Search Results - "Kamat, Medha N"

Chemoselective Synthesis of Oligosaccharides of 2-Deoxy-2-aminosugars by Bongat, Aileen F. G, Kamat, Medha N, Demchenko, Alexei V

“…Along with the application of the S-benzoxazolyl glycosides to the high-yielding synthesis of disaccharides of the 2-amino-2-deoxy series, chemoselective…”
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Chemical Synthesis of a Hyaluronic Acid Decasaccharide by Lu, Xiaowei, Kamat, Medha N, Huang, Lijun, Huang, Xuefei

“…The chemical synthesis of a hyaluronic acid decasaccharide using the preactivation-based chemoselective glycosylation strategy is described. Assembly of large…”
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Direct Synthesis of Diastereomerically Pure Glycosyl Sulfonium Salts by Mydock, Laurel K, Kamat, Medha N, Demchenko, Alexei V

“…It is reported that stable glycosyl sulfonium salts can be generated via direct anomeric S-methylation of ethylthioglycosides. Mechanistically, this pathway…”
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A Concise Synthesis of the Repeating Unit of Capsular Polysaccharide Staphylococcus aureus Type 8 by Visansirikul, Satsawat, Yasomanee, Jagodige P, Pornsuriyasak, Papapida, Kamat, Medha N, Podvalnyy, Nikita M, Gobble, Chase P, Thompson, Melissa, Kolodziej, Stephen A, Demchenko, Alexei V

“…The first synthesis of the repeating unit of S. aureus capsular polysaccharide type 8 is described. The repeating unit is an unusual trisaccharide sequence of…”
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Versatile Synthesis and Mechanism of Activation of S-Benzoxazolyl Glycosides by Kamat, Medha N, Rath, Nigam P, Demchenko, Alexei V

“…As a part of a program for developing new efficient procedures for stereoselective glycosylation, a range of S-benzoxazolyl (SBox) glycosides have been…”
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Revisiting the Armed−Disarmed Concept Rationale:  S-Benzoxazolyl Glycosides in Chemoselective Oligosaccharide Synthesis by Kamat, Medha N, Demchenko, Alexei V

“…It has been discovered that 2-O-benzyl-3,4,6-tri-O-acyl SBox glycosides are significantly less reactive than even “disarmed” peracylated derivatives. This…”
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S-Benzoxazolyl as a Stable Protecting Moiety and a Potent Anomeric Leaving Group in Oligosaccharide Synthesis by Kamat, Medha N, De Meo, Cristina, Demchenko, Alexei V

“…As a part of a program for developing new versatile building blocks for stereoselective glycosylation and convergent oligosaccharide synthesis, we demonstrated…”
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Application of Glycosyl Thioimidates in Solid-Phase Oligosaccharide Synthesis by Parlato, M. Cristina, Kamat, Medha N, Wang, Haisheng, Stine, Keith J, Demchenko, Alexei V

“…Two stable classes of thioimidoyl derivatives, S-benzoxazolyl (SBox) and S-thiazolinyl (STaz) glycosides, were investigated as glycosyl donors for solid-phase…”
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Remote Participation-Assisted Synthesis of β-Mannosides by De Meo, Cristina, Kamat, Medha N., Demchenko, Alexei V.

“…The stereoselectivity of β‐mannosylation can be improved with the use of a participating moiety at C‐4 (O‐anisoyl, O‐thiocarbamoyl). This improvement was…”
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