Search Results - "Kadyrov, Renat"
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Low Catalyst Loading in Ring-Closing Metathesis Reactions
Published in Chemistry : a European journal (14-01-2013)“…An efficient procedure is described for ring‐closing metathesis reactions. A conversion of 95 % for diethyl diallylmalonate in dilute solution could be…”
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2
Olefin Metathesis: Catalyst Inhibition as a Result of Isomerization
Published in ChemCatChem (07-01-2016)“…Ring‐closing metathesis of N,N‐diallyl‐tosylamide and allyl‐N‐10‐undecenenoyl‐l‐proline by using low levels of Ru‐catalyst loading were investigated. The…”
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3
Practical Imidazole‐Based Phosphine Ligands for Selective Palladium‐Catalyzed Hydroxylation of Aryl Halides
Published in Angewandte Chemie International Edition (19-01-2009)“…The phenol countdown: Novel imidazole‐based phosphine ligands are synthesized on scales up to 100 g by a convenient lithiation–phosphorylation method. The…”
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4
Highly Enantioselective Hydrogen-Transfer Reductive Amination: Catalytic Asymmetric Synthesis of Primary Amines
Published in Angewandte Chemie International Edition (17-11-2003)“…Ammonium formate is the hydrogen source in the catalytic asymmetric reductive amination of ketones presented here (Leuckart–Wallach‐type reaction). The…”
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5
Comorbid Complicated Course of Vegetative Diabetic Polyneuropathy. Clinical Case. Multidisciplinary Approach in Treatment
Published in BioNanoScience (01-06-2021)“…Diabetic polyneuropathy is the most difficult to diagnose manifestation of diabetes mellitus. It affects many organs and systems and exacerbates complications…”
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6
The doping effect of fluorinated aromatic hydrocarbon solvents on the performance of common olefin metathesis catalysts: application in the preparation of biologically active compounds
Published in Chemical communications (Cambridge, England) (01-01-2008)“…Aromatic fluorinated hydrocarbons, used as solvents for olefin metathesis reactions, catalysed by standard commercially available Ru precatalysts, allow…”
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7
Scalable Synthesis of 1,3,4,5-Tetraaryl Imidazolium Salts as Precursors of Sterically Demanding N-Heterocyclic Carbenes
Published in SynOpen (2017) (01-01-2020)“…Abstract A convenient, large-scale, and cost-efficient synthesis of 4,5-diarylsubstituted N , N -diarylimidazolium salts is described. A variety of…”
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Fine-tuning NHC ligands for ruthenium-catalyzed hydrogenation of carboxylic esters to alcohols
Published in Journal of catalysis (01-10-2023)“…[Display omitted] •Ru-complexes and imidazolium salts bearing N-cyclohexyl, N-cycloheptyl and N-cyclooctyl enable reduction of esters to alcohols at 40°C.•The…”
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9
Ruthenium Olefin Metathesis Catalysts Containing Six-Membered Sulfone and Sulfonamide Chelating Rings
Published in Organometallics (14-03-2011)“…The preparation and X-ray structure characterization of new olefin metathesis initiators containing sulfone- and sulfonamide-substituted benzylidene ligands…”
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10
Hydrogenolysis of Carboxylic Ortho Esters
Published in Journal of organic chemistry (07-10-2022)“…It is demonstrated for the first time that carboxylic ortho esters may be reduced to acetals using hydrogen as the reducing agent. Hydrogenolysis was performed…”
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11
A Highly Tunable Family of Chiral Bisphospholanes for Rh-Catalyzed Enantioselective Hydrogenation Reactions
Published in Chemistry : a European journal (23-06-2006)“…A set of 16 new and closely related bisphospholane ligands have been prepared by using a highly flexible and convergent approach. Each synthesis can be…”
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12
Reduction of Amides to Amines under Mild Conditions via Catalytic Hydrogenation of Amide Acetals and Imidates
Published in Advanced synthesis & catalysis (11-01-2019)“…A simple and general protocol was developed for selective conversion of amides into amines. Amides were converted into amide acetals and imido esters by…”
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13
Synthesis of Ru alkylidene complexes
Published in Beilstein journal of organic chemistry (21-01-2011)“…The present work describes the robust synthesis of Ru alkylidene complexes (PCy(3))(2)Cl(2)Ru=CHR - precursors for metathesis catalysts. Moreover, the dynamic…”
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14
Hydrogenolysis of Amide Acetals and Iminium Esters
Published in ChemCatChem (09-01-2018)“…Amide acetals and iminium esters were hydrogenated into amines under very mild reaction conditions over common hydrogenation catalysts. This finding provides a…”
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15
Reductive Alkylation of Amines with Carboxylic Ortho Esters
Published in Advanced synthesis & catalysis (19-08-2020)“…We have demonstrated for the first time that carboxylic ortho esters could be used as an alkylating agent in the reductive alkylation of amines. A variety of…”
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16
Direct Reductive Amination versus Hydrogenation of Intermediates -A Comparison
Published in Advanced synthesis & catalysis (01-04-2004)“…The direct reductive amination of acetophenone with benzylamine or piperidine was studied in comparison with the hydrogenation of possible intermediates like a…”
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A Scrutiny on the Reductive Amination of Carbonyl Compounds Catalyzed by Homogeneous Rh(I) Diphosphane Complexes
Published in Advanced synthesis & catalysis (01-02-2002)“…The reductive amination of a series of aldehydes with secondary amines and H2 in the presence of a homogeneous Rh‐diphosphane catalyst was studied in order to…”
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18
Economic preparation of 1,3-diphenyl-1,3-bis(diphenylphosphino)propane: a versatile chiral diphosphine ligand for enantioselective hydrogenations
Published in Tetrahedron: asymmetry (19-09-2003)“…The enantioselective hydrogenation of 1,3-diarylpropane-1,3-diones with chiral Ru(II)-diphosphine catalyst has been studied. In a first approach it was found,…”
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19
Oxidative Cleavage of Long Chain Olefins to Carboxylic Acids with Hydrogen Peroxide
Published in Topics in catalysis (01-11-2014)“…The role of phase-transfer catalysts (PTC) (ammonium and phosphonium salts) with various anions on the biphasic oxidative cleavage of long chain olefins with…”
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20
Protective Action of Xymedon on the Morphological Structures of the Pancreas of the Rat in Ischemia
Published in BioNanoScience (01-09-2018)“…Pathologic processes associated with the effect of ischemia on the pancreas are not yet fully investigated and searching for ways of reduction of the damaging…”
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