Search Results - "Jalan, Ankur"
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Convergent Total Synthesis of Yaku'amide A
Published in Angewandte Chemie International Edition (01-03-2021)“…Total synthesis of the anticancer peptide natural product yaku'amide A is reported. Its β‐tert‐hydroxy amino acids were prepared by regioselective…”
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Journal Article -
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Mechanistic Study of Diketopiperazine Formation during Solid-Phase Peptide Synthesis of Tirzepatide
Published in ACS omega (20-12-2022)“…This study focused on investigating diketopiperazine (DKP) and the formation of associated double-amino-acid deletion impurities during linear solid-phase…”
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Journal Article -
3
Convergent Total Synthesis of Yaku'amide A
Published in Angewandte Chemie (01-03-2021)“…Total synthesis of the anticancer peptide natural product yaku'amide A is reported. Its β‐tert‐hydroxy amino acids were prepared by regioselective…”
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Journal Article -
4
Microwave-Promoted Tin-Free Iminyl Radical Cyclization with TEMPO Trapping: A Practical Synthesis of 2‑Acylpyrroles
Published in Organic letters (06-02-2015)“…Microwave-promoted iminyl radical cyclizations can be terminated by trapping with TEMPO, affording functionalized adducts. The use of alkynes as radical…”
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Journal Article -
5
Metal-free reductive desulfurization of C-sp 3 -substituted thiols using phosphite catalysis
Published in Chemical science (Cambridge) (30-08-2023)“…Phosphines and phosphites are critical tools for non-metal desulfurative methodologies due to the strength of the PS bond. An overarching premise in these…”
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Journal Article -
6
Enantiomeric purity analysis of synthetic peptide therapeutics by direct chiral high-performance liquid chromatography-electrospray ionization tandem mass spectrometry
Published in Journal of chromatography. B, Analytical technologies in the biomedical and life sciences (15-03-2023)“…•Chiral separations of underivatized amino acids using Crownpak®CR-I(+) and Chiralpak® ZWIX(-) packings interfaced with HPLC-MS/MS.•Application for purity…”
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Journal Article -
7
Metal-free reductive desulfurization of C-sp3-substituted thiols using phosphite catalysis
Published in Chemical science (Cambridge) (13-07-2023)“…Phosphines and phosphites are critical tools for non-metal desulfurative methodologies due to the strength of the P=S bond. An overarching premise in these…”
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Journal Article -
8
Metal-free reductive desulfurization of C-sp-substituted thiols using phosphite catalysis
Published in Chemical science (Cambridge) (30-08-2023)“…Phosphines and phosphites are critical tools for non-metal desulfurative methodologies due to the strength of the P&z.dbd;S bond. An overarching premise in…”
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Journal Article -
9
Bulky Dehydroamino Acids Enhance Proteolytic Stability and Folding in β‑Hairpin Peptides
Published in Organic letters (06-10-2017)“…The bulky dehydroamino acids dehydrovaline (ΔVal) and dehydroethylnorvaline (ΔEnv) can be inserted into the turn regions of β-hairpin peptides without…”
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Journal Article -
10
Contribution of Bulky α,β-Dehydroamino Acids to the Proteolytic Stability and Enhanced Folding of β-Hairpins and Progress Towards the Total Synthesis of Yaku'Amide A
Published 01-01-2018“…This dissertation primarily covers the impact of bulky α,β-dehydroamino acids on the proteolytic stability and enhanced folding of β-hairpins. It partly…”
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Dissertation -
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Adaptive 360 degree image recognition approach to empower visually impaired
Published in 2017 IEEE International Conference on Power, Control, Signals and Instrumentation Engineering (ICPCSI) (01-09-2017)“…The visually impaired, in their daily lives face innumerable challenges. Amongst which, the ability to independently navigate and perform daily tasks are the…”
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Conference Proceeding