Search Results - "Kalogeras, Ioannis M."
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Prediction of glass transition temperatures: Binary blends and copolymers
Published in Materials letters (30-06-2008)“…Glass transition temperature T g values characterize pure polymers, polymer blends, copolymers, as well as matrices in polymer-based composites. T g s as…”
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Glass transition temperatures in binary polymer blends
Published in Journal of polymer science. Part B, Polymer physics (01-01-2009)“…Knowledge of the glass transition temperatures (Tgs) as function of composition reflects miscibility (or lack of it) and is decisive for virtually all…”
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A novel approach for analyzing glass-transition temperature vs. composition patterns: Application to pharmaceutical compound + polymer systems
Published in European journal of pharmaceutical sciences (18-04-2011)“…In medicine, polymer-based materials are commonly used as excipients of poorly water-soluble drugs. The success of the encapsulation, as well as the…”
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Contradicting perturbations of the segmental and secondary relaxation dynamics of polymer strands constrained in nanopores
Published in Acta materialia (01-04-2005)“…The glass transition and the sub-glassy relaxations in 1 mm bulk-like poly(methyl methacrylate) (PMMA) films and PMMA confined in ∼5 nm silica pores were…”
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Description and molecular interpretations of anomalous compositional dependences of the glass transition temperatures in binary organic mixtures
Published in Thermochimica acta (20-09-2010)“…The present study explores the applicability of a three-parameter equation: T g = φ 1 T g,1 + (1 − φ 1) T g,2 + φ 1(1 − φ 1)[ a 0 + a 1(2 φ 1–1) + a 2(2 φ 1–1)…”
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Nanoscale Confinement Effects on the Relaxation Dynamics in Networks of Diglycidyl Ether of Bisphenol-A and Low-Molecular-Weight Poly(ethylene oxide)
Published in The journal of physical chemistry. B (22-03-2007)“…Thermoplastic poly(ethylene oxide) (PEO) (M w(PEO) ≈ 4000) has been used to prepare thermosetting nanocomposites incorporating diglycidyl ether of bisphenol A…”
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The diverse effect of antiplasticizer in the molecular dynamics of an organic dye-doped polymer observed at different motional lengthscales
Published in European polymer journal (01-05-2009)“…Complementary thermal analysis techniques were used to study blending-induced perturbations in polymer dynamics pertaining to different motional lengthscales…”
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Free-Space and Intermolecular Interaction Effects on the Local-Chain Rotational Relaxation Dynamics in Dye + Polymer Lasing Materials
Published in Macromolecules (10-02-2004)“…Dielectric relaxation spectroscopy (DRS) and thermally stimulated depolarization currents (TSDC) are combined to analyze the secondary (β) side-chain…”
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Thermally stimulated currents of poly(methyl methacrylate): Comments on the molecular origin of a Debye-type signal between the α- and β-relaxation modes
Published in Journal of polymer science. Part B, Polymer physics (15-02-2004)“…Several variants of thermally stimulated currents (TSCs) have been used to characterize an unusual room‐temperature (RT) Debye‐type relaxation mode (denoted…”
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Dielectric Probe of Intermolecular Interactions in Poly(methyl methacrylate) (PMMA) and PMMA + SiO2 Matrixes Doped with Luminescent Organics
Published in The journal of physical chemistry. B (16-08-2001)“…Modifications in the molecular dynamics of the side-chain relaxation in poly(methyl methacrylate) (PMMA) have been recorded by monitoring the thermally…”
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Dielectric properties of cured epoxy resin + poly(ethylene oxide) blends
Published in Journal of non-crystalline solids (15-09-2005)“…Epoxy resin (ER) + poly(ethylene oxide) (PEO) blends cured with 4,4′-diaminodiphenyl-methane were studied by thermally stimulated currents and dielectric…”
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Journal Article Conference Proceeding -
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Glass transitions in binary drug + polymer systems
Published in Materials letters (31-12-2009)“…To evaluate miscibility, glass transition temperatures T g have been determined for two binary polymer (Plasdone S-630 copovidone or Eudragit® E) + drug…”
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Side-chain motions in poly(methyl methacrylate)+SiO 2 hosts of fluorescent dyes studied by thermally stimulated discharge currents: effects of confinement and blending
Published in Polymer (Guilford) (2003)“…The thermally stimulated discharge (TSD) currents technique has been used to study different types of inter- and intra-molecular interactions between the…”
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Encapsulation of hydrophobic drugs in a copolymer: Glass transition behavior and miscibility evaluation
Published in Polymer engineering and science (01-08-2011)“…The knowledge of glass transition temperatures Tg in drug + polymer systems is indispensable for drug encapsulation. Tg values as a function of composition…”
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Journal Article Conference Proceeding -
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Effects of blending with fluorescing molecules on the dynamics of the β , α , and α ′ relaxations observed in poly(methyl methacrylate)
Published in Applied physics letters (23-10-2006)“…Perturbations in typical dielectric or calorimetric features of the molecular relaxation dynamics in amorphous poly(methyl methacrylate) and two blends with a…”
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Thermophysical Properties and Molecular Relaxations in Cured Epoxy Resin + PEO Blends: Observations on Factors Controlling Miscibility
Published in Macromolecular chemistry and physics (19-05-2006)“…Thermophysical properties and molecular relaxations in aromatic amine‐cured diglycidyl ether of bisphenol‐A (DGEBA) epoxy oligomer and poly(ethylene oxide)…”
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