Search Results - "Jilek, Robert E"

A General and Modular Synthesis of Monoimidouranium(IV) Dihalides by Jilek, Robert. E, Spencer, Liam P, Kuiper, David L, Scott, Brian L, Williams, Ursula J, Kikkawa, James M, Schelter, Eric J, Boncella, James M

“…The conproportionation reaction between the dimeric diimidouranium(V) species [U(N t Bu)2(I)( t Bu2bpy)]2 ( t Bu2bpy = 4,4′-di-tert-butyl-2,2′-bipyridyl) and…”
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Tetrahalide Complexes of the [U(NR)2]2+ Ion: Synthesis, Theory, and Chlorine K‑Edge X‑ray Absorption Spectroscopy by Spencer, Liam P, Yang, Ping, Minasian, Stefan G, Jilek, Robert E, Batista, Enrique R, Boland, Kevin S, Boncella, James M, Conradson, Steven D, Clark, David L, Hayton, Trevor W, Kozimor, Stosh A, Martin, Richard L, MacInnes, Molly M, Olson, Angela C, Scott, Brian L, Shuh, David K, Wilkerson, Marianne P

“…Synthetic routes to salts containing uranium bis-imido tetrahalide anions [U(NR)2X4]2– (X = Cl–, Br–) and non-coordinating NEt4 + and PPh4 + countercations are…”
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Bis(1,2,3,4-η⁴-anthracene)ferrate(1-): A Paramagnetic Homoleptic Polyarene Transition-Metal Anion by Brennessel, William W, Jilek, Robert E, Ellis, John E

“…Magnetic personalities: [Fe(η4‐C14H10)2]− is an unprecedented example of an anionic 17‐electron homoleptic polyarene transition‐metal complex. This species is…”
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Structurally Distinct Homoleptic Anthracene Complexes, [M(C₁₄H₁₀)₃]²⁻, M=Titanium, Zirconium, Hafnium: Tris(arene) Complexes for a Triad of Transition Metals by Jilek, Robert E, Jang, Meehae, Smolensky, Eric D, Britton, J. Doyle, Ellis, John E

“…Being positive about anions: Hydrocarbon complexes containing negative‐valent Hf are obtained for the first time as tris(polyarene)hafnates(2−),…”
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A Direct Route to Bis(imido)uranium(V) Halides via Metathesis of Uranium Tetrachloride by Jilek, Robert E, Spencer, Liam P, Lewis, Richard A, Scott, Brian L, Hayton, Trevor W, Boncella, James M

“…Metathesis reactions between uranium tetrachloride and lithium 2,6-diisopropylphenylamide in the presence of 4,4′-dialkyl-2,2′-bipyridyl (R2bpy; R = Me, tBu)…”
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Preparation and Reactivity of the Versatile Uranium(IV) Imido Complexes U(NAr)Cl2(R2bpy)2 (R = Me, t Bu) and U(NAr)Cl2(tppo)3 by Jilek, Robert E, Tomson, Neil C, Shook, Ryan L, Scott, Brian L, Boncella, James M

“…Uranium tetrachloride undergoes facile reactions with 4,4′-dialkyl-2,2′-bipyridine, resulting in the generation of UCl4(R2bpy)2, R = Me, t Bu. These…”
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Preparation of Epitaxial Uranium Dicarbide Thin Films by Polymer-Assisted Deposition by Jilek, Robert E, Bauer, Eve, Burrell, Anthony K, McCleskey, Thomas M, Jia, Quanxi, Scott, Brian L, Beaux, Miles F, Durakiewicz, Tomasz, Joyce, John J, Rector, Kirk D, Xiong, Jie, Gofryk, Krzysztof, Ronning, Filip, Martin, Richard L

“…High quality epitaxial thin films of cubic UC2 were synthesized using a solution based technique. The films were characterized using XRD, UPS, Raman, and…”
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Bis(pyrene)metal complexes of vanadium, niobium and titanium: isolable homoleptic pyrene complexes of transition metals by Kucera, Benjamin E., Jilek, Robert E., Brennessel, William W., Ellis, John E.

