Search Results - "Joost, Maximilian"

Reactivity of Gold Complexes towards Elementary Organometallic Reactions by Joost, Maximilian, Amgoune, Abderrahmane, Bourissou, Didier

“…For a while, the reactivity of gold complexes was largely dominated by their Lewis acid behavior. In contrast to the other transition metals, the elementary…”
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Facile Oxidative Addition of Aryl Iodides to Gold(I) by Ligand Design: Bending Turns on Reactivity by Joost, Maximilian, Zeineddine, Abdallah, Estévez, Laura, Mallet−Ladeira, Sonia, Miqueu, Karinne, Amgoune, Abderrahmane, Bourissou, Didier

“…Thanks to rational ligand design, the first gold(I) complexes to undergo oxidative addition of aryl iodides were discovered. The reaction proceeds under mild…”
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Oxidative Addition of Carbon-Carbon Bonds to Gold by Joost, Maximilian, Estévez, Laura, Miqueu, Karinne, Amgoune, Abderrahmane, Bourissou, Didier

“…The oxidative addition of strained CC bonds (biphenylene, benzocyclobutenone) to DPCb (diphosphino‐carborane) gold(I) complexes is reported. The resulting…”
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Synthesis, Structure, and Reactivity of an NHC Silyl Gold(I) Complex by Joost, Maximilian, Saffon-Merceron, Nathalie, Amgoune, Abderrahmane, Bourissou, Didier

“…The first example of a silyl gold­(I) complex stabilized by an N-heterocyclic carbene (NHC) was synthesized and fully characterized, including…”
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Oxidative Addition of Carbon-Carbon Bonds to Gold by Joost, Maximilian, Estévez, Laura, Miqueu, Karinne, Amgoune, Abderrahmane, Bourissou, Didier

“…The oxidative addition of strained CC bonds (biphenylene, benzocyclobutenone) to DPCb (diphosphino‐carborane) gold(I) complexes is reported. The resulting…”
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Enhanced π-Backdonation from Gold(I): Isolation of Original Carbonyl and Carbene Complexes by Joost, Maximilian, Estévez, Laura, Mallet-Ladeira, Sonia, Miqueu, Karinne, Amgoune, Abderrahmane, Bourissou, Didier

“…The specific electronic properties of bent o‐carborane diphosphine gold(I) fragments were exploited to obtain the first classical carbonyl complex of gold…”
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Mn(III) O^N^O Complexes as Water‐tolerant and Environmentally Benign Catalysts for Polyurethane Foam Synthesis by Ocansey, Edward, Sala, Oliver, Kamm, Marina, Joost, Maximilian, Bokern, Stefan, Rominger, Frank, Hashmi, A. Stephen K., Mormul, Jaroslaw, Schaub, Thomas

“…Polyurethanes are synthesized on industrial scale by the reaction of diisocyanates with diols in the presence of catalysts which are commonly based on tin…”
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Direct syn Insertion of Alkynes and Allenes into AuSi Bonds by Joost, Maximilian, Gualco, Pauline, Mallet-Ladeira, Sonia, Amgoune, Abderrahmane, Bourissou, Didier

“…Complete control: Alkynes and allenes are shown to insert into AuSi bonds with complete stereocontrol and in most cases complete regiocontrol. The ensuing…”
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Diazomethane umpolung atop anthracene: an electrophilic methylene transfer reagentElectronic supplementary information (ESI) available: Experimental procedures and characterization data. CCDC 1580349-1580351. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7sc04506a by Joost, Maximilian, Transue, Wesley J, Cummins, Christopher C

“…Formal addition of diazomethane's terminal nitrogen atom to the 9,10-positions of anthracene yields H 2 CN 2 A ( 1 , A = C 14 H 10 or anthracene). The…”
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Diazomethane umpolung atop anthracene: an electrophilic methylene transfer reagent† †Electronic supplementary information (ESI) available: Experimental procedures and characterization data. CCDC 1580349–1580351. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7sc04506a by Joost, Maximilian, Transue, Wesley J., Cummins, Christopher C.

