Search Results - "Kale, Balaji S."
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Gold-Catalyzed [4 + 1]-Annulation Reactions between 1,4-Diyn-3-ols and Isoxazoles To Construct a Pyrrole Core
Published in Organic letters (06-07-2018)“…This work reports gold-catalyzed [4 + 1]-annulation reactions between 1,4-diyn-3-ols and isoxazoles or benzisoxazoles to yield pyrrole derivatives. The…”
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A Sequential Route to Cyclopentenes from 1,6‐Enynes and Diazo Ketones through Gold and Rhodium Catalysis
Published in Advanced synthesis & catalysis (02-02-2017)“…This work reports the construction of cyclopentene cores from 1,6‐enynes and aryl diazo ketones through two new reaction sequences involving initial…”
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Gold(I)-Catalyzed Oxidative 1,4-Additions of 3‑En-1-ynamide with Nitrones via Carbon- versus Nitrogen-Addition Chemoselectivity
Published in Organic letters (19-02-2021)“…This work reports gold-catalyzed 1,4-oxofunctionalizations of 3-en-1-ynamides with nitrones, yielding two distinct E-configured products. We obtained…”
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Gold-Catalyzed Aromatizations of 3‑Ene-5-siloxy-1,6-diynes with Nitrosoarenes To Enable 1,4-N,O-Functionalizations: One-Pot Construction of 4‑Hydroxy-3-aminobenzaldehyde Cores
Published in Organic letters (18-10-2019)“…This work describes gold-catalyzed aromatizations of 3-ene-5-siloxy-1,6-diynes with nitrosoarenes to form 4-hydroxy-3-aminobenzaldehyde derivatives,…”
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Gold‐Catalyzed Oxidative Cross‐Coupling Reactions among Two Distinct Arenes and One Gold Carbene with Phosphoric Acids as Cocatalysts
Published in Advanced synthesis & catalysis (22-12-2020)“…Gold‐catalyzed oxidative cross‐coupling reactions of two distinct arenes with one gold carbene furnish triarylmethane products. Notably, competitive…”
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Gold-Catalyzed N,O‑Functionalizations of 6‑Allenyl-1-ynes with N‑Hydroxyanilines To Construct Benzo[b]‑azepin-4-one Cores
Published in Organic letters (06-10-2017)“…Gold-catalyzed reactions of 6-allen-1-ynes with N-hydroxyanilines afford thermally stable benzoazepin-4-ones in anti-selectivity; these anti-configured…”
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Lipase mediated separation of triterpene structural isomers, α- and β-amyrin
Published in Tetrahedron letters (07-05-2014)“…Pentacyclic triterpenoids α- and β-amyrin possess a wide range of biological and pharmacological activities. High structural similarity between these two…”
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