Search Results - "Junqueira, João"
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Splicing the active phases of copper/cobalt-based catalysts achieves high-rate tandem electroreduction of nitrate to ammonia
Published in Nature communications (02-03-2022)“…Electrocatalytic recycling of waste nitrate (NO 3 − ) to valuable ammonia (NH 3 ) at ambient conditions is a green and appealing alternative to the Haber−Bosch…”
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B‐Cu‐Zn Gas Diffusion Electrodes for CO2 Electroreduction to C2+ Products at High Current Densities
Published in Angewandte Chemie International Edition (12-04-2021)“…Electroreduction of CO2 to multi‐carbon products has attracted considerable attention as it provides an avenue to high‐density renewable energy storage…”
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Single‐entity Electrochemistry Unveils Dynamic Transformation during Tandem Catalysis of Cu2O and Co3O4 for Converting NO3− to NH3
Published in Angewandte Chemie International Edition (13-02-2023)“…Electrochemically converting nitrate to ammonia is an essential and sustainable approach to restoring the globally perturbed nitrogen cycle. The rational…”
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Probing the Local Reaction Environment During High Turnover Carbon Dioxide Reduction with Ag‐Based Gas Diffusion Electrodes
Published in Chemistry : a European journal (01-04-2021)“…Discerning the influence of electrochemical reactions on the electrode microenvironment is an unavoidable topic for electrochemical reactions that involve the…”
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Enhanced Nitrate‐to‐Ammonia Efficiency over Linear Assemblies of Copper‐Cobalt Nanophases Stabilized by Redox Polymers
Published in Advanced materials (Weinheim) (01-08-2023)“…Renewable electricity‐powered nitrate (NO3−) reduction reaction (NO3RR) offers a net‐zero carbon route to the realization of high ammonia (NH3) productivity…”
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A Metal–Organic Framework derived CuxOyCz Catalyst for Electrochemical CO2 Reduction and Impact of Local pH Change
Published in Angewandte Chemie International Edition (18-10-2021)“…Developing highly efficient and selective electrocatalysts for the CO2 reduction reaction to produce value‐added chemicals has been intensively pursued. We…”
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In Situ Carbon Corrosion and Cu Leaching as a Strategy for Boosting Oxygen Evolution Reaction in Multimetal Electrocatalysts
Published in Advanced materials (Weinheim) (01-04-2022)“…The number of active sites and their intrinsic activity are key factors in designing high‐performance catalysts for the oxygen evolution reaction (OER). The…”
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Optimized Ag Nanovoid Structures for Probing Electrocatalytic Carbon Dioxide Reduction Using Operando Surface-Enhanced Raman Spectroscopy
Published in Langmuir (16-10-2018)“…Surface-enhanced Raman spectroscopy is a powerful analytical tool and a strongly surface structure-dependent process. Importantly, it can be coupled with…”
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Closing the Gap for Electronic Short‐Circuiting: Photosystem I Mixed Monolayers Enable Improved Anisotropic Electron Flow in Biophotovoltaic Devices
Published in Angewandte Chemie International Edition (25-01-2021)“…Well‐defined assemblies of photosynthetic protein complexes are required for an optimal performance of semi‐artificial energy conversion devices, capable of…”
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High-Throughput Exploration of Metal Vanadate Thin-Film Systems (M–V–O, M = Cu, Ag, W, Cr, Co, Fe) for Solar Water Splitting: Composition, Structure, Stability, and Photoelectrochemical Properties
Published in ACS combinatorial science (14-12-2020)“…Combinatorial synthesis and high-throughput characterization of thin-film materials libraries enable to efficiently identify both photoelectrochemically active…”
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Simultaneous Anodic and Cathodic Formate Production in a Paired Electrolyzer by CO2 Reduction and Glycerol Oxidation
Published in ChemSusChem (09-06-2023)“…Electrochemical CO2 conversion is a key technology to promote the production of carbon‐containing molecules, alongside reducing CO2 emissions leading to a…”
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Redox Replacement of Silver on MOF‐Derived Cu/C Nanoparticles on Gas Diffusion Electrodes for Electrocatalytic CO2 Reduction
Published in Chemistry : a European journal (24-02-2022)“…Bimetallic tandem catalysts have emerged as a promising strategy to locally increase the CO flux during electrochemical CO2 reduction, so as to maximize the…”
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In-situ electrochemical reconstruction and modulation of adsorbed hydrogen coverage in cobalt/ruthenium-based catalyst boost electroreduction of nitrate to ammonia
Published in Nature communications (03-10-2024)“…The electroreduction of nitrate offers a promising, sustainable, and decentralized route to generate valuable ammonia. However, a key challenge in the nitrate…”
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Ag‐induced Phase Transition of Bi2O3 Nanofibers for Enhanced Energy Conversion Efficiency towards Formate in CO2 Electroreduction
Published in Chemistry, an Asian journal (17-01-2023)“…Bi‐based electrocatalysts have been widely investigated in the CO2 reduction reaction (CO2RR) for the formation of formate. However, it remains a challenge to…”
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Combinatorial Synthesis and High-Throughput Characterization of Fe–V–O Thin-Film Materials Libraries for Solar Water Splitting
Published in ACS combinatorial science (10-09-2018)“…The search for suitable materials for solar water splitting is addressed with combinatorial material science methods. Thin film Fe–V–O materials libraries were…”
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Combinatorial Screening of Electronic and Geometric Effects in Compositionally Complex Solid Solutions Toward a Rational Design of Electrocatalysts
Published in Advanced energy materials (01-01-2024)“…Alloying dissimilar elements presents an effective strategy for enhancing the electrocatalytic properties of multi‐metal materials. This enhancement can be…”
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Nanostructured Fe-Doped Ni3S2 Electrocatalyst for the Oxygen Evolution Reaction with High Stability at an Industrially-Relevant Current Density
Published in ACS applied materials & interfaces (30-10-2024)“…A novel oxygen evolution reaction (OER) electrocatalyst was prepared by a synthesis strategy consisting of the solvothermal growth of Ni3S2 nanostructures on…”
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Hollow CeO2@Co2N Nanosheets Derived from Co‐ZIF‐L for Boosting the Oxygen Evolution Reaction
Published in Advanced materials interfaces (01-05-2021)“…Rational design of highly active electrocatalysts for the oxygen evolution reaction (OER) is critical to improving overall electrochemical water splitting…”
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Bioelectrocatalytic CO2 Reduction by Redox Polymer-Wired Carbon Monoxide Dehydrogenase Gas Diffusion Electrodes
Published in ACS applied materials & interfaces (19-10-2022)“…The development of electrodes for efficient CO2 reduction while forming valuable compounds is critical. The use of enzymes as catalysts provides the advantage…”
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Is Cu instability during the CO2 reduction reaction governed by the applied potential or the local CO concentration?
Published in Chemical science (Cambridge) (27-01-2021)“…Cu-based catalysts have shown structural instability during the electrochemical CO2 reduction reaction (CO2RR). However, studies on monometallic Cu catalysts…”
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