Search Results - "Juli-Anna Dolyniuk"
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MgSiAs: An Unexplored System with Promising Nonlinear Optical Properties
Published in Advanced functional materials (25-07-2018)“…Two new non‐centrosymmetric ternary compounds, MgSiAs2 and Mg3Si6As8, are discovered via metal flux and solid‐state synthetic methods. MgSiAs2 belongs to the…”
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Breaking the Tetra‐Coordinated Framework Rule: New Clathrate Ba8M24P28+δ (M=Cu/Zn)
Published in Angewandte Chemie (International ed.) (20-02-2017)“…A new clathrate type has been discovered in the Ba/Cu/Zn/P system. The crystal structure of the Ba8M24P28+δ (M=Cu/Zn) clathrate is composed of the pentagonal…”
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High-efficiency thermoelectric Ba8Cu14Ge6P26: bridging the gap between tetrel-based and tetrel-free clathrates
Published in Chemical science (Cambridge) (2017)“…A new type-I clathrate, Ba8Cu14Ge6P26, was synthesized by solid-state methods as a polycrystalline powder and grown as a cm-sized single crystal via the…”
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Clathrate Ba8Au16P30: The “Gold Standard” for Lattice Thermal Conductivity
Published in Journal of the American Chemical Society (21-08-2013)“…A novel clathrate phase, Ba8Au16P30, was synthesized from its elements. High-resolution powder X-ray diffraction and transmission electron microscopy were used…”
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Chemical Bonding and Transport Properties in Clathrates‑I with Cu–Zn–P Frameworks
Published in Chemistry of materials (22-05-2018)“…Quaternary clathrate-I phases with an overall composition of Ba8 M 16+yP30‑y (M = Cu,Zn) exhibit complex structural chemistry. Characterization of the…”
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Twisted Kelvin Cells and Truncated Octahedral Cages in the Crystal Structures of Unconventional Clathrates, AM2P4 (A = Sr, Ba; M = Cu, Ni)
Published in Chemistry of materials (23-06-2015)“…A new strontium nickel polyphosphide, SrNi2P4, was synthesized from elements and structurally characterized by single-crystal X-ray diffraction. It…”
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mP-BaP3: A New Phase from an Old Binary System
Published in Chemistry : a European journal (18-08-2014)“…A polyphosphide, mP‐BaP3, with a unique two‐dimensional phosphorus layer has been discovered and characterized. It crystallizes in the monoclinic space group…”
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Synthesis and Characterization of K and Eu Binary Phosphides
Published in Materials (13-01-2019)“…The synthesis, structural characterization, and optical properties of the binary Zintl phases of -EuP₃, -EuP₃, EuP₂, and -K₄P₆ are reported in this study…”
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High Pressure Properties of a Ba-Cu-Zn-P Clathrate-I
Published in Materials (12-08-2016)“…The high pressure properties of the novel tetrel-free clathrate, Ba₈Cu Zn P , were investigated using synchrotron powder X-ray diffraction. The pressure was…”
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Unconventional Clathrates with Transition Metal–Phosphorus Frameworks
Published in Accounts of chemical research (16-01-2018)“…Conspectus In this Account, we focused on a unique class of inclusion compounds, intermetallic clathrates, which exist in a variety of structures and exhibit…”
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Clathrate thermoelectrics
Published in Materials science & engineering. R, Reports : a review journal (01-10-2016)“…Clathrates represent a fascinating class of inorganic materials with a unique structural motif: 3D framework with large polyhedral cages encapsulating guest…”
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Zintl Salts Ba2P7X (X = Cl, Br, and I): Synthesis, Crystal, and Electronic Structures
Published in Crystals (Basel) (01-09-2013)“…Two barium phosphide halides, Ba2P7Br and Ba2P7I, were synthesized and structurally characterized by single crystal X-ray diffraction. Both compounds…”
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Superseding van der Waals with Electrostatic Interactions: Intercalation of Cs into the Interlayer Space of SiAs 2
Published in Inorganic chemistry (15-04-2019)“…Cs M Si As (M = Cu, Zn, or Ga; y = 0.15-0.19; x depends on M) represents a new group of pseudo-two-dimensional compounds that allow property tuning with…”
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Crystal and Electronic Structure and Optical Properties of AE 2 SiP 4 ( AE = Sr, Eu, Ba) and Ba 4 Si 3 P 8
Published in Zeitschrift für anorganische und allgemeine Chemie (1950) (15-02-2019)“…Three new compounds in the AE ‐Si‐P ( AE = Sr, Eu, Ba) systems are reported. Sr 2 SiP 4 and Eu 2 SiP 4 , the first members of their respective ternary systems,…”
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Ternary Zinc Antimonides Unlocked Using Hydride Synthesis
Published in Inorganic chemistry (19-07-2021)“…Three new sodium zinc antimonides Na11Zn2Sb5, Na4Zn9Sb9, and NaZn3Sb3 were synthesized utilizing sodium hydride NaH as a reactive sodium source. In comparison…”
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Ba and Sr Binary Phosphides: Synthesis, Crystal Structures, and Bonding Analysis
Published in Inorganic chemistry (08-09-2015)“…Synthesis, crystal structures, and chemical bonding are reported for four binary phosphides with different degrees of phosphorus oligomerization, ranging from…”
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BaAu2P4: layered zintl polyphosphide with infinite ∞(1)(P–) chains
Published in Inorganic chemistry (17-06-2013)“…Barium gold polyphosphide BaAu2P4 was synthesized from elements and structurally characterized by single crystal X-ray diffraction. BaAu2P4 crystallizes in a…”
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Clathrate BaNi2P4: An Interplay of Heat and Charge Transport Due to Strong Host–Guest Interactions
Published in Chemistry of materials (22-09-2020)“…Heat and charge transport properties of the metallic unconventional clathrate BaNi2P4, hosting Ba cations in oversized Ni8P16 cages, are investigated. A novel…”
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Crystal and Electronic Structure and Optical Properties of AE2SiP4 (AE = Sr, Eu, Ba) and Ba4Si3P8
Published in Zeitschrift für anorganische und allgemeine Chemie (1950) (15-02-2019)“…Three new compounds in the AE‐Si‐P (AE = Sr, Eu, Ba) systems are reported. Sr2SiP4 and Eu2SiP4, the first members of their respective ternary systems, are…”
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