Search Results - "Karlen, Steven D"
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Electrochemical Aminoxyl-Mediated Oxidation of Primary Alcohols in Lignin to Carboxylic Acids: Polymer Modification and Depolymerization
Published in Journal of the American Chemical Society (25-09-2019)“…An electrochemical process has been developed for chemoselective oxidation of primary alcohols in lignin to the corresponding carboxylic acids. The…”
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2
Short-term facilitation of microbial litter decomposition by ultraviolet radiation
Published in The Science of the total environment (15-02-2018)“…Solar radiation plays an important role in carbon cycling by increasing the decomposition rates of plant litter and soil organic matter (i.e…”
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3
Tricin‐lignins: occurrence and quantitation of tricin in relation to phylogeny
Published in The Plant journal : for cell and molecular biology (01-12-2016)“…Summary Tricin [5,7‐dihydroxy‐2‐(4‐hydroxy‐3,5‐dimethoxyphenyl)‐4H‐chromen‐4‐one], a flavone, was recently established as an authentic monomer in grass…”
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4
Reductive Cleavage Method for Quantitation of Monolignols and Low‐Abundance Monolignol Conjugates
Published in ChemSusChem (25-05-2018)“…As interest in biomass utilization has grown, the manipulation of lignin biosynthesis has received significant attention, such that recent work has demanded…”
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5
Singlet Exciton Fission in Polycrystalline Thin Films of a Slip-Stacked Perylenediimide
Published in Journal of the American Chemical Society (02-10-2013)“…The crystal structure of N,N-bis(n-octyl)-2,5,8,11-tetraphenylperylene-3,4:9,10-bis(dicarboximide), 1, obtained by X-ray diffraction reveals that 1 has a…”
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6
Downregulation of p‐COUMAROYL ESTER 3‐HYDROXYLASE in rice leads to altered cell wall structures and improves biomass saccharification
Published in The Plant journal : for cell and molecular biology (01-09-2018)“…Summary p‐Coumaroyl ester 3‐hydroxylase (C3′H) is a key enzyme involved in the biosynthesis of lignin, a phenylpropanoid polymer that is the major constituent…”
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7
Eukaryotic Acquisition of a Bacterial Operon
Published in Cell (07-03-2019)“…Operons are a hallmark of bacterial genomes, where they allow concerted expression of functionally related genes as single polycistronic transcripts. They are…”
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p‐Coumaroyl‐CoA:monolignol transferase (PMT) acts specifically in the lignin biosynthetic pathway in Brachypodium distachyon
Published in The Plant journal : for cell and molecular biology (01-03-2014)“…Grass lignins contain substantial amounts of p‐coumarate (pCA) that acylate the side‐chains of the phenylpropanoid polymer backbone. An acyltransferase, named…”
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9
Identification and characterization of a set of monocot BAHD monolignol transferases
Published in Plant physiology (Bethesda) (03-05-2022)“…Plant BAHD acyltransferases perform a wide range of enzymatic tasks in primary and secondary metabolism. Acyl-CoA monolignol transferases, which couple a CoA…”
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10
Magnetic Field Sensing Beyond the Standard Quantum Limit Using 10-Spin NOON States
Published in Science (American Association for the Advancement of Science) (29-05-2009)“…Quantum entangled states can be very delicate and easily perturbed by their external environment. This sensitivity can be harnessed in measurement technology…”
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11
Assessing the Viability of Recovery of Hydroxycinnamic Acids from Lignocellulosic Biorefinery Alkaline Pretreatment Waste Streams
Published in ChemSusChem (21-04-2020)“…The hydroxycinnamic acids p‐coumaric acid (pCA) and ferulic acid (FA) add diversity to the portfolio of products produced by using grass‐fed lignocellulosic…”
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12
Defining the Diverse Cell Populations Contributing to Lignification in Arabidopsis Stems
Published in Plant physiology (Bethesda) (01-06-2017)“…Many land plants evolved tall and sturdy growth habits due to specialized cells with thick lignified cell walls: tracheary elements that function in water…”
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13
A bacterial biosynthetic pathway for methylated furan fatty acids
Published in The Journal of biological chemistry (17-07-2020)“…Fatty acids play many important roles in cells and also in industrial processes. Furan fatty acids (FuFAs) are present in the lipids of some plant, fish, and…”
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14
Highly Decorated Lignins in Leaf Tissues of the Canary Island Date Palm Phoenix canariensis
Published in Plant physiology (Bethesda) (01-11-2017)“…The cell walls of leaf base tissues of the Canary Island date palm (Phoenix canariensis) contain lignins with the most complex compositions described to date…”
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15
Naturally p-Hydroxybenzoylated Lignins in Palms
Published in Bioenergy research (01-09-2015)“…The industrial production of palm oil concurrently generates a substantial amount of empty fruit bunch (EFB) fibers that could be used as a feedstock in a…”
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16
Symmetry and dynamics of molecular rotors in amphidynamic molecular crystals
Published in Proceedings of the National Academy of Sciences - PNAS (24-08-2010)“…Rotary biomolecular machines rely on highly symmetric supramolecular structures with rotating units that operate within a densely packed frame of reference,…”
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Variation in energy sorghum hybrid TX08001 biomass composition and lignin chemistry during development under irrigated and non-irrigated field conditions
Published in PloS one (23-04-2018)“…This study was conducted to document the extent and basis of compositional variation of shoot biomass of the energy Sorghum bicolor hybrid TX08001 during…”
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Overexpression of a Sugarcane BAHD Acyltransferase Alters Hydroxycinnamate Content in Maize Cell Wall
Published in Frontiers in plant science (21-04-2021)“…The purification of hydroxycinnamic acids [ -coumaric acid ( CA) and ferulic acid (FA)] from grass cell walls requires high-cost processes. Feedstocks with…”
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19
Ultrafast entangling gates between nuclear spins using photoexcited triplet states
Published in Nature physics (01-08-2012)“…Nuclear spin is seen as a robust qubit. Electrons can be used to ‘read’ to the nuclear state, but their presence causes decoherence. Researchers now show that…”
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Exponential Distance Dependence of Photoinitiated Stepwise Electron Transfer in Donor–Bridge–Acceptor Molecules: Implications for Wirelike Behavior
Published in Journal of the American Chemical Society (14-03-2012)“…Donor–bridge–acceptor (D–B–A) systems in which a 3,5-dimethyl-4-(9-anthracenyl)julolidine (DMJ-An) chromophore and a naphthalene-1,8:4,5-bis(dicarboximide)…”
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