Selective synthesis of cyclododec-2-en-1-yl ethers via palladium-catalyzed allylic substitution reaction: a kinetic study

The palladium-catalyzed reaction between isomeric cyclododec-2-en-1-yl acetates and primary aliphatic alcohols was found to result in high yields of the reaction products obtained. The selectivity with respect to cyclododec-2-en-1-yl ethers formed as reaction products ranged from 73% to 93%. The kin...

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Bibliographic Details
Published in:	Turkish journal of chemistry Vol. 38; pp. 242 - 247
Main Authors:	KOLEV, Asen, MITKOVA, Magdalena, KOTOV, Stefan, BALBOLOV, Encho
Format:	Journal Article
Language:	English
Published:	TUBITAK 2014
Subjects:	Alkoxylation, acetoxycyclododec-2-enes, kinetic model
Online Access:	Get full text
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Summary:	The palladium-catalyzed reaction between isomeric cyclododec-2-en-1-yl acetates and primary aliphatic alcohols was found to result in high yields of the reaction products obtained. The selectivity with respect to cyclododec-2-en-1-yl ethers formed as reaction products ranged from 73% to 93%. The kinetics of the reaction of acetoxycyclododec-2-enes with alcohols was studied within the temperature range of 328--358 K. A kinetic equation best fitting the experimental data was provided.
Bibliography:	http://dergipark.ulakbim.gov.tr/tbtkchem/article/view/5000022239
ISSN:	1300-0527 1303-6130 1303-6130
DOI:	10.3906/kim-1304-58