Search Results - "Jin, Zhichao"
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EEG classification using sparse Bayesian extreme learning machine for brain–computer interface
Published in Neural computing & applications (01-06-2020)“…Mu rhythm is a spontaneous neural response occurring during a motor imagery (MI) task and has been increasingly applied to the design of brain–computer…”
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Catalytic atroposelective synthesis of axially chiral benzonitriles via chirality control during bond dissociation and CN group formation
Published in Nature communications (10-01-2022)“…The applications of axially chiral benzonitriles and their derivatives remain mostly unexplored due to their synthetic difficulties. Here we disclose an…”
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3
Carbene and photocatalyst-catalyzed decarboxylative radical coupling of carboxylic acids and acyl imidazoles to form ketones
Published in Nature communications (23-05-2022)“…The carbene and photocatalyst co-catalyzed radical coupling of acyl electrophile and a radical precursor is emerging as attractive method for ketone synthesis…”
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Carbene-catalyzed atroposelective synthesis of axially chiral styrenes
Published in Nature communications (10-01-2022)“…Axially chiral styrenes bearing a chiral axis between a sterically non-congested acyclic alkene and an aryl ring are difficult to prepare due to low rotational…”
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N‐Heterocyclic Carbene Organocatalysis: Activation Modes and Typical Reactive Intermediates
Published in Chinese journal of chemistry (01-10-2020)“…N‐Heterocyclic carbene (NHC) organocatalysis has been developed as an important approach in modern organic synthesis. Versatile activation modes within NHC…”
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N‐Heterocyclic Carbene (NHC)‐Organocatalyzed Kinetic Resolutions, Dynamic Kinetic Resolutions, and Desymmetrizations
Published in Chemistry, an Asian journal (04-09-2018)“…The last couple of decades have witnessed tremendous development within N‐heterocyclic carbene (NHC) organocatalysis. NHCs have been used as powerful organic…”
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Catalytic asymmetric acetalization of carboxylic acids for access to chiral phthalidyl ester prodrugs
Published in Nature communications (11-04-2019)“…Carboxylic acids are common moieties in medicines. They can be converted to phthalidyl esters as prodrugs. Unfortunately, phthalidyl esters are now mostly…”
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Enantioselective Construction of Bicyclic Pyran and Hydrindane Scaffolds via Intramolecular Rauhut–Currier Reactions Catalyzed by Thiourea-Phosphines
Published in ACS catalysis (07-09-2018)“…Highly enantioselective intramolecular RC reactions via desymmetrization of cyclohexadienones have been developed. By employing cyclohexadienones with a…”
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9
Carbene-Catalyzed Alkylation of Carboxylic Esters via Direct Photoexcitation of Acyl Azolium Intermediates
Published in ACS catalysis (05-03-2021)“…A carbene-catalyzed reductive coupling reaction of carboxylic esters and substituted Hantzsch esters is disclosed. Key steps of this reaction include…”
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Tectorigenin Inhibits Glycolysis-induced Cell Growth and Proliferation by Modulating LncRNA CCAT2/miR-145 Pathway in Colorectal Cancer
Published in Current cancer drug targets (01-01-2024)“…Colorectal cancer (CRC) places a heavy burden on global health. Tectorigenin (Tec) is a type of flavonoid-based compound obtained from the Chinese medical herb…”
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Carbon–carbon bond activation of cyclobutenones enabled by the addition of chiral organocatalyst to ketone
Published in Nature communications (05-02-2015)“…The activation of carbon–carbon (C–C) bonds is an effective strategy in building functional molecules. The C–C bond activation is typically accomplished via…”
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Enhancing Performance of the National Field Triage Guidelines Using Machine Learning: Development of a Prehospital Triage Model to Predict Severe Trauma
Published in Journal of medical Internet research (30-09-2024)“…Prehospital trauma triage is essential to get the right patient to the right hospital. However, the national field triage guidelines proposed by the American…”
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13
Carbene‐Catalyzed Dynamic Kinetic Resolution and Asymmetric Acylation of Hydroxyphthalides and Related Natural Products
Published in Angewandte Chemie International Edition (02-03-2020)“…A catalytic dynamic kinetic resolution and asymmetric acylation reaction of hydroxyphthalides is developed. The reaction involves formation of a carbene…”
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Chiral Nitroarenes as Enantioselective Single-Electron-Transfer Oxidants for Carbene-Catalyzed Radical Reactions
Published in Organic letters (20-09-2019)“…A new class of chiral oxidants is developed. These readily accessible oxidants contain a nitro group for oxidation and a chiral sulfonamide moiety for…”
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Cycloaddition of cyclobutenone and azomethine imine enabled by chiral isothiourea organic catalysts
Published in Chemical science (Cambridge) (01-10-2015)“…The addition of an organic catalyst to the ketone moiety of a γ-mono-chloride substituted cyclobutenone destroys its stable, conjugated and nearly planar…”
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Research Advances on the Bioactivity of 1,2,3-Triazolium Salts
Published in International journal of molecular sciences (27-06-2023)“…1,2,3-Triazolium salts have demonstrated significant potential in the fields of medicine and agriculture, exhibiting exceptional antibacterial, antifungal,…”
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Facile access to benzofuran derivatives through radical reactions with heteroatom-centered super-electron-donors
Published in Nature communications (15-11-2023)“…The development of suitable electron donors is critical to single-electron-transfer (SET) processes. The use of heteroatom-centered anions as…”
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Highly Diastereo- and Enantioselective Synthesis of 5-Substituted 3-Pyrrolidin-2-ones: Vinylogous Michael Addition under Multifunctional Catalysis
Published in Angewandte Chemie International Edition (28-03-2011)“…A direct line: A direct organocatalytic asymmetric vinylogous Michael addition of α,β‐unsaturated γ‐butyrolactams with α,β‐unsaturated ketones has been…”
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Carbene and Acid Cooperative Catalytic Reactions of Aldehydes and o‑Hydroxybenzhydryl Amines for Highly Enantioselective Access to Dihydrocoumarins
Published in Organic letters (03-11-2017)“…A highly enantioselective method for quick access to dihydrocoumarins is reported. The reaction involves a cooperative catalytic process with carbene and in…”
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Machine learning approach for the prediction of 30-day mortality in patients with sepsis-associated encephalopathy
Published in BMC medical research methodology (04-07-2022)“…Abstract Objective Our study aimed to identify predictors as well as develop machine learning (ML) models to predict the risk of 30-day mortality in patients…”
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