Search Results - "Kümmel, Steffen"
-
1
Continuous-Flow Stable Sulfur Isotope Analysis of Organic and Inorganic Compounds by EA-MC-ICPMS
Published in Analytical chemistry (Washington) (28-05-2024)“…Elemental analysis (EA) coupled to isotope ratio mass spectrometry (IRMS) is a well-established method to derive stable isotope ratios of sulfur (34S/32S)…”
Get full text
Journal Article -
2
Soil from a Hexachlorocyclohexane Contaminated Field Site Inoculates Wheat in a Pot Experiment to Facilitate the Microbial Transformation of β‑Hexachlorocyclohexane Examined by Compound-Specific Isotope Analysis
Published in Environmental science & technology (19-10-2021)“…β-Hexachlorocyclohexane (β-HCH) is a remnant from former HCH pesticide production. Its removal from the environment gained attention in the last few years…”
Get full text
Journal Article -
3
Humic Substance Photosensitized Degradation of Phthalate Esters Characterized by 2H and 13C Isotope Fractionation
Published in Environmental science & technology (07-02-2023)“…The photosensitized transformation of organic chemicals is an important degradation mechanism in natural surface waters, aerosols, and water films on surfaces…”
Get full text
Journal Article -
4
Uptake and Transformation of Hexachlorocyclohexane Isomers (HCHs) in Tree Growth Rings at a Contaminated Field Site
Published in Environmental science & technology (13-06-2023)“…The potential transformation of hexachlorocyclohexane isomers (HCHs) within tree trunks could have a significant impact on the use of phytoscreening. However,…”
Get full text
Journal Article -
5
Tracking the transformation of persistent organic pollutants in food webs using multi element isotope and enantiomer fractionation
Published in Journal of hazardous materials (05-05-2024)“…In order to track the transformation of persistent organic pollutants (POPs) in food webs, field experiments were conducted at two sites using stable isotope…”
Get full text
Journal Article -
6
Determination of Stable Hydrogen Isotopic Composition and Isotope Enrichment Factor at Low Hydrogen Concentration
Published in Analytical chemistry (Washington) (07-11-2023)“…Determination of stable hydrogen isotopic compositions (δ2H) is currently challenged to achieve a high detection limit for reaching the linear range where δ2H…”
Get full text
Journal Article -
7
Uptake and Metabolization of HCH Isomers in Trees Examined over an Annual Growth Period by Compound-Specific Isotope Analysis and Enantiomer Fractionation
Published in Environmental science & technology (19-07-2022)“…To understand the role of plants for natural attenuation, a field study was conducted to characterize the fate of HCH in trees over an annual growth period…”
Get full text
Journal Article -
8
Compound-Specific Isotope Analysis and Enantiomer Fractionation to Characterize the Transformation of Hexachlorocyclohexane Isomers in a Soil–Wheat Pot System
Published in Environmental science & technology (21-07-2020)“…The uptake by plants from soil is one of the first steps for hexachlorocyclohexane (HCH) isomers to enter the food web. However, the HCH transformation…”
Get full text
Journal Article -
9
Characterization of Hexachlorocyclohexane Isomer Dehydrochlorination by LinA1 and LinA2 Using Multi-element Compound-Specific Stable Isotope Analysis
Published in Environmental science & technology (06-12-2022)“…Dehydrochlorination is one of the main (thus far discovered) processes for aerobic microbial transformation of hexachlorocyclohexane (HCH) which is mainly…”
Get full text
Journal Article -
10
Direct Phototransformation of Sulfamethoxazole Characterized by Four-Dimensional Element Compound Specific Isotope Analysis
Published in Environmental science & technology (11-06-2024)“…The antibiotic sulfamethoxazole (SMX) undergoes direct phototransformation by sunlight, constituting a notable dissipation process in the environment. SMX…”
Get full text
Journal Article -
11
Compound-Specific Hydrogen Isotope Analysis of Heteroatom-Bearing Compounds via Gas Chromatography–Chromium-Based High-Temperature Conversion (Cr/HTC)–Isotope Ratio Mass Spectrometry
Published in Analytical chemistry (Washington) (15-09-2015)“…The traditional high-temperature conversion (HTC) approach toward compound-specific stable isotope analysis (CSIA) of hydrogen for heteroatom-bearing (i.e., N,…”
Get full text
Journal Article -
12
Simultaneous Compound-Specific Analysis of δ33S and δ34S in Organic Compounds by GC-MC-ICPMS Using Medium- and Low-Mass-Resolution Modes
Published in Analytical chemistry (Washington) (03-11-2020)“…Compound-specific isotope analysis of sulfur (δ34S-CSIA) in organic compounds was established in the last decade employing gas chromatography connected to…”
Get full text
Journal Article -
13
The deep-subsurface sulfate reducer Desulfotomaculum kuznetsovii employs two methanol-degrading pathways
Published in Nature communications (16-01-2018)“…Methanol is generally metabolized through a pathway initiated by a cobalamine-containing methanol methyltransferase by anaerobic methylotrophs (such as…”
Get full text
Journal Article -
14
Dual C and Cl compound-specific isotope analysis and metagenomic insights into the degradation of the pesticide methoxychlor
Published in Journal of hazardous materials (05-12-2024)“…This study investigates the use of multi-element compound-specific isotope analysis (ME-CSIA) to monitor degradation processes of methoxychlor, a persistent…”
Get full text
Journal Article -
15
Photosynthesis-driven methane production in oxic lake water as an important contributor to methane emission
Published in Limnology and oceanography (01-12-2020)“…Recent discovery of methane (CH₄) production in oxic waters challenges the conventional understanding of strict anoxic requirement for biological CH₄…”
Get full text
Journal Article -
16
Hydrogen isotope labeling unravels origin of soil-bound organic contaminant residues in biodegradability testing
Published in Nature communications (24-10-2024)“…Biodegradability testing in soil helps to identify safe synthetic organic chemicals but is still obscured by the formation of soil-bound ‘non-extractable’…”
Get full text
Journal Article -
17
Requirements for Chromium Reactors for Use in the Determination of H Isotopes in Compound-Specific Stable Isotope Analysis of Chlorinated Compounds
Published in Analytical chemistry (Washington) (04-02-2020)“…There is a strong need for careful quality control in hydrogen compound-specific stable isotope analysis (CSIA) of halogenated compounds. This arises in part…”
Get full text
Journal Article -
18
Back flux during anaerobic oxidation of butane support archaea-mediated alkanogenesis
Published in Nature communications (07-11-2024)“…Microbial formation and oxidation of volatile alkanes in anoxic environments significantly impacts biogeochemical cycles on Earth. The discovery of archaea…”
Get full text
Journal Article -
19
Hydrogen Isotope Fractionation As a Tool to Identify Aerobic and Anaerobic PAH Biodegradation
Published in Environmental science & technology (15-03-2016)“…Aerobic and anaerobic polycyclic aromatic hydrocarbon (PAH) biodegradation was characterized by compound specific stable isotope analysis (CSIA) of the carbon…”
Get full text
Journal Article -
20
Tracking deuterium uptake in hydroponically grown maize roots using correlative helium ion microscopy and Raman micro-spectroscopy
Published in Plant methods (14-07-2023)“…Investigations into the growth and self-organization of plant roots is subject to fundamental and applied research in various areas such as botany,…”
Get full text
Journal Article