Search Results - "Kamer, Paul C. J"
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Catalytic reductive aminations using molecular hydrogen for synthesis of different kinds of amines
Published in Chemical Society reviews (07-09-2020)“…Reductive aminations constitute an important class of reactions widely applied in research laboratories and industries for the synthesis of amines as well as…”
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Advanced Model Compounds for Understanding Acid-Catalyzed Lignin Depolymerization: Identification of Renewable Aromatics and a Lignin-Derived Solvent
Published in Journal of the American Chemical Society (20-07-2016)“…The development of fundamentally new approaches for lignin depolymerization is challenged by the complexity of this aromatic biopolymer. While overly…”
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Phosphite-Containing Ligands for Asymmetric Catalysis
Published in Chemical reviews (09-03-2011)“…Van Leeuwen et al examine the use of phosphite-containing ligands for asymmetric catalysis…”
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Ultra-small cobalt nanoparticles from molecularly-defined Co-salen complexes for catalytic synthesis of amines
Published in Chemical science (Cambridge) (21-03-2020)“…We report the synthesis of in situ generated cobalt nanoparticles from molecularly defined complexes as efficient and selective catalysts for reductive…”
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Wide-Bite-Angle Diphosphine Ligands in Thermally Activated Delayed Fluorescent Copper(I) Complexes: Impact on the Performance of Electroluminescence Applications
Published in Inorganic chemistry (19-07-2021)“…We report a series of seven cationic heteroleptic copper(I) complexes of the form [Cu(P^P)(dmphen)]BF4, where dmphen is 2,9-dimethyl-1,10-phenanthroline…”
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Facile synthesis of supported Ru-Triphos catalysts for continuous flow application in selective nitrile reduction
Published in Chemical science (Cambridge) (21-09-2019)“…The selective catalytic hydrogenation of nitriles represents an important but challenging transformation for many homogeneous and heterogeneous catalysts…”
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Ligand Bite Angle Effects in Metal-catalyzed C−C Bond Formation
Published in Chemical reviews (09-08-2000)“…Van Leeuwen et al summarize the effect of the bite angle of bidentate ligands on the catalytic formation of carbon-to-carbon bonds. Their data show that the…”
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Simple ruthenium-catalyzed reductive amination enables the synthesis of a broad range of primary amines
Published in Nature communications (08-10-2018)“…The production of primary benzylic and aliphatic amines, which represent essential feedstocks and key intermediates for valuable chemicals, life science…”
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Encapsulation of Transition Metal Catalysts by Ligand-Template Directed Assembly
Published in Journal of the American Chemical Society (11-02-2004)“…Encapsulated transition metal catalysts are presented that are formed by templated self-assembly processes of simple building blocks such as porphyrins and…”
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Organocatalytic Chemoselective Primary Alcohol Oxidation and Subsequent Cleavage of Lignin Model Compounds and Lignin
Published in ChemSusChem (10-07-2017)“…A one‐pot two‐step degradation of lignin β‐O‐4 model compounds initiated by preferred oxidation of the primary over the secondary hydroxyl groups with a…”
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Synthesis and Reactivity of Chiral, Wide-Bite-Angle, Hybrid Diphosphorus Ligands
Published in European journal of inorganic chemistry (01-04-2014)“…Effective and modular synthetic approaches toward phosphine–phosphite ligands and phosphine–phosphonite ligands featuring a diphenyl ether backbone have been…”
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Alcoholysis of Acylpalladium(II) Complexes Relevant to the Alternating Copolymerization of Ethene and Carbon Monoxide and the Alkoxycarbonylation of Alkenes: the Importance of Cis-Coordinating Phosphines
Published in Journal of the American Chemical Society (07-05-2003)“…The mechanism and kinetics of the solvolysis of complexes of the type [(L−L)Pd(C(O)CH3)(S)]+[CF3SO3]- (L−L = diphosphine ligand, S = solvent, CO, or donor atom…”
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P‑Chirogenic Diphosphazanes with Axially Chiral Substituents and Their Use in Rh-Catalyzed Asymmetric Hydrogenation
Published in Journal of organic chemistry (20-11-2020)“…A convenient synthesis of enantiopure P-chirogenic diphosphazanes incorporating bulky bisphenol and 1,1′-bi-2-naphthol-derived substituents via the…”
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Bioinspired Catalyst Design and Artificial Metalloenzymes
Published in Chemistry : a European journal (18-04-2011)“…Many bioinspired transition‐metal catalysts have been developed over the recent years. In this review the progress in the design and application of ligand…”
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Site-Isolation Effects in a Dendritic Nickel Catalyst for the Oligomerization of Ethylene
Published in Journal of the American Chemical Society (17-11-2004)“…Dendrimers, specifically suited to construct site-isolated groups due to their well-defined hyperbranched structure, have been used as a ligand design element…”
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Dendrimers as Support for Recoverable Catalysts and Reagents
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Nylon Intermediates from Bio‐Based Levulinic Acid
Published in Angewandte Chemie International Edition (11-03-2019)“…Use of ZrO2/SiO2 as a solid acid catalyst in the ring‐opening of biobased γ‐valerolactone with methanol in the gas phase leads to mixtures of methyl 2‐, 3‐,…”
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Enzyme Activity by Design: An Artificial Rhodium Hydroformylase for Linear Aldehydes
Published in Angewandte Chemie International Edition (23-10-2017)“…Artificial metalloenzymes (ArMs) are hybrid catalysts that offer a unique opportunity to combine the superior performance of natural protein structures with…”
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Reversible C−H Activation, Facile C−B/B−H Metathesis and Apparent Hydroboration Catalysis by a Dimethylxanthene‐Based Frustrated Lewis Pair
Published in Chemistry : a European journal (20-07-2018)“…A dimethylxanthene‐based phosphine/borane frustrated Lewis pair (FLP) is shown to effect reversible C−H activation, cleaving phenylacetylene, PhCCH, to give an…”
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Parallel Synthesis and Screening of Polymer-Supported Phosphorus-Stereogenic Aminophosphane-Phosphite and -Phosphinite Ligands
Published in Angewandte Chemie (International ed.) (18-08-2008)“…Bound to Ps: An efficient, rapid, parallel solid‐phase synthesis of a series of resin‐bound P‐stereogenic aminophosphane–phosphinite and –phosphite ligands is…”
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