“…Reduction of VCl3(THF)3 (THF is tetrahydrofuran) and NbCl4(THF)2 by alkali metal pyrene radical anion salts in THF affords the paramagnetic sandwich complexes…”
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Pentafluorosulfanylbenzene chemistry: Role of copper in the Sheppard reaction, direct fluorination of aromatic sulfenyl chlorides, and several potentially energetic SF5-benzenes by Sipyagin, Alexey M., Bateman, Colin P., Matsev, Andrej V., Waterfeld, Alfred, Jilek, Robert E., Key, Christopher D., Szulczewski, Gregory J., Thrasher, Joseph S.

“…The Sheppard reaction most likely proceeds through the intermediacy of aryl thiolates whose formation from aromatic disulfides is catalyzed by coinage metal…”
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Bis(1,2,3,4-η4-anthracene)ferrate(1−): A Paramagnetic Homoleptic Polyarene Transition-Metal Anion by Brennessel, William W., Jilek, Robert E., Ellis, John E.

“…Kein altes Eisen: [Fe(η4‐C14H10)2]− ist der erste homoleptische anionische 17‐Elektronen‐Polyarenkomplex eines Übergangsmetalls und der erste isolierbare…”
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[2+2] cycloaddition reactions at terminal imido uranium(IV) complexes to yield isolable cycloadducts by Jilek, Robert E., Tomson, Neil C., Scott, Brian L., Boncella, James M.

“…The reaction of aryl isocyanates with U(IV) imido complexes proceeds via a [2+2] cycloaddition reaction between the imido group and the isocyanate to give…”
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Preparation and Reactivity of the Versatile Uranium(IV) Imido Complexes U(NAr)Cl 2 (R 2 bpy) 2 (R = Me, t Bu) and U(NAr)Cl 2 (tppo) 3 by Jilek, Robert E., Tomson, Neil C., Shook, Ryan L., Scott, Brian L., Boncella, James M.

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Pentafluorosulfanylbenzene chemistry: Role of copper in the Sheppard reaction, direct fluorination of aromatic sulfenyl chlorides, and several potentially energetic SF sub(5)-benzenes by Sipyagin, Alexey M, Bateman, Colin P, Matsev, Andrej V, Waterfeld, Alfred, Jilek, Robert E, Key, Christopher D, Szulczewski, Gregory J, Thrasher, Joseph S

“…In honor of the awardee Dr. Teruo Umemoto and his significant advances in the preparation of pentafluorosulfanylbenzenes [1], we will first overview our…”
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Preparation and reactivity of the versatile uranium(IV) imido complexes U(NAr)Cl₂(R₂bpy)₂ (R = Me, (t)Bu) and U(NAr)Cl₂(tppo) by Jilek, Robert E, Tomson, Neil C, Shook, Ryan L, Scott, Brian L, Boncella, James M

“…Uranium tetrachloride undergoes facile reactions with 4,4'-dialkyl-2,2'-bipyridine, resulting in the generation of UCl4(R2bpy)2, R = Me, (t)Bu. These…”
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Structurally Distinct Homoleptic Anthracene Complexes, [M(C14H10)3]2−, M=Titanium, Zirconium, Hafnium: Tris(arene) Complexes for a Triad of Transition Metals by Jilek, Robert E., Jang, Meehae, Smolensky, Eric D., Britton, J. Doyle, Ellis, John E.

“…Positives zu Anionen: Kohlenwasserstoffkomplexe von Hf in negativen Oxidationsstufen wurden erstmals ausgehend von Tris(polyaren)hafnaten(2−)…”
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Bis(1,2,3,4‐η 4 ‐anthracene)ferrate(1−): A Paramagnetic Homoleptic Polyarene Transition‐Metal Anion by Brennessel, William W., Jilek, Robert E., Ellis, John E.

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