Search Results - "Jesse, Kate A"

Gold‐Catalyzed Friedel–Crafts‐Like Reaction of Benzylic Alcohols to Afford 1,1‐Diarylalkanes by Oakley, James V., Stanley, Tyler J., Jesse, Kate A., Melanese, Amanda K., Alvarez, Araceli A., Prince, Aloha L., Cain, Stephanie E., Wenzel, Anna G., Iafe, Robert G.

“…A gold‐catalyzed, Friedel–Crafts‐like benzylation of unactivated benzylic alcohols to form 1,1‐diarylalkanes has been developed. The operationally convenient…”
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Leveraging ligand-based proton and electron transfer for aerobic reactivity and catalysis by Jesse, Kate A, Anderson, John S

“…While O is an abundant, benign, and thermodynamically potent oxidant, it is also kinetically inert. This frequently limits its use in synthetic…”
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Generation and Oxidative Reactivity of a Ni(II) Superoxo Complex via Ligand-Based Redox Non-Innocence by McNeece, Andrew J, Jesse, Kate A, Xie, Jiaze, Filatov, Alexander S, Anderson, John S

“…Metal ligand cooperativity is a powerful strategy in transition metal chemistry. This type of mechanism for the activation of O is best exemplified by heme…”
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Enzyme-Like Hydroxylation of Aliphatic C–H Bonds From an Isolable Co-Oxo Complex by Goetz, McKenna K, Schneider, Joseph E, Filatov, Alexander S, Jesse, Kate A, Anderson, John S

“…The selective hydroxylation of aliphatic C–H bonds remains a challenging but broadly useful transformation. Nature has evolved systems that excel at this…”
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Nickel-Mediated Dehydrogenative Aryl–Aryl Homocoupling of a Bulky Phosphino-Pyridine by Mannava, Vennela, Jesse, Kate A, Anderson, John S

“…Aryl–aryl bond formation through dehydrogenative coupling is an attractive transformation due to the atom and step economy of working with unfunctionalized C–H…”
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Neocuproine as a Redox-Active Ligand Platform on Iron and Cobalt by Jesse, Kate A, Filatov, Alexander S, Xie, Jiaze, Anderson, John S

“…A family of bis­(neocuproine) complexes of Fe2+ and Co2+ have been investigated for neocuproine redox noninnocence. A series of redox isomers of…”
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Reversible Switching of Organic Diradical Character via Iron-Based Spin-Crossover by Kawamura, Airi, Xie, Jiaze, Boyn, Jan-Niklas, Jesse, Kate A, McNeece, Andrew J, Hill, Ethan A, Collins, Kelsey A, Valdez-Moreira, Juan A, Filatov, Alexander S, Kurutz, Josh W, Mazziotti, David A, Anderson, John S

“…Organic diradicals are uncommon species that have been intensely studied for their unique properties and potential applicability in a diverse range of…”
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Generation and Aerobic Oxidative Catalysis of a Cu(II) Superoxo Complex Supported by a Redox-Active Ligand by Czaikowski, Maia E., McNeece, Andrew J., Boyn, Jan-Niklas, Jesse, Kate A., Anferov, Sophie W., Filatov, Alexander S., Mazziotti, David A., Anderson, John S.

“…Cu systems feature prominently in aerobic oxidative catalysis in both biology and synthetic chemistry. Metal ligand cooperativity is a common theme in both…”
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Silver-Catalyzed, N -Formylation of Amines Using Glycol Ethers by King, Bradley H, Wang, Michelle L, Jesse, Kate A, Kaur, Guneet, Tran, Brianna, Walser-Kuntz, Ryan, Iafe, Robert G, Wenzel, Anna G

“…A silver-catalyzed protocol was found to afford the -formylation of amines in moderate-to-good yields. Ethylene glycol-derived, oligomeric ethers were found to…”
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Reversible homolytic activation of water via metal-ligand cooperativity in a T-shaped Ni(ii) complex by Chang, Mu-Chieh, Jesse, Kate A, Filatov, Alexander S, Anderson, John S

“…A T-shaped Ni(ii) complex [ DHPy]Ni has been prepared and characterized. EPR spectra and DFT calculations of this complex suggest that the electronic structure…”
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Impact of Pendent Ammonium Groups on Solubility and Cycling Charge Carrier Performance in Nonaqueous Redox Flow Batteries by Jesse, Kate A., Abad, Sergio Diaz, Studvick, Chad, Andrade, Gabriel A., Maurya, Sandip, Scott, Brian L., Mukundan, Rangachary, Popov, Ivan A., Davis, Benjamin L.

“…The synthesis, characterization, electrochemical performance, and theoretical modeling of two base-metal charge carrier complexes incorporating a pendent…”
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Direct Aerobic Generation of a Ferric Hydroperoxo Intermediate Via a Preorganized Secondary Coordination Sphere by Jesse, Kate A, Anferov, Sophie W, Collins, Kelsey A, Valdez-Moreira, Juan A, Czaikowski, Maia E, Filatov, Alexander S, Anderson, John S

“…Enzymes exert control over the reactivity of metal centers with precise tuning of the secondary coordination sphere of active sites. One particularly elegant…”
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Collaborative Learning in Chemistry: Impact of COVID-19 by Gemmel, Philipp M, Goetz, McKenna K, James, Nicole M, Jesse, Kate A, Ratliff, Britni J

“…Student learning and course performance are often improved when students actively engage with content. However, pedagogical practices that foster active…”
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Iron(II) Complexes Featuring a Redox‐Active Dihydrazonopyrrole Ligand by Jesse, Kate A., Chang, Mu‐Chieh, Filatov, Alexander S., Anderson, John S.

“…Nature uses control of the secondary coordination sphere to facilitate an astounding variety of transformations. Similarly, synthetic chemists have found…”
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Oxadiazole derivatives as stable anolytes for >3 V non-aqueous redox flow battery by Jesse, Kate A., Diaz-Abad, Sergio, Van Pelt, Christopher E., Pentzer, Emily, Davis, Benjamin L., Maurya, Sandip

“…•Stable derivatives of DiPhenOx are synthesized and characterized as anolytes.•Cyano and ester groups improve electrochemical stability of parent…”
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Reversible homolytic activation of water via metal-ligand cooperativity in a T-shaped Ni(ii) complexElectronic supplementary information (ESI) available: Experimental details and CIF files. CCDC 1569427, 1860789-1860792. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c8sc03719a by Chang, Mu-Chieh, Jesse, Kate A, Filatov, Alexander S, Anderson, John S

“…A T-shaped Ni( ii ) complex [ Tol,Ph DHPy]Ni has been prepared and characterized. EPR spectra and DFT calculations of this complex suggest that the electronic…”
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Reversible homolytic activation of water via metal–ligand cooperativity in a T-shaped Ni(II) complex by Chang, Mu-Chieh, Jesse, Kate A., Filatov, Alexander S., Anderson, John S.

“…Ligand based storage of H-atoms enables the reversible homolysis of water by a T-shaped Ni(II) complex…”
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Reversible homolytic activation of water via metal–ligand cooperativity in a T-shaped Ni(ii) complex† †Electronic supplementary information (ESI) available: Experimental details and CIF files. CCDC 1569427, 1860789–1860792. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c8sc03719a by Chang, Mu-Chieh, Jesse, Kate A., Filatov, Alexander S., Anderson, John S.

“…Ligand based storage of H-atoms enables the reversible homolysis of water by a T-shaped Ni complex. A T-shaped Ni( ii ) complex [ Tol,Ph DHPy]Ni has been…”
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