Search Results - "Karwacki, Christopher J"
-
1
Photocatalytic Oxidation of Sulfur Mustard and Its Simulant on BODIPY-Incorporated Polymer Coatings and Fabrics
Published in ACS applied materials & interfaces (06-06-2018)“…Sulfur mustard is one of the most toxic chemical warfare agents worldwide. We report the use of 4,4-difluoro-4-bora-3a,4a-diaza-s-indacene (BODIPY)…”
Get full text
Journal Article -
2
Sense and Shoot: Simultaneous Detection and Degradation of Low-Level Contaminants Using Graphene-Based Smart Material Assembly
Published in ACS nano (22-07-2014)“…Smart material nanoassemblies that can simultaneously sense and shoot low-level contaminants from air and water are important for overcoming the threat of…”
Get full text
Journal Article -
3
Surface Chemistry and Morphology of Zirconia Polymorphs and the Influence on Sulfur Dioxide Removal
Published in Journal of physical chemistry. C (19-05-2011)“…Zirconium hydroxide was calcined at discrete temperatures up to 900 °C to study the effect of thermal treatment on the structure and surface chemistry related…”
Get full text
Journal Article -
4
A solvent-free solid catalyst for the selective and color-indicating ambient-air removal of sulfur mustard
Published in Communications chemistry (08-03-2021)“…Bis(2-chloroethyl) sulfide or sulfur mustard (HD) is one of the highest-tonnage chemical warfare agents and one that is highly persistent in the environment…”
Get full text
Journal Article -
5
CdSe/CdS Nanorod Photocatalysts: Tuning the Interfacial Charge Transfer Process through Shell Length
Published in Chemistry of materials (28-07-2015)“…CdSe/CdS core/shell semiconductor nanorods (NR) with rod-in-rod morphology offer new strategies for designing highly emissive nanostructures. The interplay…”
Get full text
Journal Article -
6
Solid-Phase Detoxification of Chemical Warfare Agents using Zirconium-Based Metal Organic Frameworks and the Moisture Effects: Analyze via Digestion
Published in ACS applied materials & interfaces (12-06-2019)“…Zirconium-based metal organic frameworks (Zr-MOFs) are highly chemically and thermally stable and have been of particular interest as reactive sorbents for…”
Get full text
Journal Article -
7
Optimizing Toxic Chemical Removal through Defect‐Induced UiO‐66‐NH2 Metal–Organic Framework
Published in Chemistry : a European journal (13-11-2017)“…For the first time, an increasing number of defects were introduced to the metal–organic framework UiO‐66‐NH2 in an attempt to understand the…”
Get full text
Journal Article -
8
All-Weather Dry Decontaminant Polymer-H 2 O 2 Complex for HD Degradation
Published in ACS applied materials & interfaces (03-07-2024)“…Hydrogen peroxide (H O ) is a highly effective decontaminant against chemical warfare agents (CWAs) when present both in a liquid and as a solid powder. For…”
Get full text
Journal Article -
9
All-Weather Dry Decontaminant Polymer‑H2O2 Complex for HD Degradation
Published in ACS applied materials & interfaces (03-07-2024)“…Hydrogen peroxide (H2O2) is a highly effective decontaminant against chemical warfare agents (CWAs) when present both in a liquid and as a solid powder. For…”
Get full text
Journal Article -
10
Modeling of Diffusion of Acetone in UiO-66
Published in Journal of physical chemistry. C (31-12-2020)“…Highly porous zirconium-based metal–organic frameworks (MOFs) have been widely studied as materials for sorption and destruction of chemical warfare agents…”
Get full text
Journal Article -
11
Laponite-Incorporated UiO-66-NH2‑Polyethylene Oxide Composite Membranes for Protection against Chemical Warfare Agent Simulants
Published in ACS applied materials & interfaces (03-03-2021)“…A strategy is developed to enhance the barrier protection of polyethylene oxide (PEO)-metal–organic framework (MOF) composite films against chemical warfare…”
Get full text
Journal Article -
12
Metal–Organic Framework- and Polyoxometalate-Based Sorbents for the Uptake and Destruction of Chemical Warfare Agents
Published in ACS applied materials & interfaces (01-04-2020)“…The threat of chemical warfare agents (CWAs), assured by their ease of synthesis and effectiveness as a terrorizing weapon, will persist long after the…”
Get full text
Journal Article -
13
Adsorption of Substituted Benzene Derivatives on Silica: Effects of Electron Withdrawing and Donating Groups
Published in Journal of physical chemistry. C (23-06-2016)“…A fundamental understanding of the forces that drive uptake and binding of aromatic molecules on well-characterized surfaces such as silica is important for…”
Get full text
Journal Article -
14
-
15
Disordered Mesoporous Zirconium (Hydr)oxides for Decomposition of Dimethyl Chlorophosphate
Published in ACS applied materials & interfaces (15-05-2019)“…A facile method for the formation of mesoporosity within nonporous zirconium hydr(oxides) (ZrO2/Zr(OH)4) is presented and their detoxifying capabilities…”
Get full text
Journal Article -
16
Laponite-Incorporated UiO-66-NH 2 -Polyethylene Oxide Composite Membranes for Protection against Chemical Warfare Agent Simulants
Published in ACS applied materials & interfaces (03-03-2021)“…A strategy is developed to enhance the barrier protection of polyethylene oxide (PEO)-metal-organic framework (MOF) composite films against chemical warfare…”
Get full text
Journal Article -
17
In Situ Nuclear Magnetic Resonance Investigation of Molecular Adsorption and Kinetics in Metal–Organic Framework UiO-66
Published in The journal of physical chemistry letters (21-01-2021)“…Thermodynamic and kinetic properties of molecular adsorption and transport in metal–organic frameworks (MOFs) are crucially important for many applications,…”
Get full text
Journal Article -
18
Adsorption of 2‑Chloroethyl Ethyl Sulfide on Silica: Binding Mechanism and Energy of a Bifunctional Hydrogen-Bond Acceptor at the Gas–Surface Interface
Published in Journal of physical chemistry. C (08-01-2015)“…This work investigates the fundamental nature of sulfur mustard surface adsorption by characterizing interfacial hydrogen bonding and other intermolecular…”
Get full text
Journal Article -
19
Conducting an evaluation of CBRN canister protection capabilities against emerging chemical and radiological hazards
Published in Journal of occupational and environmental hygiene (02-10-2020)“…In the event of a chemical, biological, radiological, or nuclear (CBRN) hazard release, emergency responders rely on respiratory protection to prevent…”
Get full text
Journal Article -
20
Dry Reactive H2O2–Polymer Complexes for the Degradation of Mustard Gas
Published in ACS applied polymer materials (13-11-2020)“…We report an all-solid dry complex oxidizing agent against sulfur mustard (HD) and its simulant 2-chloroethyl ethyl sulfide. Polymer complexes of…”
Get full text
Journal Article