Search Results - "KRZYSTEK, J"
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High-frequency and high-field electron paramagnetic resonance (HFEPR): a new spectroscopic tool for bioinorganic chemistry
Published in Journal of biological inorganic chemistry (01-03-2014)“…This minireview describes high-frequency and high-field electron paramagnetic resonance (HFEPR) spectroscopy in the context of its application to bioinorganic…”
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Slow Magnetic Relaxation in a CoII-YIII Single-Ion Magnet with Positive Axial Zero-Field Splitting
Published in Angewandte Chemie International Edition (26-08-2013)“…A magnetic Co‐production: The complex [Co(μ‐L)(μ‐OAc)Y(NO3)2] (see structure O red, N blue, C gray), in which the CoII ion exhibits a D value of approximately…”
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Slow magnetic relaxation in a Co(II)-Y(III) single-ion magnet with positive axial zero-field splitting
Published in Angewandte Chemie International Edition (26-08-2013)Get full text
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Multi-frequency, high-field EPR as a powerful tool to accurately determine zero-field splitting in high-spin transition metal coordination complexes
Published in Coordination chemistry reviews (01-09-2006)“…Electron paramagnetic resonance at multiple, high frequencies (95–700 GHz) and at correspondingly high magnetic fields (up to 25 T), known as HFEPR, is a…”
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Magnetic Anisotropy of Tetrahedral Co II Single-Ion Magnets: Solid-State Effects
Published in Inorganic chemistry (03-10-2016)“…This study reports the static and dynamic magnetic characterization of two mononuclear tetrahedral Co complexes, [Co{ Pr P(E)NP(E) Pr } ], where E = S (CoS )…”
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Incorporation of Cr III into a Keggin Polyoxometalate as a Chemical Strategy to Stabilize a Labile {Cr III O 4 } Tetrahedral Conformation and Promote Unattended Single-Ion Magnet Properties
Published in Journal of the American Chemical Society (19-02-2020)“…Polyoxometalates (POMs) provide rigid and highly symmetric coordination sites and can be used as a strategy for the stabilization of magnetic ions. Herein, we…”
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Haldane topological spin-1 chains in a planar metal-organic framework
Published in Nature communications (06-09-2023)“…Haldane topological materials contain unique antiferromagnetic chains with symmetry-protected energy gaps. Such materials have potential applications in…”
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Coligand Effects on the Field-Induced Double Slow Magnetic Relaxation in Six-Coordinate Cobalt(II) Single-Ion Magnets (SIMs) with Positive Magnetic Anisotropy
Published in Inorganic chemistry (02-12-2019)“…Two mononuclear cobalt(II) compounds of formula [Co(dmphen)2(OOCPh)]ClO4·1/2H2O·1/2CH3OH (1) and [Co(dmbipy)2(OOCPh)]ClO4 (2) (dmphen =…”
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Zero-Field Splitting in Pseudotetrahedral Co(II) Complexes: a Magnetic, High-Frequency and -Field EPR, and Computational Study
Published in Inorganic chemistry (19-08-2013)“…Six pseudotetrahedral cobalt(II) complexes of the type [CoL2Cl2], with L = heterocyclic N-donor ligand, have been studied in parallel by magnetometry, and…”
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Guest-dependent single-ion magnet behaviour in a cobalt(ii) metal-organic framework
Published in Chemical science (Cambridge) (01-03-2016)“…Single-ion magnets (SIMs) are the smallest possible magnetic devices for potential applications in quantum computing and high-density information storage…”
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Combining HFEPR and NMR Spectroscopies to Characterize Organochromium(III) Complexes with Large Zero-Field Splitting
Published in Organometallics (13-05-2019)“…A series of three organochromium(III) complexes, based on a quinoline-substituted cyclopentadienyl ring coordinated to a CrCl2 moietyC5Me4(C9NH6)CrCl2 (1),…”
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Differential mitochondrial roles for α-synuclein in DRP1-dependent fission and PINK1/Parkin-mediated oxidation
Published in Cell death & disease (17-08-2021)“…Mitochondria are highly dynamic organelles with strict quality control processes that maintain cellular homeostasis. Within axons, coordinated cycles of…”
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Cytosine Nucleobase Ligand: A Suitable Choice for Modulating Magnetic Anisotropy in Tetrahedrally Coordinated Mononuclear Co II Compounds
Published in Inorganic chemistry (20-02-2017)“…A family of tetrahedral mononuclear Co complexes with the cytosine nucleobase ligand is used as the playground for an in-depth study of the effects that the…”
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Terahertz EPR spectroscopy using a 36-tesla high-homogeneity series-connected hybrid magnet
Published in Journal of magnetic resonance (1997) (01-08-2023)“…[Display omitted] •High-field (36 T) EPR spectrometer.•High-resolution (<1 mT) THz EPR spectroscopy.•Resolved BDPA g-tensor.•Gd spin label g-anisotropy…”
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Highly Anisotropic Rhenium(IV) Complexes: New Examples of Mononuclear Single-Molecule Magnets
Published in Journal of the American Chemical Society (18-09-2013)“…The rhenium(IV) complex (NBu4)2[ReBr4(ox)] (1) (ox = oxalate and NBu4 + = tetra-n-butylammonium cation) has been prepared and its crystal structure determined…”
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Applying Unconventional Spectroscopies to the Single‐Molecule Magnets, Co(PPh3)2X2 (X=Cl, Br, I): Unveiling Magnetic Transitions and Spin‐Phonon Coupling
Published in Chemistry : a European journal (02-08-2021)“…Large separation of magnetic levels and slow relaxation in metal complexes are desirable properties of single‐molecule magnets (SMMs). Spin‐phonon coupling…”
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Characterization of the Ligand Field in Pseudo‐Octahedral Ni(II) Complexes of Pincer‐Type Amido Ligands: Magnetism, Redox Behavior, Electronic Absorption and High‐Frequency and ‐Field EPR Spectroscopy
Published in European journal of inorganic chemistry (02-10-2023)“…The description of π‐donor amido moieties as ‘weak‐field’ ligands can belie the influence of metal‐ligand covalency on the overall ligand field of coordination…”
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Field-Induced Slow Magnetic Relaxation in a Mononuclear Manganese(III)-Porphyrin Complex
Published in Chemistry : a European journal (23-11-2015)“…We report on a novel manganese(III)–porphyrin complex with the formula [MnIII(TPP)(3,5‐Me2pyNO)2]ClO4⋅CH3CN (2; 3,5‐Me2pyNO=3,5‐dimethylpyridine N‐oxide,…”
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Reversible solvatomagnetic switching in a single-ion magnet from an entatic state
Published in Chemical science (Cambridge) (01-05-2017)“…A vast impact on molecular nanoscience can be achieved using simple transition metal complexes as dynamic chemical systems to perform specific and selective…”
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