Search Results - "Jessop, Philip G."
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Extraction of phenols from lignin microwave-pyrolysis oil using a switchable hydrophilicity solvent
Published in Bioresource technology (01-02-2014)“…[Display omitted] •Switchable-hydrophilicity solvents were used to extract phenols from lignin bio-oil.•Phenols were successfully extracted and the SHS (91%)…”
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Switchable viscosity triggered by CO2 using smart worm-like micelles
Published in Chemical communications (Cambridge, England) (01-01-2013)“…We report two CO2-responsive aqueous solutions having switchable viscosity. The solution of sodium octadecyl sulfate and 2-(dimethylamino)ethanol forms…”
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Switchable Surfactants
Published in Science (American Association for the Advancement of Science) (18-08-2006)“…Many industrial applications that rely on emulsions would benefit from an efficient, rapid method of breaking these emulsions at a specific desired stage. We…”
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"Switchable Water": Aqueous Solutions of Switchable Ionic Strength
Published in ChemSusChem (26-04-2010)“…“Salting out” is a standard method for separating water‐soluble organic compounds from water. In this method, adding a large amount of salt to the aqueous…”
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CO2‑Responsive Branched Polymers for Forward Osmosis Applications: The Effect of Branching on Draw Solute Properties
Published in Industrial & engineering chemistry research (14-07-2021)“…CO2-responsive branched poly(N,N-dimethylallylamine) (b-PDMAAm) was evaluated as a potential draw solute for forward osmosis. PDMAAm with different degrees of…”
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Sodium Methyl Carbonate as an Effective C1 Synthon. Synthesis of Carboxylic Acids, Benzophenones, and Unsymmetrical Ketones
Published in Organic letters (07-06-2019)“…Reported is the synthesis of carboxylic acids, symmetrical ketones, and unsymmetrical ketones with selectivity achieved by exploiting the differential…”
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A Conventional Surfactant Becomes CO2-Responsive in the Presence of Switchable Water Additives
Published in Chemistry : a European journal (26-04-2013)“…We have developed a new benign means of reversibly breaking emulsions and latexes by using “switchable water”, an aqueous solution of switchable ionic…”
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One-Pot Synthesis of Poly((diethylamino)ethyl methacrylate-co-styrene)‑b‑poly(methyl methacrylate-co-styrene) Nanoparticles via Nitroxide-Mediated Polymerization
Published in Macromolecules (14-04-2015)“…Poly((diethylamino)ethyl methacrylate-co-styrene)-b-poly(methyl methacrylate-co-styrene) nanoparticles were prepared by one-pot process via…”
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Switchable Solvents Consisting of Amidine/Alcohol or Guanidine/Alcohol Mixtures
Published in Industrial & engineering chemistry research (06-02-2008)“…Liquids that consist of a mixture of an alcohol and either an amidine or a guanidine have been developed to switch from a low-polarity form to a high-polarity…”
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Reversible Absorption of Volatile Organic Compounds by Switchable-Hydrophilicity Solvents: A Case Study of Toluene with N , N -Dimethylcyclohexylamine
Published in ACS omega (12-01-2021)“…Absorption is one of the most important treatment technologies for the removal of volatile organic compounds (VOCs) from tail gases, yet the separation of the…”
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Switchable-Hydrophilicity Solvents for Product Isolation and Catalyst Recycling in Organocatalysis
Published in ChemSusChem (07-04-2016)“…Switchable‐hydrophilicity solvents (SHSs) are solvents that can switch reversibly between a water‐miscible state to a state that forms a biphasic mixture with…”
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CO2‑Responsive Low Molecular Weight Polymer with High Osmotic Pressure as a Draw Solute for Forward Osmosis
Published in ACS omega (26-12-2023)“…A key challenge in the development of forward osmosis (FO) technology is to identify a suitable draw solute that can generate a large osmotic pressure with…”
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Reversible Uptake of COS, CS2, and SO2: Ionic Liquids with O‐Alkylxanthate, O‐Alkylthiocarbonyl, and O‐Alkylsulfite Anions
Published in Chemistry : a European journal (03-08-2009)“…CO2‐binding organic liquids (CO2BOLs) are mixtures of a base (typically an amidine or guanidine) and an alcohol, and have been shown to reversibly capture and…”
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Liquid Poly(ethylene glycol) and Supercritical Carbon Dioxide: A Benign Biphasic Solvent System for Use and Recycling of Homogeneous Catalysts
Published in Journal of the American Chemical Society (14-05-2003)“…Poly(ethylene glycol) (PEG), having a molecular weight of 900 or 1500, is a solid at room temperature but a nonvolatile liquid at 40 °C under CO2 pressure…”
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Centrate wastewater treatment with Chlorella vulgaris: Simultaneous enhancement of nutrient removal, biomass and lipid production
Published in Chemical engineering journal (Lausanne, Switzerland : 1996) (15-06-2018)“…•Centrate wastewater can be efficiently remediated by Chlorella vulgaris.•C. vulgaris did not grow well on centrate under heterotrophic conditions.•Three…”
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Hydrogenation of Carbon Dioxide Catalyzed by Ruthenium Trimethylphosphine Complexes: The Accelerating Effect of Certain Alcohols and Amines
Published in Journal of the American Chemical Society (10-07-2002)“…A trace amount of alcohol cocatalyst and a stoichiometric amount of base are required during the hydrogenation of CO2 to formic acid catalyzed by ruthenium…”
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Carbon Dioxide-Switchable Polymers: Where Are the Future Opportunities?
Published in Macromolecules (24-09-2019)“…Carbon dioxide has emerged as a new and innovative “trigger” for stimuli-responsive materials. It is abundant, inexpensive, nontoxic, and environmentally…”
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β-Hydroxycarboxylic Acids from Simple Ketones by Carboxylation and Asymmetric Hydrogenation
Published in Advanced synthesis & catalysis (01-12-2008)“…We present a new asymmetric synthesis of β‐hydroxycarboxylic acids from ketones, performed by carboxylation using CO2 followed by asymmetric hydrogenation…”
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Production of H2 from Combined Endothermic and Exothermic Hydrogen Carriers
Published in Journal of the American Chemical Society (17-12-2008)“…One of the major limitations to the use of fuel cell systems in vehicular transportation is the lack of hydrogen storage systems that have the required…”
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A Superior Precursor for Palladium(0)-Based Cross-Coupling and Other Catalytic Reactions
Published in Journal of organic chemistry (04-09-2009)“…The easily synthesized, easily handled compound Pd(η3-1-PhC3H4)(η5-C5H5) (II) reacts readily with mono- and bidentate tertiary phosphines to produce the…”
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