Search Results - "Jeletic, Matthew S"
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A Cobalt-Based Catalyst for the Hydrogenation of CO2 under Ambient Conditions
Published in Journal of the American Chemical Society (07-08-2013)“…Because of the continually rising levels of CO2 in the atmosphere, research for the conversion of CO2 into fuels using carbon-neutral energy is an important…”
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The Influence of the Second and Outer Coordination Spheres on Rh(diphosphine)2 CO2 Hydrogenation Catalysts
Published in ACS catalysis (03-10-2014)“…A series of [Rh(PCH2XRCH2P)2]+ complexes was prepared to investigate second and outer coordination sphere effects on CO2 hydrogenation catalysis, where X is…”
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A Cobalt Hydride Catalyst for the Hydrogenation of CO2: Pathways for Catalysis and Deactivation
Published in ACS catalysis (03-10-2014)“…The complex Co(dmpe)2H catalyzes the hydrogenation of CO2 at 1 atm and 21 °C with significant improvement in turnover frequency relative to previously…”
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Understanding the Relationship Between Kinetics and Thermodynamics in CO2 Hydrogenation Catalysis
Published in ACS catalysis (01-09-2017)“…Catalysts that are able to reduce carbon dioxide under mild conditions are highly sought after for storage of renewable energy in the form of a chemical fuel…”
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Chemical Exchange Saturation Transfer (CEST) as a Tool to Measure Ligand Flexibility of Chelating Chiral Di-N-heterocyclic Carbene Complexes
Published in Organometallics (14-11-2011)“…A series of eight [(diNHC)Rh(CO)2][OTf] complexes, 1′-R, 2′-R, and 3′-R (where diNHC = DEAM, trans-9,10- d ihydro-9,10- e thano a nthracene-11,12-diyl m…”
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Convenient in situ generation of a chiral bis-N-heterocyclic carbene palladium catalyst and its application in enantioselective synthesis
Published in Polyhedron (22-03-2013)“…A method is developed to generate a chiral bis-carbene palladium catalyst from the corresponding C2-symmetric diimidazolium salt and cheap Pd(OAc)2. A series…”
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Mono- and Bimetallic Rhodium(I) Complexes Supported by New C 2-Symmetric Bis-N-heterocyclic Carbene Ligands: Metalation via CC Bond Cleavage under Mild Conditions
Published in Organometallics (22-10-2007)“…The first example of a tethered chiral enetetramine is presented along with its mild metalation with Rh(I) sources to produce chiral, bis-N-heterocyclic…”
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Latency and Immobilization in Silicone Resin by (NHC)Pt(dvtms) Complexes through a Partially Self-Consuming Ligand
Published in Organometallics (22-01-2024)“…Silicones have a plethora of uses but have limitations in placement errors and continuous cross-linking. To address these challenges, we sought to develop a…”
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Understanding the Relationship Between Kinetics and Thermodynamics in CO 2 Hydrogenation Catalysis
Published in ACS catalysis (01-09-2017)“…Linear free-energy relationships have been identified that link the kinetic activity for catalytic hydrogenation of CO2 to formate with the thermodynamic…”
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A Cobalt-Based Catalyst for the Hydrogenation of CO 2 under Ambient Conditions
Published in Journal of the American Chemical Society (07-08-2013)Get full text
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Synthesis and characterization of κ-2- bis- N-heterocyclic carbene rhodium(I) catalysts: Application in enantioselective arylboronic acid addition to cyclohex-2-enones
Published in Journal of organometallic chemistry (01-10-2011)“…This manuscript describes the synthesis and characterization of new derivatives of di- N-heterocyclic carbene (diNHC) ligands derived from…”
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The Influence of the Second and Outer Coordination Spheres on Rh(diphosphine) 2 CO 2 Hydrogenation Catalysts
Published in ACS catalysis (03-10-2014)Get full text
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A Cobalt Hydride Catalyst for the Hydrogenation of CO 2 : Pathways for Catalysis and Deactivation
Published in ACS catalysis (03-10-2014)Get full text
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