Search Results - "Johnstone, Erik V."
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Hybridised production of technetium-99m and technetium-101 with fluorine-18 on a low-energy biomedical cyclotron
Published in EPJ techniques and instrumentation (10-02-2023)“…New modes of production and supply of short-lived radioisotopes using accelerators are becoming attractive alternatives to the use of nuclear reactors. In this…”
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Fusion-Based Neutron Generator Production of Tc-99m and Tc-101: A Prospective Avenue to Technetium Theranostics
Published in Pharmaceuticals (Basel, Switzerland) (29-08-2021)“…Presented are the results of 99mTc and 101Tc production via neutron irradiation of natural isotopic molybdenum (Mo) with epithermal/resonance neutrons…”
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Discovery, nuclear properties, synthesis and applications of technetium-101
Published in Communications chemistry (20-10-2022)“…Technetium-101 ( 101 Tc) has been poorly studied in comparison with other Tc isotopes, although it was first identified over ~80 years ago shortly after the…”
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An Investigation of Iodovanadinite Wasteforms for the Immobilisation of Radio-Iodine and Technetium
Published in Ceramics (01-09-2023)“…99Tc and 129I are two long-lived, highly soluble and mobile fission products that pose a long-term hazard. A proposed wasteform for the disposal of…”
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Magnetic Circular Dichroism and Electronic Structure of [Re2X4(PMe3)4]+ (X = Cl, Br)
Published in Inorganic chemistry (03-02-2014)“…Magnetic circular dichroism (MCD) and electronic absorption spectroscopies have been used to probe the electronic structure of the classical paramagnetic…”
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Study of the Interaction of Eu3+ with Microbiologically Induced Calcium Carbonate Precipitates using TRLFS
Published in Environmental science & technology (15-11-2016)“…The microbial induced biomineralization of calcium carbonate using the ureolytic bacterium Sporosarcina pasteurii in the presence of trivalent europium, a…”
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Technetium retention by gamma alumina nanoparticles and the effect of sorbed Fe2
Published in Journal of hazardous materials (15-04-2020)“…[Display omitted] •Technetium (Tc) is sorbed (6.5%) on γ-Al2O3 NPs in absence of Fe2+ (binary system).•Tc removal highly enhances when Fe2+ is pre-sorbed on…”
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Study of the Interaction of Eu 3+ with Microbiologically Induced Calcium Carbonate Precipitates using TRLFS
Published in Environmental science & technology (15-11-2016)“…The microbial induced biomineralization of calcium carbonate using the ureolytic bacterium Sporosarcina pasteurii in the presence of trivalent europium, a…”
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Technetium: The First Radioelement on the Periodic Table
Published in Journal of chemical education (14-03-2017)“…The radioactive nature of technetium is discussed using a combination of introductory nuclear physics concepts and empirical trends observed in the chart of…”
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Recent Advances in Technetium Halide Chemistry
Published in Accounts of chemical research (18-02-2014)“…Transition metal binary halides are fundamental compounds, and the study of their structure, bonding, and other properties gives chemists a better…”
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β-Technetium Trichloride: Formation, Structure, and First-Principles Calculations
Published in Inorganic chemistry (07-05-2012)“…A second polymorph of technetium trichloride, β-TcCl3, has been identified from the reaction between Tc metal and Cl2 gas. The structure of β-TcCl3 consists of…”
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Technetium Tetrachloride Revisited: A Precursor to Lower-Valent Binary Technetium Chlorides
Published in Inorganic chemistry (06-08-2012)“…Technetium tetrachloride has been prepared from the reaction of technetium metal with excess chlorine in sealed Pyrex ampules at elevated temperatures. The…”
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Molecular and Electronic Structure of Re2Br4(PMe3)4
Published in Inorganic chemistry (18-07-2016)“…The dinuclear rhenium(II) complex Re2Br4(PMe3)4 was prepared from the reduction of [Re2Br8]2– with (n-Bu4N)BH4 in the presence of PMe3 in propanol. The…”
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A Decade of Dinuclear Technetium Complexes with Multiple Metal-Metal Bonds
Published in European journal of inorganic chemistry (01-09-2014)“…Transition metal complexes with multiple metal–metal bonds exhibit interesting catalytic and biological properties. One element whose metal–metal bond…”
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β‑Technetium Dichloride: Solid-State Modulated Structure, Electronic Structure, and Physical Properties
Published in Journal of the American Chemical Society (23-10-2013)“…A second polymorph of technetium dichloride, β-TcCl2, has been synthesized from the reaction of Tc metal and chlorine in a sealed tube at 450 °C. The…”
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A Trigonal-Prismatic Hexanuclear Technetium(II) Bromide Cluster: Solid-State Synthesis and Crystallographic and Electronic Structure
Published in Inorganic chemistry (20-05-2013)“…The compound Na{[Tc6Br12]2Br} has been obtained from the decomposition of TcBr4 under vacuum in a Pyrex ampule at 450 °C. The stoichiometry of the compound has…”
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Synthesis and Structure of Technetium Trichloride
Published in Journal of the American Chemical Society (17-11-2010)“…Technetium trichloride has been synthesized by reaction of Tc2(O2CCH3)4Cl2 with HCl(g) at 300 °C. The mechanism of formation mimics the one described earlier…”
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Technetium Dichloride: A New Binary Halide Containing Metal–Metal Multiple Bonds
Published in Journal of the American Chemical Society (15-06-2011)“…Technetium dichloride has been discovered. It was synthesized from the elements and characterized by several physical techniques, including single crystal…”
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Probing the Presence of Multiple Metal–Metal Bonds in Technetium Chlorides by X‑ray Absorption Spectroscopy: Implications for Synthetic Chemistry
Published in Inorganic chemistry (03-09-2012)“…The cesium salts of [Tc2X8]3– (X = Cl, Br), the reduction product of (n-Bu4N)[TcOCl4] with (n-Bu4N)BH4 in THF, and the product obtained from reaction of…”
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Synthetic and Coordination Chemistry of the Heavier Trivalent Technetium Binary Halides: Uncovering Technetium Triiodide
Published in Inorganic chemistry (16-12-2013)“…Technetium tribromide and triiodide were obtained from the reaction of the quadruply Tc–Tc-bonded dimer Tc2(O2CCH3)4Cl2 with flowing HX(g) (X = Br, I) at…”
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