations are promising routes to replace environmentally harmful oxidants with O2 in organic syntheses. Here, we report a molecular barium…”
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A Simple Approach to the Visible-Light Photoactivation of Molecular Metal Oxides
Published in Inorganic chemistry (16-10-2017)“…This study explores a new method to maximize the visible-light-driven photocatalytic performance of organic–inorganic hybrid polyoxometalates (POMs)…”
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Self-assembly of a tetrahedral 58-nuclear barium vanadium oxide cluster
Published in Chemical communications (Cambridge, England) (01-01-2013)“…We report the synthesis and characterization of a molecular barium vanadium oxide cluster featuring high nuclearity and high symmetry. The tetrameric, 2.3 nm…”
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Controlled Reactivity Tuning of Metal-Functionalized Vanadium Oxide Clusters
Published in Chemistry : a European journal (18-05-2015)“…Controlling the assembly and functionalization of molecular metal oxides [MxOy]n− (M=Mo, W, V) allows the targeted design of functional molecular materials…”
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6
Orbital Engineering: Photoactivation of an Organofunctionalized Polyoxotungstate
Published in Chemistry : a European journal (01-01-2017)“…Tungsten‐based polyoxometalates (POMs) have been employed as UV‐driven photo‐catalysts for a range of organic transformations. Their photoactivity is dependent…”
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One–step Synthesizable Lindqvist−isopolyoxometalates as Promising New Catalysts for Selective Conversion of Glucose as a Model Substrate for Lignocellulosic Biomass to Formic Acid
Published in ChemistrySelect (Weinheim) (16-07-2016)“…A series of Lindqvist‐isopolyoxometalates [M6O19]n− (M=W, V) were synthesized under one‐pot conditions and were applied in the homogeneous oxidation of glucose…”
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3D‐Printable Photochromic Molecular Materials for Reversible Information Storage
Published in Advanced materials (Weinheim) (27-06-2018)“…The formulation of advanced molecular materials with bespoke polymeric ionic‐liquid matrices that stabilize and solubilize hybrid organic–inorganic…”
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Redox‐Active Hybrid Polyoxometalate‐Stabilised Gold Nanoparticles
Published in Angewandte Chemie International Edition (17-08-2020)“…We report the design and preparation of multifunctional hybrid nanomaterials through the stabilization of gold nanoparticles with thiol‐functionalised hybrid…”
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Stabilization of Low‐Valent Iron(I) in a High‐Valent Vanadium(V) Oxide Cluster
Published in Angewandte Chemie International Edition (13-11-2017)“…Low‐valent iron centers are critical intermediates in chemical and bio‐chemical processes. Herein, we show the first example of a low‐valent FeI center…”
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Solvent-Controlled Polymerization of Molecular Strontium Vanadate Monomers into 1D Strontium Vanadium Oxide Chains
Published in Inorganic chemistry (03-09-2019)“…We report the polymerization of a solvent-stabilized molecular strontium vanadium oxide monomer into infinite 1D chains. Supramolecular polymerization is…”
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Reply to Comment on Stabilization of Low‐Valent Iron(I) in a High‐Valent Vanadium(V) Oxide Cluster
Published in Angewandte Chemie International Edition (22-07-2019)“…The authors of the Communication “Stabilization of Low‐Valent Iron(I) in a High‐Valent Vanadium(V) Oxide Cluster” reply to a Comment by Dr. Sproules, who…”
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Photochromic Materials: 3D‐Printable Photochromic Molecular Materials for Reversible Information Storage (Adv. Mater. 26/2018)
Published in Advanced materials (Weinheim) (01-06-2018)“…Novel reversible photochromic materials consisting of bespoke poly(ionic liquid) matrices and hybrid organic–inorganic polyoxometalates are presented by Graham…”
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In Situ Assembly, De‐Metalation and Induced Repair of a Copper‐Polyoxovanadate Oxidation Catalyst
Published in ChemistrySelect (Weinheim) (11-07-2017)“…Polyoxometalates (POMs) offer a rich dynamic solution chemistry so that in principle, the assembly and repair of POM oxidation catalysts in situ, i. e. under…”
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Novel phenanthroline-diaryldiazadiene ligands with heteroditopic coordination spheres
Published in Dalton transactions : an international journal of inorganic chemistry (21-09-2015)“…1,10-Phenanthroline-5,6-diaryldiazadienes are key structures for the development of novel heterodinuclear photocatalysts and for the construction of extended…”
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Ruthenium Imidazophenanthrolinium Complexes with Prolonged Excited-State Lifetimes
Published in European journal of inorganic chemistry (01-08-2015)“…A series of ruthenium polypyridyl complexes [Ru(tbbpy)3][PF6]2 (0, tbbpy = 4,4′‐di‐tert‐butyl‐2,2′‐bipyridine), [Ru(tbbpy)2(bbip)][PF6]3 {1, (bbip)Br =…”
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Back Cover: Orbital Engineering: Photoactivation of an Organofunctionalized Polyoxotungstate (Chem. Eur. J. 1/2017)
Published in Chemistry : a European journal (01-01-2017)“…Simple organic functionalization was shown to be a cost‐effective and durable approach to the visible‐light photoactivation of polyoxometalates (POMs). A new…”
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18
Redox‐Active Hybrid Polyoxometalate‐Stabilised Gold Nanoparticles
Published in Angewandte Chemie (17-08-2020)“…We report the design and preparation of multifunctional hybrid nanomaterials through the stabilization of gold nanoparticles with thiol‐functionalised hybrid…”
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Antwort auf den Kommentar zu “Stabilisierung eines niedrigvalenten Eisen(I)‐Ions in einem hochvalentem molekularen Vanadium(V) Oxid‐Cluster”
Published in Angewandte Chemie (22-07-2019)“…Die Autoren der Zuschrift “Stabilisierung eines niedrigvalenten Eisen(I)‐Ions in einem hochvalentem molekularen Vanadium(V) Oxid‐Cluster” antworten auf ein…”
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Stabilisierung eines niedrigvalenten Eisen(I)‐Ions in einem hochvalenten molekularen Vanadium(V)‐Oxid‐Cluster
Published in Angewandte Chemie (13-11-2017)“…Niedrigvalente Eisenzentren sind wichtige Zwischenstufen in chemischen und biochemischen Prozessen. Hier wird das erste Beispiel eines niedrigvalenten…”
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