“…Formal addition of diazomethane's terminal nitrogen atom to the 9,10-positions of anthracene yields H 2 CN 2 A ( 1 , A = C 14 H 10 or anthracene). Formal…”
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Diazomethane umpolung atop anthracene: an electrophilic methylene transfer reagent by Joost, Maximilian, Transue, Wesley J, Cummins, Christopher C

“…Formal addition of diazomethane's terminal nitrogen atom to the 9,10-positions of anthracene yields H CN ( , = C H or anthracene). The synthesis of this…”
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Sulfur monoxide thermal release from an anthracene-based precursor, spectroscopic identification, and transfer reactivity by Joost, Maximilian, Nava, Matthew, Transue, Wesley J., Martin-Drumel, Marie-Aline, McCarthy, Michael C., Patterson, David, Cummins, Christopher C.

“…Sulfur monoxide (SO) is a highly reactive molecule and thus, eludes bulk isolation. We report here on synthesis and reactivity of a molecular precursor for SO…”
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Synthesis, Structures, and Electronic Properties of O- and S‑Heterocyclic Carbene Complexes of Iridium, Copper, Silver, and Gold by Joost, Maximilian, Nieger, Martin, Lutz, Martin, Ehlers, Andreas W, Slootweg, J. Chris, Lammertsma, Koop

“…O- and S-heterocyclic carbenes (OHCs, SHCs) are shown experimentally and computationally to be stronger π acceptors than NHCs and lack, of course, substituents…”
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Mechanisms of syn-Insertion of Alkynes and Allenes into Gold–Silicon Bonds: A Comprehensive Experimental/Theoretical Study by Joost, Maximilian, Estevez, Laura, Mallet-Ladeira, Sonia, Miqueu, Karinne, Amgoune, Abderrahmane, Bourissou, Didier

“…A detailed mechanistic study is reported for the syn-insertion of alkynes and allenes in the Au–Si bonds of complexes (R3P)­Au–SiR′Ph2 (R = Ph, Me and R′ =…”
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Direct Evidence for Intermolecular Oxidative Addition of σ(SiSi) Bonds to Gold by Joost, Maximilian, Gualco, Pauline, Coppel, Yannick, Miqueu, Karinne, Kefalidis, Christos E., Maron, Laurent, Amgoune, Abderrahmane, Bourissou, Didier

“…Oxidative addition plays a major role in transition‐metal catalysis, but this elementary step remains very elusive in gold chemistry. It is now revealed that…”
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An Anthracene-based Precursor for Sulfur Monoxide Delivery: Thermal Release, Spectroscopic Identification and Transfer Reactivity by Joost, Maximilian, Nava, Matthew, Transue, Wesley J., Martin-Drumel, M. A., Mccarthy, Michael, Patterson, David, Cummins, Christopher C

“…Sulfur monoxide (SO) is a highly reactive molecule and thus eludes bulk isolation. We report here on synthesis and reactivity of a molecular precursor for SO…”
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σ‑SiH Complexes of Copper: Experimental Evidence and Computational Analysis by Joost, Maximilian, Mallet-Ladeira, Sonia, Miqueu, Karinne, Amgoune, Abderrahmane, Bourissou, Didier

“…Copper and gold complexes 2–4 of the diphosphine-hydrosilane [Ph2P(o-C6H4)]2MeSiH ligand 1 have been prepared, and their bonding situation has been analyzed…”
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Enhanced [pi]-Backdonation from Gold(I): Isolation of Original Carbonyl and Carbene Complexes by Joost, Maximilian, Estevez, Laura, Mallet-Ladeira, Sonia, Miqueu, Karinne, Amgoune, Abderrahmane, Bourissou, Didier

“…The specific electronic properties of bent o-carborane diphosphine gold(I) fragments were exploited to obtain the first classical carbonyl complex of gold…”
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Direct syn Insertion of Alkynes and Allenes into AuSi Bonds by Joost, Maximilian, Gualco, Pauline, Mallet-Ladeira, Sonia, Amgoune, Abderrahmane, Bourissou, Didier

“…Complete control: Alkynes and allenes are shown to insert into AuSi bonds with complete stereocontrol and in most cases complete regiocontrol. The ensuing…”
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Reaktivität von Goldkomplexen in metallorganischen Elementarreaktionen by Joost, Maximilian, Amgoune, Abderrahmane, Bourissou, Didier

“…Seit langem war die Reaktivität von Goldkomplexen überwiegend durch ihre Eigenschaft als Lewis‐Säure bestimmt. Im Unterschied zu anderen Übergangsmetallen…”
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