Search Results - "Kadlecek, Daniel E"
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Transition-Metal-Promoted Reactions of Boron Hydrides. 16. Platinum- and Palladium-Catalyzed Olefin Addition and Olefin Dehydrogenative Borylation Reactions of arachno-6,8-C2B7H13: Syntheses and Structural Characterizations of 7-R-arachno-6,8-C2B7H12 and 7-(trans-R-CHCH)-arachno-6,8-C2B7H12
Published in Journal of the American Chemical Society (08-11-2000)Get full text
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Reactions of arachno-6,8-C2B7H12- with electron deficient olefins: syntheses of cyano-substituted carboranes
Published in Inorganic chemistry (22-03-2004)“…The syntheses of new cyano-substituted derivatives of arachno-6,8-C(2)B(7)H(13) have been achieved through the addition reactions of the…”
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Syntheses, Crystallographic/Computational Characterizations, and Reactions of the First 10-Vertex arachno- and nido-Phosphamonocarbaboranes
Published in Journal of the American Chemical Society (08-01-2003)“…A synthetic sequence involving the initial reaction of a substituted phosphorus dihalide (RPCl(2), R = CH(3), C(6)H(5)) with the arachno-CB(8)H(13)(-) (1-)…”
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Syntheses, Crystallographic/Computational Characterizations, and Reactions of the First 10-Vertex a rachno- and n ido-Phosphamonocarbaboranes
Published in Journal of the American Chemical Society (08-01-2003)“…A synthetic sequence involving the initial reaction of a substituted phosphorus dihalide (RPCl2, R = CH3, C6H5) with the arachno-CB8H13 - (1 - ) monoanion…”
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Dications of Fluorenylidenes: Conformational and Electronic Effects on the Paratropicity/Antiaromaticity of Fluorenyl Cations with Cyclic Substituents
Published in Journal of organic chemistry (26-12-1997)“…Oxidation of tetrabenzofulvalene derivatives 1−5 containing fluorenylidene and 5−7-membered rings resulted in the formation of dications which are effectively…”
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Dications of Tetrabenzofulvalenes. Paratropicity and .sigma. Donation in Perpendicular Antiaromatic Systems
Published in Journal of the American Chemical Society (01-12-1994)Get full text
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Synthesis of the arachno-4-CB(8)H(12)(2)(-) monocarbaborane dianion and NMR/computational studies of the fluxional processes observed in the isoelectronic nine-vertex arachno anions: arachno-4-CB(8)H(12)(2)(-), arachno-4-CB(8)H(13)(-), and arachno-4-SB(8)H(11)(-)
Published in Inorganic chemistry (12-08-2002)“…The new monocarbaborane dianion, arachno-4-CB(8)H(12)(2)(-) has been synthesized from the reaction of arachno-4-CB(8)H(14) with 2 equiv of NaH in polar…”
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Synthesis of the arachno -4-CB 8 H 12 2 - Monocarbaborane Dianion and NMR/Computational Studies of the Fluxional Processes Observed in the Isoelectronic Nine-Vertex arachno Anions: arachno -4-CB 8 H 12 2 - , arachno -4-CB 8 H 13 - , and arachno -4-SB 8 H 11
Published in Inorganic chemistry (01-08-2002)Get full text
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Reactions of a rachno -6,8-C 2 B 7 H 12 - with Electron Deficient Olefins: Syntheses of Cyano-Substituted Carboranes
Published in Inorganic chemistry (01-03-2004)Get full text
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Synthesis of the arachno-4-CB8H122- Monocarbaborane Dianion and NMR/Computational Studies of the Fluxional Processes Observed in the Isoelectronic Nine-Vertex arachno Anions: arachno-4-CB8H122-, arachno-4-CB8H13-, and arachno-4-SB8H11
Published in Inorganic chemistry (12-08-2002)Get full text
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Syntheses and structural characterizations of endo-eta(1)-, exo-eta(1)-, eta(4)-, eta(5)-, and eta(6)-metallaphosphamonocarbaborane complexes derived from a versatile new polyborane ligand: exo-6-R-arachno-6,7-PCB(8)H(12)
Published in Journal of the American Chemical Society (08-01-2003)“…Deprotonation of the phosphamonocarbaborane, exo-6-R-arachno-6,7-PCB(8)H(12) (R = Ph 1a or Me 1b), yields exo-6-R-arachno-6,7-PCB(8)H(11)(-), which when…”
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Syntheses and Structural Characterizations of e ndo- η 1 -, exo -η 1 -, η 4 -, η 5 -, and η 6 -Metallaphosphamonocarbaborane Complexes Derived from a Versatile New Polyborane Ligand: e xo -6-R- a rachno -6,7-PCB 8 H 12
Published in Journal of the American Chemical Society (01-01-2003)Get full text
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Transition-Metal-Promoted Reactions of Boron Hydrides. 16. Platinum- and Palladium-Catalyzed Olefin Addition and Olefin Dehydrogenative Borylation Reactions of a rachno -6,8-C 2 B 7 H 13 : Syntheses and Structural Characterizations of 7-R- a rachno -6,8-C 2 B 7 H 12 and 7-( trans -R-CHCH)- a rachno -6,8-C 2 B 7 H 12
Published in Journal of the American Chemical Society (01-11-2000)Get full text
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Hybrid diborolyl/carbaboranyl triple-decker compounds: [(η 5-pentamethylcyclopentdienyl)ruthenium(μ,η 5-1,3-diborolyl)rhodiumcarbaboranyl] complexes
Published in Journal of organometallic chemistry (01-12-2000)“…Reaction of the violet sandwich [(η 5-C 5Me 5)Ru{η 5-(CMe) 2(BMe) 2(CMe)}] with [(C 2H 4) 2RhCl] 2 generates the tetranuclear complex [(η 5-C 5Me 5)Ru{μ,η…”
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Synthesis of the arachno-4-CB8H12 2- Monocarbaborane Dianion and NMR/Computational Studies of the Fluxional Processes Observed in the Isoelectronic Nine-Vertex arachno Anions: arachno-4-CB8H12 2-, arachno-4-CB8H13 -, and arachno-4-SB8H11
Published in Inorganic chemistry (12-08-2002)“…The new monocarbaborane dianion, arachno-4-CB8H12 2- has been synthesized from the reaction of arachno-4-CB8H14 with 2 equiv of NaH in polar solvents. DFT/GIAO…”
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Reactions of a rachno-6,8-C2B7H12 - with Electron Deficient Olefins: Syntheses of Cyano-Substituted Carboranes
Published in Inorganic chemistry (22-03-2004)“…The syntheses of new cyano-substituted derivatives of arachno-6,8-C2B7H13 have been achieved through the addition reactions of the arachno-6,8-C2B7H12 - (1 - )…”
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Transition-Metal-Promoted Reactions of Boron Hydrides. 16. Platinum- and Palladium-Catalyzed Olefin Addition and Olefin Dehydrogenative Borylation Reactions of a rachno-6,8-C2B7H13: Syntheses and Structural Characterizations of 7-R-a rachno-6,8-C2B7H12 and 7-(trans-R-CHCH)-a rachno-6,8-C2B7H12
Published in Journal of the American Chemical Society (08-11-2000)“…The chloroplatinic acid or platinum(II) bromide-catalyzed reaction of arachno-6,8-C2B7H13 with ethylene results in hydroboration to yield the single product…”
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