Search Results - "JacobivonWangelin, Axel"
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Metal-Free Carbonylations by Photoredox Catalysis
Published in Angewandte Chemie International Edition (09-02-2015)“…The synthesis of benzoates from aryl electrophiles and carbon monoxide is a prime example of a transition‐metal‐catalyzed carbonylation reaction which is…”
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2
Reductive Cross-Coupling Reactions between Two Electrophiles
Published in Chemistry : a European journal (02-06-2014)“…Reductive cross‐electrophile coupling reactions have recently been developed to a versatile and sustainable synthetic tool for selective CC bond formation…”
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3
Hydroaminations of Alkenes: A Radical, Revised, and Expanded Version
Published in Angewandte Chemie International Edition (05-10-2015)“…Radical changes: The applicability of alkene hydroamination has recently been significantly expanded by the development of radical variants that are based on…”
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4
Ambient-Light-Mediated Copper-Catalyzed CC and CN Bond Formation
Published in Angewandte Chemie International Edition (03-06-2013)“…Bringing to light: The rediscovery of visible light as an abundant energy source for organic reactions has most recently brought copper-catalyzed coupling…”
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5
Application of Visible-to-UV Photon Upconversion to Photoredox Catalysis: The Activation of Aryl Bromides
Published in Chemistry : a European journal (26-10-2015)“…The activation of aryl–Br bonds was achieved by sequential combination of a triplet–triplet annihilation process of the organic dyes, butane‐2,3‐dione and…”
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6
Dichromatic Photocatalytic Substitutions of Aryl Halides with a Small Organic Dye
Published in Chemistry : a European journal (02-01-2018)“…Photocatalytic bond activations are generally limited by the photon energy and the efficiency of energy and electron transfer processes. Direct two‐photon…”
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7
Ambient-Light-Mediated Copper-Catalyzed CC and CN Bond Formation
Published in Angewandte Chemie International Edition (03-06-2013)“…Bringing to light: The rediscovery of visible light as an abundant energy source for organic reactions has most recently brought copper‐catalyzed coupling…”
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8
Heteroatom-Free Arene-Cobalt and Arene-Iron Catalysts for Hydrogenations
Published in Angewandte Chemie International Edition (01-04-2014)“…75 years after the discovery of hydroformylation, cobalt catalysts are now undergoing a renaissance in hydrogenation reactions. We have evaluated arene…”
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9
Aromatic Chlorosulfonylation by Photoredox Catalysis
Published in ChemSusChem (10-01-2017)“…Visible‐light photoredox catalysis enables the efficient synthesis of arenesulfonyl chlorides from anilines. The new protocol involves the convenient in situ…”
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10
Iron-Catalyzed Cross-Coupling of Alkenyl Acetates
Published in Angewandte Chemie International Edition (01-09-2015)“…Stable CO linkages are generally unreactive in cross‐coupling reactions which mostly employ more electrophilic halides or activated esters (triflates,…”
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11
Iron-Catalyzed Isomerizations of Olefins
Published in ChemCatChem (17-10-2011)“…On the move: A highly practical olefin isomerization protocol under iron catalysis has been developed. The standard conditions involve reaction of the olefin…”
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12
Chlorostyrenes in Iron-Catalyzed Biaryl Coupling Reactions
Published in Angewandte Chemie International Edition (06-02-2012)“…An effective protocol for iron‐catalyzed biaryl syntheses by coupling chlorostyrenes with aryl Grignard reagents requires only mild reaction conditions and…”
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13
Iron‐Catalyzed Cyclotrimerization of Terminal Alkynes by Dual Catalyst Activation in the Absence of Reductants
Published in Angewandte Chemie International Edition (10-07-2017)“…Catalyzing C−C bond‐forming reactions with earth‐abundant metals under mild conditions is at the heart of sustainable synthesis. The cyclotrimerization of…”
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14
Oxidative N-Heterocyclic Carbene Catalysis
Published in ChemCatChem (01-07-2012)“…Hand‐in‐hand with oxidants: Highlighted are the developments in oxidative (and oxygenative) N‐heterocyclic carbene‐catalyzed acylation reactions that employ…”
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15
Visible Light Driven Hydro-/Deuterodefunctionalization of Anilines
Published in Chemistry : a European journal (16-03-2015)“…The defunctionalization of anilines is an important strategy in aromatic‐substitution chemistry. Herein, we report on visible light mediated hydro‐ and…”
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16
Synthesis and Catalysis of Redox‐Active Bis(imino)acenaphthene (BIAN) Iron Complexes
Published in ChemCatChem (23-08-2017)“…Reactions of various substituted bis(imino)acenaphthenes (R‐BIANs) with FeCl2(thf)1.5 afforded the tetrahedral complexes (R‐BIAN)FeCl2 (2) from bulky…”
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17
Alkene Metalates as Hydrogenation Catalysts
Published in Chemistry : a European journal (02-03-2017)“…First‐row transition‐metal complexes hold great potential as catalysts for hydrogenations and related reductive reactions. Homo‐ and heteroleptic arene/alkene…”
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18
Iron(0) Particles: Catalytic Hydrogenations and Spectroscopic Studies
Published in ChemCatChem (01-08-2012)“…Ironing it out: The simple pre‐catalyst system FeCl3/EtMgCl was applied to the hydrogenation of various alkenes and alkynes at room temperature. Domino…”
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19
Iron-Catalyzed Reductive Aryl-Alkenyl Cross-Coupling Reactions
Published in ChemCatChem (10-01-2011)“…Direct and to the point: The simple precatalyst system FeCl3/TMEDA has been effectively applied to cross‐coupling reactions of various arylmagnesium bromides…”
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20
Steric Enhancement of the Chemiluminescence of Luminols
Published in Chemistry : a European journal (06-07-2015)“…A surprising 20‐fold increase in chemiluminescence efficiency was observed for dialkyl luminol derivatives in comparison with the parent compound. This effect…”
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