Search Results - "KNOWLES, William V"
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Identification of active Zr–WOx clusters on a ZrO2 support for solid acid catalysts
Published in Nature chemistry (01-12-2009)“…Tungstated zirconia is a robust solid acid catalyst for light alkane (C 4 –C 8 ) isomerization. Several structural models for catalytically active sites have…”
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New insights into the nature of the acidic catalytic active sites present in ZrO2-supported tungsten oxide catalysts
Published in Journal of catalysis (15-05-2008)“…An extensive series of supported WO3/ZrOx(OH)4-2x catalysts (WZrOH) were synthesized by standard aqueous impregnation of ammonium metatungstate into an…”
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Catalytic activity in individual cracking catalyst particles imaged throughout different life stages by selective staining
Published in Nature chemistry (01-11-2011)“…Fluid catalytic cracking (FCC) is the major conversion process used in oil refineries to produce valuable hydrocarbons from crude oil fractions. Because the…”
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Microspectroscopic insight into the deactivation process of individual cracking catalyst particles with basic sulfur components
Published in Applied catalysis. A, General (29-03-2012)“…[Display omitted] ► Basic sulfur poisons interact with Brønsted acid sites forming oligomeric carbocations. ► Oligomeric carbocations are coke intermediates. ►…”
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Tuning the Electronic and Molecular Structures of Catalytic Active Sites with Titania Nanoligands
Published in Journal of the American Chemical Society (21-01-2009)“…A series of supported 1−60% TiO2/SiO2 catalysts were synthesized and subsequently used to anchor surface VO x redox and surface WO x acid sites. The supported…”
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Staining of Fluid-Catalytic-Cracking Catalysts: Localising Brønsted Acidity within a Single Catalyst Particle
Published in Chemistry : a European journal (23-01-2012)“…A time‐resolved in situ micro‐spectroscopic approach has been used to investigate the Brønsted acidic properties of fluid‐catalytic‐cracking (FCC) catalysts at…”
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Manganese(II) Oxide Nanohexapods: Insight into Controlling the Form of Nanocrystals
Published in Chemistry of materials (04-04-2006)“…Cross-shaped and octahedral nanoparticles (hexapods) of MnO in size, and fragments thereof, are created in an amine/carboxylic acid mixture from manganese…”
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Identification of active Zr–WO x clusters on a ZrO 2 support for solid acid catalysts
Published in Nature chemistry (01-12-2009)Get full text
Journal Article -
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New insights into the nature of the acidic catalytic active sites present in ZrO 2-supported tungsten oxide catalysts
Published in Journal of catalysis (2008)“…An extensive series of supported WO 3/ZrO x (OH) 4−2 x catalysts (WZrOH) were synthesized by standard aqueous impregnation of ammonium metatungstate into an…”
Get full text
Journal Article -
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Identification of active Zr-WO(x) clusters on a ZrO2 support for solid acid catalysts
Published in Nature chemistry (01-12-2009)“…Tungstated zirconia is a robust solid acid catalyst for light alkane (C(4)-C(8)) isomerization. Several structural models for catalytically active sites have…”
Get full text
Journal Article