Search Results - "Jacke, Jürgen"
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Bis(trimethylsilyl)ethyne as a Two-Electron Alkyne Ligand in Group 6 Carbonylmetal(0) Complexes: Photochemical Syntheses and Comprehensive Characterization of M(CO)5(η2-Me3SiC⋮CSiMe3) (M = W, Mo, Cr) and trans-Mo(CO)4(η2-Me3SiC⋮CSiMe3)2
Published in Organometallics (12-09-2005)“…Continued irradiation of W(CO)6 in the presence of excess bis(trimethylsilyl)ethyne (btmse) in n-hexane solution yields W(CO)5(η2-btmse) as the sole product,…”
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Sequential Photosubstitution of Carbon Monoxide by (E)-Cyclooctene in Hexacarbonyltungsten: Structural Aspects, Multistep Photokinetics, and Quantum Yields
Published in Organometallics (16-08-1999)“…The photochemical conversion of W(CO)6 (1) into a trans-W(CO)4(η2-olefin)2 complex has been investigated using (E)-cyclooctene (eco) as a model olefin…”
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Photoreactions of group 6 metal carbonyls with ethene: syntheses of trans-(η2-ethene)2M(CO)4 (M=Cr, Mo, W)
Published in Journal of the American Chemical Society (25-11-1987)Get full text
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Alkene Carbon−Hydrogen Bond Activation at a Heterobimetallic Center: [RuCo(CO)3(μ-CO)(η-C5Me5){μ-η2:η2-C(CF3)C(CF3)}]
Published in Organometallics (13-09-2004)“…Reaction of [RuCo(CO)3(μ-CO)(η-C5Me5){μ-η2:η2-C(CF3)C(CF3)}] (3) with alkenes gave the bis(vinyl) complexes…”
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Photoreactions of group 6 metal carbonyls with olefins
Published in Pure and applied chemistry (01-01-1988)“…Abstract…”
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Alkene Carbon−Hydrogen Bond Activation at a Heterobimetallic Center: [RuCo(CO)3(μ-CO)(η-C5Me5){μ-η2:η2-C(CF3)C(CF3)}]
Published in Organometallics (13-09-2004)Get full text
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